Benzofuranone stabilization of phosphate esters
    1.
    发明授权
    Benzofuranone stabilization of phosphate esters 失效
    苯并呋喃酮磷酸酯稳定化

    公开(公告)号:US07071347B2

    公开(公告)日:2006-07-04

    申请号:US10220408

    申请日:2001-03-01

    IPC分类号: C07F9/02

    CPC分类号: C07F9/025

    摘要: A method for decolorizing and stabilizing alkylphenyl esters of phosphoric acid which comprises contacting the esters with an effective amount of a benzofuranone (e.g., is 5,7-di-t-butyl-3-(3,4 di-methylphenyl)3H-benzofuran-2-one) for a sufficient length of time to decolorize and stabilize the esters against subsequent color formation.

    摘要翻译: 一种使磷酸的烷基苯基酯脱色和稳定的方法,其包括使酯与有效量的苯并呋喃(例如,5,7-二叔丁基-3-(3,4-二甲基苯基)3H-苯并呋喃 -2-酮)足够长的时间以使酯脱色并稳定酯以防止随后的颜色形成。

    Alkylation of triphenylphosphate
    2.
    发明申请
    Alkylation of triphenylphosphate 失效
    磷酸三苯酯的烷基化

    公开(公告)号:US20050137425A1

    公开(公告)日:2005-06-23

    申请号:US10744466

    申请日:2003-12-23

    IPC分类号: C07F9/02 C07F9/12

    CPC分类号: C07F9/12

    摘要: A process for the alkylation of triphenylphosphate by reaction of triphenylphosphate with an olefin in the presence of an effective amount of a solid acid catalyst selected from the group consisting of at least one zeolite, heteropolyacid or salt thereof, metal triflate, non-aryl group-containing metal sulfonic acid, metal halide Lewis acid, or compatible mixture of any such catalyst.

    摘要翻译: 在有效量的选自至少一种沸石,杂多酸或其盐的金属三氟甲磺酸酯,非芳基基团的烷基酯的固体酸催化剂存在下,通过使磷酸三苯酯与烯烃反应来烷基化磷酸三苯酯的方法, 含有金属磺酸,金属卤化物路易斯酸或任何这种催化剂的相容混合物。

    BENZOFURANONE STABILIZATION OF PHOSPHATE ESTERS
    4.
    发明申请
    BENZOFURANONE STABILIZATION OF PHOSPHATE ESTERS 失效
    苯唑嘌呤稳定磷酸酯酯

    公开(公告)号:US20060063947A1

    公开(公告)日:2006-03-23

    申请号:US10220408

    申请日:2001-03-01

    IPC分类号: C07F9/02

    CPC分类号: C07F9/025

    摘要: A method for decolorizing and stabilizing alkylphenyl esters of phosphoric acid which comprises contacting the esters with an effective amount of a benzofuranone (e.g., is 5,7-di-t-butyl-3-(3,4 di-methylphenyl)3H-benzofuran-2-one) for a sufficient length of time to decolorize and stabilize the esters against subsequent color formation.

    摘要翻译: 一种使磷酸的烷基苯基酯脱色和稳定的方法,其包括使酯与有效量的苯并呋喃(例如,5,7-二叔丁基-3-(3,4-二甲基苯基)3H-苯并呋喃 -2-酮)足够长的时间以使酯脱色并稳定酯以防止随后的颜色形成。

    Arbuzov reactions employing an aliphatic solvent
    5.
    发明授权
    Arbuzov reactions employing an aliphatic solvent 失效
    使用脂族溶剂的Arbuzov反应

    公开(公告)号:US4311652A

    公开(公告)日:1982-01-19

    申请号:US154170

    申请日:1980-05-28

    IPC分类号: C07F9/40

    CPC分类号: C07F9/4015 C07F9/4075

    摘要: An improved process for phosphite rearrangement wherein the phosphite is rearranged to the phosphonate. The improvement comprises conducting the phosphite rearrangement reaction in an aliphatic solvent which is miscible with the reactants at reaction temperatures, and immiscible with the product at lower temperatures. Increased yields of the phosphonate product are obtained without the need for additional distillation for solvent separation.

    摘要翻译: 亚磷酸酯重排的改进方法,其中将亚磷酸酯重排为膦酸酯。 改进之处在于在脂肪族溶剂中进行亚磷酸酯重排反应,其在反应温度下可与反应物混溶,并且在较低温度下与产物不混溶。 获得了增加的膦酸盐产物的产率,而不需要额外的蒸馏用于溶剂分离。