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1.发明授权Process and adsorbent for separating ethanol and associated oxygenates from a biofermentation system 有权用于从生物发酵系统中分离乙醇和相关含氧化合物的方法和吸附剂公开(公告)号：US08658845B2
公开(公告)日：2014-02-25
申请号：US13478160
申请日：2012-05-23
IPC分类号： C07C29/76
CPC分类号： C07C29/76 , C07C29/80 , Y02E50/17 , Y02E50/343 , C07C31/08 , C07C31/207
摘要： Disclosed is a process and an adsorbent for the separation of ethanol associated oxygenates from a dilute mixture of ethanol and associated oxygenates in water in the presence of organic compounds derived from a biofermentation process. After pretreatment, the separation is carried out in a simulated moving bed adsorption system employing an stationary phase adsorbent comprising fluorinated carbon or modified C18 silica gel selective for the adsorption of ethanol and associated oxygenates, such as 2,3-butanediol, with a mobile phase desorbent selected from the group consisting of methanol, ethanol, propanol, and methyl tertiary butyl ether. The process is useful for removing water from dilute aqueous mixtures of organic compounds comprising ethanol in dilute concentration in water and produced by fermentation, biomass extraction, biocatalytic and enzymatic processes which are not economically recoverable by conventional distillation methods.
摘要翻译： 公开了一种用于在衍生自生物发酵过程的有机化合物存在下从乙醇和相关含氧化合物的稀释混合物中分离乙醇相关氧化物的方法和吸附剂。 在预处理之后，在模拟移动床吸附系统中进行分离，所述吸附系统使用包含氟化碳的固定相吸附剂或选择性地用于吸附乙醇和相关氧化物如2,3-丁二醇的改性C18硅胶与流动相 选自甲醇，乙醇，丙醇和甲基叔丁基醚的解吸剂。 该方法可用于从含水稀释浓度的乙醇的有机化合物的稀释含水混合物中除去水，并通过发酵，生物提取，生物催化和酶法，通过常规蒸馏方法经济可回收而产生。
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2.发明申请PROCESS AND ADSORBENT FOR SEPARATING ETHANOL AND ASSOCIATED OXYGENATES FROM A BIOFERMENTATION SYSTEM 有权从生物系统分离乙醇和相关氧化剂的方法和吸附剂公开(公告)号：US20130317260A1
公开(公告)日：2013-11-28
申请号：US13478160
申请日：2012-05-23
IPC分类号： C07C29/76
CPC分类号： C07C29/76 , C07C29/80 , Y02E50/17 , Y02E50/343 , C07C31/08 , C07C31/207
摘要： Disclosed is a process and an adsorbent for the separation of ethanol associated oxygenates from a dilute mixture of ethanol and associated oxygenates in water in the presence of organic compounds derived from a biofermentation process. After pretreatment, the separation is carried out in a simulated moving bed adsorption system employing an stationary phase adsorbent comprising fluorinated carbon or modified C18 silica gel selective for the adsorption of ethanol and associated oxygenates, such as 2,3-butanediol, with a mobile phase desorbent selected from the group consisting of methanol, ethanol, propanol, and methyl tertiary butyl ether. The process is useful for removing water from dilute aqueous mixtures of organic compounds comprising ethanol in dilute concentration in water and produced by fermentation, biomass extraction, biocatalytic and enzymatic processes which are not economically recoverable by conventional distillation methods.
摘要翻译： 公开了一种用于在衍生自生物发酵过程的有机化合物存在下从乙醇和相关含氧化合物的稀释混合物中分离乙醇相关氧化物的方法和吸附剂。 在预处理之后，在模拟移动床吸附系统中进行分离，所述吸附系统使用包含氟化碳的固定相吸附剂或选择性地用于吸附乙醇和相关氧化物如2,3-丁二醇的改性C18硅胶与流动相 选自甲醇，乙醇，丙醇和甲基叔丁基醚的解吸剂。 该方法可用于从含水稀释浓度的乙醇的有机化合物的稀释含水混合物中除去水，并通过发酵，生物提取，生物催化和酶法，通过常规蒸馏方法经济可回收而产生。
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3.发明申请PROCESS FOR PRODUCING CHEMICALS USING MICROBIAL FERMENTATION OF SUBSTRATES COMPRISING CARBON MONOXIDE 审中-公开使用包含一氧化碳的基材的微生物发酵生产化学品的方法公开(公告)号：US20120045807A1
公开(公告)日：2012-02-23
申请号：US13212891
申请日：2011-08-18
摘要： A process for converting a substrate such as carbon monoxide to useful chemicals has been developed. The process involves providing a substrate comprising CO to a bioreactor which contains a culture of one or more micro-organisms and anaerobically fermenting the substrate to produce 2,3-butanediol (BDO). The BDO is next converted to one or more of butane, butadiene and/or methyl ethyl ketone which in turn can be converted to other compounds. The source of the CO can be an industrial process such as the ferrous metal products manufacturing. The microorganism can be Clostridium autoethanogenum, Clostridium ljundahlii or Clostridium ragsdalei.
摘要翻译： 已经开发了用于将诸如一氧化碳的底物转化为有用化学品的方法。 该方法包括向生物反应器提供包含CO的底物，其含有一种或多种微生物的培养物，并且无氧发酵底物以产生2,3-丁二醇（BDO）。 接下来将BDO转化成丁烷，丁二烯和/或甲基乙基酮中的一种或多种，其又可以转化为其它化合物。 CO的来源可以是工业过程，如黑色金属产品制造。 微生物可以是自动乙醇梭菌，Clostridium ljundahlii或Clostridium ragsdalei。
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