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1.发明申请公开(公告)号：US20170136137A1
公开(公告)日：2017-05-18
申请号：US15419376
申请日：2017-01-30
发明人： Thomas Ellsworth MCWORTER , Aaron ROSENBLATT , Robert SHAY , Barzin KERAMATI , Peter KAZLAS , Madhu ANAND , John Peter HOBBS
CPC分类号： A61L2/18 , A01N59/00 , A23L3/358 , A23V2002/00 , A61K33/00 , A61K33/20 , C01B11/022 , C01B11/024 , C01B11/028 , C02F1/50 , C02F2303/04 , Y10T428/13 , Y10T428/131 , Y10T428/1334 , Y10T428/1352 , A01N25/22
摘要： Stable, aqueous solutions of chlorine dioxide and methods for producing stable, aqueous solutions of chlorine dioxide are disclosed. Generally, the chlorine dioxide solutions of the invention are aqueous solutions containing about 1000 ppm by weight or less of total impurities and/or 10 ppm or less of manganese and iron combined. The aqueous chlorine dioxide solutions are storage stable for at least 90 days at 25° C. and maintain at least 75% of the initial chlorine dioxide concentration. Methods of preparing, using and transporting the chlorine dioxide solutions are also disclosed.
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2.发明授权Storage-stable aqueous solutions of chlorine dioxide and methods for preparing and using them 有权储存稳定的二氧化氯水溶液及其制备和使用方法公开(公告)号：US09580317B2
公开(公告)日：2017-02-28
申请号：US14824548
申请日：2015-08-12
发明人： Thomas Ellsworth McWhorter , Aaron Rosenblatt , Robert Shay , Barzin Keramati , Peter Kazlas , Madhu Anand , John Peter Hobbs
CPC分类号： C01B11/024 , A01N59/00 , A61K33/00 , B65B63/00 , C01B11/022 , C01B11/028 , Y10T428/13 , Y10T428/131 , Y10T428/1334 , Y10T428/1352
摘要： The present invention is for extremely pure solutions of chlorine dioxide, methods for making such solutions and to compositions and methods for storing, shipping and using such solutions. Generally, the chlorine dioxide solutions of the invention are aqueous solutions containing about 2500 ppm or less of total impurities. The chlorine dioxide solution can be prepared by passing dilute highly pure chlorine gas through a bed of substantially solid sodium chloride and contacting the resulting chlorine dioxide gas with a liquid.
摘要翻译： 本发明是用于二氧化氯的非常纯的溶液，制备这种溶液的方法以及用于储存，运输和使用这些溶液的组合物和方法。 通常，本发明的二氧化氯溶液是含有约2500ppm或更少的总杂质的水溶液。 通过将稀释的高纯氯气通过基本上固体的氯化钠床并使所得的二氧化氯气体与液体接触来制备二氧化氯溶液。
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3.发明授权公开(公告)号：US09045341B2
公开(公告)日：2015-06-02
申请号：US13365912
申请日：2012-02-03
申请人： Thomas Ellsworth McWhorter , Peter Kazlas , Madhu Anand , John Peter Hobbs , Aaron A. Rosenblatt , Robert H. Shay , Barzin Keramati
发明人： Thomas Ellsworth McWhorter , Peter Kazlas , Madhu Anand , John Peter Hobbs , Aaron A. Rosenblatt , Robert H. Shay , Barzin Keramati
CPC分类号： C01B11/024 , A01N59/00 , A61K33/00 , B65B63/00 , C01B11/022 , C01B11/028 , Y10T428/13 , Y10T428/131 , Y10T428/1334 , Y10T428/1352
摘要： The present invention is for extremely pure solutions of chlorine dioxide, methods for making such solutions and to compositions and methods for storing, shipping and using such solutions. Generally, the chlorine dioxide solutions of the invention are aqueous solutions containing about 2500 ppm or less of total impurities. The chlorine dioxide solution can be prepare by passing dilute highly pure chlorine gas through a bed of substantially solid sodium chlorite and contacting the resulting chlorine dioxide gas with a liquid.
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4.发明申请Storage-Stable Aqueous Solutions of Chlorine Dioxide and Methods for Preparing and Using Them 有权储存稳定的二氧化氯水溶液及其制备和使用方法公开(公告)号：US20120135167A1
公开(公告)日：2012-05-31
申请号：US13365902
申请日：2012-02-03
申请人： Thomas Ellsworth McWhorter , Peter Kazlas , Madhu Anand , John Peter Hobbs , Aaron A. Rosenblatt , Robert H. Shay , Barzin Keramati
发明人： Thomas Ellsworth McWhorter , Peter Kazlas , Madhu Anand , John Peter Hobbs , Aaron A. Rosenblatt , Robert H. Shay , Barzin Keramati
IPC分类号： B32B1/08
CPC分类号： C01B11/024 , A01N59/00 , A61K33/00 , B65B63/00 , C01B11/022 , C01B11/028 , Y10T428/13 , Y10T428/131 , Y10T428/1334 , Y10T428/1352
摘要： The present invention is for extremely pure solutions of chlorine dioxide, methods for making such solutions and to compositions and methods for storing, shipping and using such solutions. Generally, the chlorine dioxide solutions of the invention are aqueous solutions containing about 2500 ppm or less of total impurities. The chlorine dioxide solution can be prepare by passing dilute highly pure chlorine gas through a bed of substantially solid sodium chloride and contacting the resulting chlorine dioxide gas with a liquid.
摘要翻译： 本发明是用于二氧化氯的非常纯的溶液，制备这种溶液的方法以及用于储存，运输和使用这些溶液的组合物和方法。 通常，本发明的二氧化氯溶液是含有约2500ppm或更少的总杂质的水溶液。 可以通过将稀释的高纯氯气通过基本上固体的氯化钠床并使得到的二氧化氯气体与液体接触来制备二氧化氯溶液。
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5.发明授权Storage-stable aqueous solutions of chlorine dioxide and methods for preparing and using them 有权储存稳定的二氧化氯水溶液及其制备和使用方法公开(公告)号：US09045338B2
公开(公告)日：2015-06-02
申请号：US13365869
申请日：2012-02-03
申请人： Thomas Ellsworth McWhorter , Peter Kazlas , Madhu Anand , John Peter Hobbs , Aaron A. Rosenblatt , Robert H. Shay , Barzin Keramati
发明人： Thomas Ellsworth McWhorter , Peter Kazlas , Madhu Anand , John Peter Hobbs , Aaron A. Rosenblatt , Robert H. Shay , Barzin Keramati
CPC分类号： C01B11/024 , A01N59/00 , A61K33/00 , B65B63/00 , C01B11/022 , C01B11/028 , Y10T428/13 , Y10T428/131 , Y10T428/1334 , Y10T428/1352
摘要： The present invention is for extremely pure solutions of chlorine dioxide, methods for making such solutions and to compositions and methods for storing, shipping and using such solutions. Generally, the chlorine dioxide solutions of the invention are aqueous solutions containing about 2500 ppm or less of total impurities. The chlorine dioxide solution can be prepare by passing dilute highly pure chlorine gas through a bed of substantially solid sodium chlorite and contacting the resulting chlorine dioxide gas with a liquid.
摘要翻译： 本发明是用于二氧化氯的非常纯的溶液，制备这种溶液的方法以及用于储存，运输和使用这些溶液的组合物和方法。 通常，本发明的二氧化氯溶液是含有约2500ppm或更少的总杂质的水溶液。 可以通过将稀释的高纯氯气通过基本上固体的亚氯酸钠床并使所得的二氧化氯气体与液体接触来制备二氧化氯溶液。
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6.发明申请公开(公告)号：US20120201899A1
公开(公告)日：2012-08-09
申请号：US13365885
申请日：2012-02-03
申请人： Thomas Ellsworth McWhorter , Peter Kazlas , Madhu Anand , John Peter Hobbs , Aaron A. Rosenblatt , Robert H. Shay , Barzin Keramati
发明人： Thomas Ellsworth McWhorter , Peter Kazlas , Madhu Anand , John Peter Hobbs , Aaron A. Rosenblatt , Robert H. Shay , Barzin Keramati
CPC分类号： C01B11/024 , A01N59/00 , A61K33/00 , B65B63/00 , C01B11/022 , C01B11/028 , Y10T428/13 , Y10T428/131 , Y10T428/1334 , Y10T428/1352
摘要： The present invention is for extremely pure solutions of chlorine dioxide, methods for making such solutions and to compositions and methods for storing, shipping and using such solutions. Generally, the chlorine dioxide solutions of the invention are aqueous solutions containing about 2500 ppm or less of total impurities. The chlorine dioxide solution can be prepare by passing dilute highly pure chlorine gas through a bed of substantially solid sodium chloride and contacting the resulting chlorine dioxide gas with a liquid.
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7.发明申请公开(公告)号：US20120201898A1
公开(公告)日：2012-08-09
申请号：US13365869
申请日：2012-02-03
申请人： Thomas Ellsworth McWhorter , Peter Kazlas , Madhu Anand , John Peter Hobbs , Aaron A. Rosenblatt , Robert H. Shay , Barzin Keramati
发明人： Thomas Ellsworth McWhorter , Peter Kazlas , Madhu Anand , John Peter Hobbs , Aaron A. Rosenblatt , Robert H. Shay , Barzin Keramati
IPC分类号： A01N59/00
CPC分类号： C01B11/024 , A01N59/00 , A61K33/00 , B65B63/00 , C01B11/022 , C01B11/028 , Y10T428/13 , Y10T428/131 , Y10T428/1334 , Y10T428/1352
摘要： The present invention is for extremely pure solutions of chlorine dioxide, methods for making such solutions and to compositions and methods for storing, shipping and using such solutions. Generally, the chlorine dioxide solutions of the invention are aqueous solutions containing about 2500 ppm or less of total impurities. The chlorine dioxide solution can be prepare by passing dilute highly pure chlorine gas through a bed of substantially solid sodium chloride and contacting the resulting chlorine dioxide gas with a liquid.
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8.发明授权公开(公告)号：US11135326B2
公开(公告)日：2021-10-05
申请号：US15419376
申请日：2017-01-30
发明人： Thomas Ellsworth McWhorter , Aaron Rosenblatt , Robert Shay , Barzin Keramati , Peter Kazlas , Madhu Anand , John Peter Hobbs
摘要： Stable, aqueous solutions of chlorine dioxide and methods for producing stable, aqueous solutions of chlorine dioxide are disclosed. Generally, the chlorine dioxide solutions of the invention are aqueous solutions containing about 1000 ppm by weight or less of total impurities and/or 10 ppm or less of manganese and iron combined. The aqueous chlorine dioxide solutions are storage stable for at least 90 days at 25° C. and maintain at least 75% of the initial chlorine dioxide concentration. Methods of preparing, using and transporting the chlorine dioxide solutions are also disclosed.
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公开(公告)号：US09656865B2
公开(公告)日：2017-05-23
申请号：US12296051
申请日：2007-04-05
CPC分类号： C01B11/022 , A61L2/20 , A61L2/22
摘要： New methods are disclosed for decontaminating surfaces and enclosures that avoid problems such as salt deposits, corrosion and condensation that accompany the use of known methods. The methods involve the use of chlorine dioxide solutions prepared by passing dilute chlorine gas over solid granular sodium chlorite to produce chlorine dioxide gas which is then collected to form a solution with very low levels of impurities. The chlorine dioxide gas can be introduced into an enclosure and used to disinfect a portion of the contents of the enclosure.
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10.发明授权公开(公告)号：US09045340B2
公开(公告)日：2015-06-02
申请号：US13365902
申请日：2012-02-03
申请人： Thomas Ellsworth McWhorter , Peter Kazlas , Madhu Anand , John Peter Hobbs , Aaron A. Rosenblatt , Robert H. Shay , Barzin Keramati
发明人： Thomas Ellsworth McWhorter , Peter Kazlas , Madhu Anand , John Peter Hobbs , Aaron A. Rosenblatt , Robert H. Shay , Barzin Keramati
CPC分类号： C01B11/024 , A01N59/00 , A61K33/00 , B65B63/00 , C01B11/022 , C01B11/028 , Y10T428/13 , Y10T428/131 , Y10T428/1334 , Y10T428/1352
摘要： The present invention is for extremely pure solutions of chlorine dioxide, methods for making such solutions and to compositions and methods for storing, shipping and using such solutions. Generally, the chlorine dioxide solutions of the invention are aqueous solutions containing about 2500 ppm or less of total impurities. The chlorine dioxide solution can be prepare by passing dilute highly pure chlorine gas through a bed of substantially solid sodium chlorite and contacting the resulting chlorine dioxide gas with a liquid.
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