摘要:
Potassium sulfate (K.sub.2 SO.sub.4) is prepared by contacting potassium chloride with an aqueous solution containing potassium bisulfate at a temperature of about 65.degree.-110.degree. C., cooling the solution and permitting the potassium sulfate to crystallize from solution.
摘要翻译:通过在约65-110℃的温度下使氯化钾与含有硫酸氢钾的水溶液接触来制备硫酸钾(K 2 SO 4),冷却溶液并允许硫酸钾从溶液中结晶。
摘要:
In the oxidation of a molten salt, such as copper chlorides with the simultaneous recovery of chlorine values, as chlorine and/or hydrogen chloride, oxygen is introduced into a lower bed and chlorine values are introduced into an upper bed for contact with downwardly flowing melt. By reversing the point of introduction of chlorine values and oxygen, the overall bed contact area required is increased.
摘要:
Regeneration process for spent pickle liquor comprising the oxidizing of an aqueous solution of ferrous chloride and hydrochloric acid in the presence of activated carbon to form aqueous ferric chloride which in turn is hydrolyzed to about 232*C. on a graphite hearth to yield vaporized hydrochloric acid and iron oxide.
摘要:
1. A PROCESS FOR THE GRNERATION OF HYDROGEN AND OXYGEN COMPRISING THE STEPS OF: (A) REACTING FERROUS HALIDE SELECTED FROM THE GROUP CONSISTING OF FERROUS CHLORIDE AND FERROUS HALIDE SELECTED FROM WITH STREAM AT A TEMPERATURE IN EXCESS OF ABOUT 350* C. TO PRODUCE SOLID IRON OXIDE AND A FIRST GASEOUS MIXTURE CONTAINING HYDROGEN, THE RESPECTIVE HYDROGEN HALIDE AND STEAM, (B) REMOVING AND COOLING SAID FIRST GASEOUS MIXTURE, (C) BRINGING THE COOLED FIRST GASEOUS MIXTURE INTO CONRACT WITH THE IRON OXIDE FORMED TO BRING ABOUT DISSOLUTION THEREOF AND PRODUCE A SECOND GASEOUS MIXTURE SIMILAR TO SAID FIRST MIXTURE WITH REDUCED HYDROGEN HALIDE CONTENT, (D) SEPARATING AND COLLECTING HYDROGEN GAS FROM SAID SECOND GASEOUS MIXTURE, (E) REMOVING RHE SOLUTION OF FERROUS HALIDE, THE RESPECTIVE FERRIC HALIDE, WATER AND HYDROGEN HALIDE RESULTING FROM SAID DISSOLUTION, (F) EXTRACTING FERIC HALIDE FROM SAID SOLUTION, (G) RECOVERING FEROUS HALIDE, WATER AND HYDROGEN HALIDE MIXTURE FROM THE FERRIC HALIDE-DEPLETED MIXTURE, (H) RECIRCULATING AND HEATING THE FERROUS HALIDE, WATER, HYDROGEN HALIDE MIXTURE FOR THE CONDUCT OF STEP (A), (I) THERMALLY DECOMPOSING THE EXTRACTED FERRIC HALIDE AT A TEMPERAUTRE OF ABOUT 300* C. TO PRODUCE FERROUS HALIDE AND THE RESPECTIVE HALOGEN, SAID FERROUS HALIDE BEING ADDED TO THE HEATED FERROUS HALIDE, WATER HYDROGEN HALIDE MIXTURE BEING RECIRCULATED, (J) REACTING THE HALOGEN WITH WATER AND MAGNESIUM HYDROXIDE IN THE PRESENCE OF A CATALYST FOR DECOMPOSITION OF THE WATER AND (K) RECORVERING AND COLLECTING OXYGEN GAS PRODUCED THEREBY.
摘要:
THIS INVENTION IS DIRECTED TO THE OXIDATION OF FERROUS CHLORIDE IN LIQUID AQUEOUS SOLUTION, SUCH AS WASTE HC1 PICKLE LIQUOR, TO A SOLUTION CONTAINING FERRIC CHLORIDE BY INTIMATELY INTERMINGLING SAID FERROUS CHLORIDE SOLUTION WITH FREE OXYGEN (1) IN THE PRESENCE OF A DISSOLVED PROMOTER CATION SELECTED FROM THE CLASS OF AMMONIUM, CHROMIUM, COBALT, COPPER, MANGANESE, NICKEL, ZINC OR MIXTURES THEREOF AT AN ELEVATED TEMPERATURE OR (2) IN THE ABSENCE OF PROMOTER, AT SUPERATMOSPHERIC PRESSURE AND AT A TEMPERATURE OF AT LEAST ABOUT 175*F., FOR A TIME SUFFICIENT TO OBTAIN A FERRIC CHLORIDE CONTAINING SOLUTION. A MIXTURE OF AMMONIUM IONS AND CUPRIC IONS IS THE PREFERRED PROMOTER. THE INVENTION IS ALSO DIRECTED TO PRODUCING HYDROCHLORIC ACID FROM THE FERRIC CHLORIDE SOLUTION OBTAINED BY THE AFORESAID OXIDATION PROCESS BY THE SOLUTION AT A TEMPERATURE OF ABOUT 250-400* F. TO OBTAIN A HC1 GAS-WATER VAPOR OVERHEAD AND A BOTTOMS AQUEOUS SLURRY OF IRON OXIDE.
摘要:
A method for extracting pure alumina from alunite and aluminosilicate ores having a high-SO3 content wherein a mixture of at least two alkali chlorides is added to the ore and the combined ore and alkali chlorides is heated to a temperature between 500* and 590* C.
摘要:
A REACTION MASS IS PRODUCED BY IMPREGNATING A POROUS INERT SUPPORT WITH MAGNESIUM CHLORIDE AND ALKALI METAL CHLORIDE AS WELL AS COPPER CHLORIDE AS REACTION PROMOTER, SAID REACTION MASS IS CHLORINATED BY MEANS OF HYDROGEN CHLORIDE OR AMMONIUM CHLORIDE, AND THEN THE RESULTING CHLORINATED MASS IS OXIDIZED BY OXYGEN OR AIR TO GENEARATE CHLORINE, WHILE AT THE SAME TIME THE REACTION MASS REGENERATED BY THE OXIDATION IS RECYCLED TO SAID CHLORINATION STAGE.