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    PROCESSES FOR PRODUCING Z-1,1,1,4,4,4-HEXAFLUOROBUT-2-ENE AND INTERMEDIATES FOR PRODUCING SAME
    2.
    发明申请
    PROCESSES FOR PRODUCING Z-1,1,1,4,4,4-HEXAFLUOROBUT-2-ENE AND INTERMEDIATES FOR PRODUCING SAME 有权

    公开(公告)号：US20220194879A1

    公开(公告)日：2022-06-23

    申请号：US17601512

    申请日：2020-04-03

    申请人： THE CHEMOURS COMPANY FC, LLC

    发明人： SHENG PENG ,  ALLEN CAPRON SIEVERT

    IPC分类号： C07C17/06 ,  C07C17/04 ,  C07C17/269

    摘要： Processes for producing Z-1,1,1,4,4,4-hexafluorobut-2-ene and intermediates for producing same. A process for producing 2-chloro-1,1,1,4,4,4-hexafluorobutane comprises contacting 1,1,2,4,4-pentachlorobuta-1,3-diene with HF in the liquid phase in the presence of a fluorination catalyst. A process for producing 2,2-dichloro-1,1,1,4,4,4-hexafluorobutane comprises contacting 2-chloro-1,1,1,4,4,4-hexafluorobutane with a chlorine source. A process for producing 1,1,1,4,4,4-hexafluoro-2-butyne comprises contacting 2,2-dichloro-1,1,1,4,4,4-hexafluorobutane with a base. A process for producing Z-1,1,1,4,4,4-hexafluorobut-2-ene comprises contacting 1,1,1,4,4,4-hexafluoro-2-butyne with hydrogen.

    Process for producing a chlorinated alkane
    5.
    发明授权
    Process for producing a chlorinated alkane 有权

    公开(公告)号：US10793496B2

    公开(公告)日：2020-10-06

    申请号：US16092451

    申请日：2017-04-12

    申请人： SPOLEK PRO CHEMICKOU A HUTNI VYROBU A.S.

    发明人： Zdenek Ondrus ,  Pavel Kubicek

    IPC分类号： C07C17/04 ,  C07C17/013 ,  C07C17/06 ,  C07C17/093 ,  C07C17/10 ,  C07C19/01

    摘要： A process for producing a chlorinated alkane in which an alkene or an alkane feedstock is contacted with chlorine in a chlorination zone to produce a reaction mixture containing the chlorinated alkane, wherein the chlorine supplied into the chlorination zone has an oxygen content of less than about 2000 ppmv and wherein: the chlorination zone is closed to the atmosphere, and/or the chlorination zone is operated under atmospheric or superatmospheric pressure, and/or the chlorination zone is operated under an inert atmosphere, and/or the content of dissolved oxygen in the alkene or alkane feedstock is less than 2000 ppm.

    PROCESSES FOR THE PRODUCTION OF FLUOROPROPANES AND HALOPROPENES
    6.
    发明申请
    PROCESSES FOR THE PRODUCTION OF FLUOROPROPANES AND HALOPROPENES 审中-公开

    公开(公告)号：US20200172455A1

    公开(公告)日：2020-06-04

    申请号：US16781025

    申请日：2020-02-04

    申请人： THE CHEMOURS COMPANY FC, LLC

    发明人： Velliyur Nott Mallikarjuna Rao ,  Allen Capron Sievert

    IPC分类号： C07C17/06 ,  B01J23/26

    摘要： A process is disclosed for making CF3CF2CH3, CF3CF═CH2 and/or CF3CCl═CH2. The process involves reacting at least one starting material selected from the group consisting of halopropanes of the formula CX3CH2CH2X, halopropenes of the formula CX3CH═CH2 and halopropenes of the formula CX2═CHCH2X, wherein each X is independently F or Cl, with HF and Cl2 in a reaction zone to produce a product mixture comprising HF, HCl, CF3CF2CH3, CF3CF═CH2, and CF3CCl═CH2; and recovering the CF3CF2CH3, CF3CF═CH2 and/or CF3CCl═CH2 from the product mixture. Also disclosed is a process for making CF3CH2CHF2, CF3CH═CHF, and/or CF3CH═CHCl. This process involves reacting at least one starting material selected from the group consisting of halopropenes of the formula CX3CH═CH2 and halopropenes of the formula CX2═CHCH2X, wherein each X is independently F or Cl, with HF and Cl2 in a reaction zone to produce a product mixture comprising HF, HCl, CF3CH2CHF2, CF3CH═CHF and CF3CH═CHCl; and recovering the CF3CH2CHF2, CF3CH═CHF, and/or CF3CH═CHCl from the product mixture. The molar ratio of HF to the total amount of starting materials fed to the reaction zone for both of these processes is at least stoichiometric, and the molar ratio of Cl2 to total amount of starting material fed to the reaction zone for both of these processes is 2:1 or less.

    Process for the production of chlorinated propenes
    10.
    发明授权
    Process for the production of chlorinated propenes 有权
    生产氯化丙烯的方法

    公开(公告)号：US09512053B2

    公开(公告)日：2016-12-06

    申请号：US14653503

    申请日：2013-12-18

    申请人： Blue Cube IP LLC

    发明人： Max M. Tirtowidjojo ,  David S. Laitar ,  Barry B. Fish ,  Matthew L. Grandbois

    IPC分类号： C07C17/013 ,  C07C17/21 ,  C07C17/06 ,  C07C17/04 ,  C07C17/10 ,  C07C17/25

    CPC分类号： C07C17/013 ,  C07C17/04 ,  C07C17/06 ,  C07C17/10 ,  C07C17/21 ,  C07C17/25 ,  C07C19/01 ,  C07C21/04

    摘要： Processes for the production of chlorinated propenes are provided. The processes make use of 1,2-dichloropropane as a starting material and subject a feedstream comprising the same to an ionic chlorination process. At least a portion of any tri- and tetrachlorinated propanes not amenable to ionic chlorination conditions are removed from the ionic chlorination product stream, or, are subjected to chemical base dehydrochlorination step. In this way, recycle of intermediates not amenable to ionic chlorination reactions is reduced or avoided, as is the buildup of these intermediates within the process. Selectivity and, in some embodiments, yield of the process is thus enhanced.

    摘要翻译： 提供了生产氯化丙烯的方法。 该方法利用1,2-二氯丙烷作为起始原料，并将含有该二氯丙烷的原料流进行离子氯化处理。 任何不适于离子氯化条件的任何三氯化四氯化丙烷的至少一部分从离子氯化产物流中除去，或者进行化学碱脱氯化氢步骤。 以这种方式，减少或避免不适于离子氯化反应的中间体的再循环，以及这些中间体在该方法中的积累。 因此，在一些实施方案中，选择性，因此增强了该方法的产率。