Preparation of chlorine and ammonia from ammonium chloride
    3.
    发明授权
    Preparation of chlorine and ammonia from ammonium chloride 失效
    氯化锂制备氯胺和氨

    公开(公告)号:US3627471A

    公开(公告)日:1971-12-14

    申请号:US3627471D

    申请日:1967-06-05

    IPC分类号: C01B7/05 C01B1/02

    CPC分类号: C01B7/05

    摘要: METHOD OF MAKING AMMONIA AND CHLORINE FROM AMMONIUM CHLORIDE BY THERMAL DISSOCIATION WITH A CATALYST MASS COMPRISING A PARTLY REDUCED METAL OXIDE FIXING THE CHLORINE ION AS A METALLIC CHLORIDE WHILE THE LIBERATED AMMONIA GAS PASSES OFF WITH WATER VAPOR AND IS CAPTURED. IN A SUBSEQUENT STEP OF OXIDATION THE CHLORINE IS LIBERATED AND THE METAL OXIDE IS IN A HIGHER STATE. THIS OXIDE IS AGAIN PARTLY REDUCED AND THE PROCESS IS REPEATED WITH NEW AMMONIUM CHLORIDE. IN THE IMPROVEMENT THE CATALYST MASS IS MADE OF MOLTEN ALKALI METAL CHLORIDES CONTAINING IN SUSPENSION A FINELY DIVIDED METAL OXIDE SUCH AS FE, NI, CO, AND PREFERABLY FE.