公开(公告)号：US20230323086A1

公开(公告)日：2023-10-12

申请号：US18024085

申请日：2021-06-24

申请人： UNIMATEC CO., LTD.

发明人： Satoru SAITO

IPC分类号： C08K5/46 ,  C08K5/17 ,  C08K5/31

CPC分类号： C08K5/46 ,  C08K5/17 ,  C08K5/31

摘要： A phenothiazine derivative represented by the general formula:




(wherein R1 is a monovalent aliphatic hydrocarbon group having 1 to 20 carbon atoms or an aralkyl group having 7 to 20 carbon atoms, and R2.Ar is an aralkyl group, wherein R2 is a divalent aliphatic hydrocarbon group having 1 to 10 carbon atoms, and Ar is a monovalent aromatic hydrocarbon group having 6 to 10 carbon atoms), and

a carboxyl group-containing acrylic rubber composition comprising, based on 100 parts by weight of carboxyl group-containing acrylic rubber:



(A) 0.1 to 5 parts by weight of the phenothiazine derivative represented by the formula [I];
(B) 0.1 to 3 parts by weight of a crosslinking agent for carboxyl group-containing acrylic rubber; and
(C) 0.1 to 5 parts by weight of a crosslinking accelerator for carboxyl group-containing acrylic rubber.

公开(公告)号：US20230084014A1

公开(公告)日：2023-03-16

申请号：US17798338

申请日：2020-11-05

申请人： UNIMATEC CO., LTD.

发明人： Yu SATO ,  Tetsushi KIJIMA ,  Yoshiyama KANEUMI

IPC分类号： C09K3/18 ,  C09D133/16

摘要： A soft water- and oil-repellent comprising, as an active ingredient, a copolymer of a perfluoropolyether alcohol (meth)acrylic acid derivative represented by the general formula: CH2═CR1COOCH2CF(CF3)[OCF2CF(CF3)]nOC3F7  [I] (wherein R1 is a hydrogen atom or a methyl group, and n is an integer of 1 to 20), and a (meth)acrylic acid ester represented by the general formula: CH2═CR1COOR2  [II] (wherein R1 is a hydrogen atom or a methyl group, and R2 is an alkyl group, an alkoxyalkyl group, a cycloalkyl group, an aryl group, or an aralkyl group) and having a glass transition temperature Tg of 51 to 120° C. The soft water- and oil-repellent gives a coating film formed from a coating agent which closely follows the deformation of rubber or resin, and exhibits water- and oil-repellency.

公开(公告)号：US20210403455A1

公开(公告)日：2021-12-30

申请号：US17279466

申请日：2019-11-28

申请人： UNIMATEC CO., LTD.

发明人： Junya SEINO ,  Rie AOTSU ,  Keisuke KOKIN

IPC分类号： C07D403/04 ,  C07D401/04

摘要： A fluorine-containing pyrimidine compound is provided represented by general formula (1), (2), (3), (4), (5), or (6) below. wherein, in the general formulae (1) to (6) above, R represents a hydrocarbon group having 1 to 12 carbon atoms; and X and Y each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 10 carbon atoms, —CnF2n+1 (n is an integer of 1 to 10), a nitro group, a boronate group, —OA1, —SOmA1 (m is an integer of 0 to 3), —NA1A2, —COOA1, or —CONA1A2, and A1 and A2 each independently represent a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms.

公开(公告)号：US10344172B2

公开(公告)日：2019-07-09

申请号：US15549342

申请日：2016-01-22

申请人： UNIMATEC CO., LTD.

发明人： Kyou Shimada ,  Takumi Suzuki ,  Yoshiyama Kaneumi

IPC分类号： C09D5/08 ,  C08F220/24 ,  C09K3/18 ,  C09D133/16 ,  C09D143/04 ,  C08F230/08

摘要： A fluorine-containing copolymer that is a copolymer of: a polyfluoroalkyl alcohol (meth)acrylate represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCOCR═CH2  [I] (R: a hydrogen atom, a methyl group, n: 1 to 6, a: 1 to 4, b: 1 to 3, and c: 1 to 3); benzyl (meth)acrylate or styrene; and a Si group-containing crosslinkable (meth)acrylate represented by the general formula: CH2═CRCOO(CH2)dSi(OR1)eR23−e  [II] (R: a hydrogen atom, a methyl group, R1, R2: an alkyl group having 1 to 10 carbon atoms, d: 1 to 3, e: 1 to 3). The surface-modifying agent comprising this fluorine-containing copolymer as an active ingredient have an excellent dynamic slip angle after washing with hexadecane, and anti-corrosive properties.

公开(公告)号：US10093812B2

公开(公告)日：2018-10-09

申请号：US15125036

申请日：2015-03-10

申请人： UNIMATEC CO., LTD. ,  HIROSAKI UNIVERSITY

发明人： Takeshi Fukushima ,  Katsuyuki Sato ,  Hideo Sawada

IPC分类号： C09D5/16 ,  C08K5/55 ,  C08L101/00 ,  C09D201/00 ,  C09D7/40 ,  C03C17/00

摘要： A composite material of resin—fluorine-containing boric acid composite particles comprising a resin, and a condensate of boric acid and a fluorine-containing alcohol represented by the general formula RF-A-OH (wherein RF is a perfluoroalkyl group having 6 or less carbon atoms, or a polyfluoroalkyl group, in which some of the fluorine atom or atoms of the perfluoroalkyl group are replaced by a hydrogen atom or hydrogen atoms, and which contains a terminal perfluoroalkyl group having 6 or less carbon atoms and a perfluoroalkylene group having 6 or less carbon atoms; and A is an alkylene group having 1 to 6 carbon atoms, or comprising a resin, and a condensate of boric acid, the said fluorine-containing alcohol and an alkoxysilane at a molar ratio of 1.0 or less based on the fluorine-containing alcohol. These composite materials of resin—fluorine-containing boric acid composite particles has good adhesion to inorganic substrates, and the like.

公开(公告)号：US20170291865A1

公开(公告)日：2017-10-12

申请号：US15512446

申请日：2015-09-18

申请人： UNIMATEC CO., LTD.

发明人： Takeshi FUKUSHIMA

IPC分类号： C07C21/18 ,  C07C69/63 ,  C07C67/293 ,  C07C17/363

CPC分类号： C07C21/18 ,  C07C17/361 ,  C07C17/363 ,  C07C67/293 ,  C07C69/14 ,  C07C69/63

摘要： A polyfluoroalkyl allyl compound represented by the general formula: CF3(CF2)n(CH2CF2)a(CF2CF2)bCH2CH═CH2  [I] (n: 0 to 5, a: 1 or 2, b: 0 to 3). The polyfluoroalkyl allyl compound is produced by reacting a carboxylic acid allyl adduct represented by the general formula: CF3(CF2)n(CH2CF2)a(CF2CF2)bCH2CHICH2OCOR′  [II] (n, a, and b are as defined above, and R′: a C1-C3 alkyl group) with a transition metal. This method for producing provides a polyfluoroalkyl allyl compound used as a synthetic intermediate for a fluorine-containing alkylsilane compound that can remove free iodine derived from the raw material compound, before a hydrosilylation reaction is performed, without using a metal reagent having a high environmental impact, and that has excellent handling properties.

公开(公告)号：US09765008B2

公开(公告)日：2017-09-19

申请号：US15110579

申请日：2014-12-19

申请人： UNIMATEC CO., LTD.

发明人： Keisuke Kokin ,  Mitsuru Maeda ,  Daisuke Murai

IPC分类号： C07C59/60 ,  C07C51/41

CPC分类号： C07C59/60 ,  C07C51/412

摘要： A perfluorovinyloxy polyether carboxylic acid alkali metal salt represented by the general formula is provided: CF2═CF[OCF2CF(CF3)]bO(CF2)aO[CF(CF3)CF2O]cCF(CF3)COOM  [I], wherein M is alkali metal, preferably sodium or potassium, a is an integer of 1 to 6, preferably 2, and b+c is an integer of 0 to 6, preferably 0 or 1. This perfluorovinyloxy polyether carboxylic acid alkali metal salt is produced by subjecting a perfluorovinyloxy polyether carboxylic acid alkyl ester represented by the general formula: CF2═CF[OCF2CF(CF3)]bO(CF2)aO[CF(CF3)CF2O]cCF(CF3)COOR  [II], wherein R is an alkyl group having 1 to 12 carbon atoms, a is an integer of 1 to 6, and b+c is an integer of 0 to 6; to hydrolysis or solvolysis in the presence of an alkali metal hydroxide.

公开(公告)号：US09758470B2

公开(公告)日：2017-09-12

申请号：US14910961

申请日：2014-07-16

申请人： UNIMATEC CO., LTD.

发明人： Keisuke Kokin

IPC分类号： C07C219/06 ,  C07C213/06

CPC分类号： C07C219/06 ,  C07C213/06

摘要： A bis(perfluoroether carboxylic acid alkyl)amino ester represented by the general formula: {CnF2n+1O[CF(CF3)CF2O]aCF(CF3)COO(CH2)b}2NR, wherein R is a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, an aryl group, or an aralkyl group; preferably an alkyl group having 1 to 6 carbon atoms or an aryl group; n is an integer of 1 to 3; a is an integer of 0 to 20, preferably an integer of 1 to 6; and b is an integer of 1 to 12, preferably an integer of 1 to 4. The bis(perfluoroether carboxylic acid alkyl)amino ester having an amino group at the end of the ester group is produced by reacting a perfluoroether carboxylic acid fluoride compound of the formula: CnF2n+1O[CF(CF3)CF2O]aCF(CF3)COF and a bis(hydroxyalkyl)amine compound of the formula: HO(CH2)bNR(CH2)bOH at a molar ratio of 2:1 in the presence of an alkali metal fluoride.

公开(公告)号：US20170015833A1

公开(公告)日：2017-01-19

申请号：US15125040

申请日：2015-03-10

申请人： UNIMATEC CO., LTD. ,  HIROSAKI UNIVERSITY

发明人： Takeshi Fukushima ,  Katsuyuki Sato ,  Hideo Sawada

IPC分类号： C09D1/00 ,  B01J31/38 ,  C09D5/00 ,  B01J31/12 ,  B01J35/02 ,  B01J31/02 ,  B01J35/00

CPC分类号： C09D1/00 ,  B01J27/135 ,  B01J31/0202 ,  B01J31/0231 ,  B01J31/124 ,  B01J31/38 ,  B01J35/004 ,  B01J35/02 ,  B82Y30/00 ,  C09C1/36 ,  C09D5/00

摘要： Fluorine-containing titanium oxide—nano-silica composite particles comprising a condensate of a fluorine-containing alcohol and an alkoxysilane, and titanium oxide and nano-silica particles, wherein the fluorine-containing alcohol is represented by the general formula: RF—A—OH  [I] (wherein RF is a perfluoroalkyl group having 6 or less carbon atoms, or a polyfluoroalkyl group, in which some of the fluorine atom or atoms of the perfluoroalkyl group are replaced by a hydrogen atom or atoms, and which contains a terminal perfluoroalkyl group having 6 or less carbon atoms and a perfluoroalkylene group having 6 or less carbon atoms; and A is an alkylene group having 1 to 6 carbon atoms). The fluorine-containing titanium oxide—nano-silica composite particles do not have difficulty in handling as with hydrogen fluoride, can be produced by using a fluorine-containing alcohol, which can be easily handled, and can produce a product capable of suppressing a decrease in the function of the titanium oxide as a photocatalyst even when subjected to a high-temperature heat treatment.

摘要翻译： （其中RF为碳原子数6以下的全氟烷基或多氟烷基，其中氟原子或全氟烷基的一部分被氢原子或原子取代，并且含有末端全氟烷基，具有6个 或更少的碳原子和具有6个或更少碳原子的全氟亚烷基; A是具有1至6个碳原子的亚烷基）。 含氟二氧化钛 - 纳米二氧化硅复合颗粒与氟化氢一样不易处理，可以通过使用易于处理的含氟醇制造，并且可以制造能够抑制下降的产物 即使在经受高温热处理的情况下，作为光催化剂的氧化钛的功能。

公开(公告)号：US08796368B2

公开(公告)日：2014-08-05

申请号：US12739028

申请日：2008-08-08

申请人： Ji-Shan Jin ,  Sumiko Mouri ,  Katsuyuki Sato

发明人： Ji-Shan Jin ,  Sumiko Mouri ,  Katsuyuki Sato

IPC分类号： C08F220/24 ,  C08F220/16 ,  C08F214/08 ,  C08K5/29

CPC分类号： D06M15/277 ,  C08F214/18 ,  C08F220/18 ,  C08F220/24 ,  C08F220/26 ,  C08F2220/286 ,  C08K5/205 ,  C09D133/16 ,  C09K3/18 ,  D06M15/227 ,  D06M15/256 ,  D06M15/273 ,  D06M15/576 ,  D06M2200/11 ,  D06M2200/12

摘要： A water- and oil-repellent comprising an aqueous dispersion of a fluorine-containing copolymer including as a copolymerization unit (a) a perfluoroalkylalkyl (meth)acrylate represented by the general formula CnF2n+1CmH2mOCOCR═CH2 (wherein R represents hydrogen atom or methyl group; n represents 4, 5, or 6; and m represents 1, 2, 3, or 4), (b) benzyl (meth)acrylate, (c) a fluorine-free polymerizable monomer other than benzyl (meth)acrylate, and (d) a cross-linkable group-containing polymerizable monomer; and a blocked isocyanate added to the aqueous dispersion in a weight ratio of 0.05 to 3.0 to the weight of the solid content of the aqueous dispersion.

摘要翻译： 1.一种拒水拒油剂，其特征在于，含有含氟共聚物的水分散体，其含有作为共聚单元（a）由通式CnF2n + 1CmH2mOCOCR=CH2表示的（甲基）丙烯酸全氟烷基烷基酯（其中，R表示氢原子或甲基 （甲基）丙烯酸苄酯，（c）除（甲基）丙烯酸苄酯以外的无氟可聚合单体，和 （d）可交联基团的可聚合单体; 和与水性分散体的固体成分的重量比为0.05〜3.0的嵌段异氰酸酯。