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1.发明授权Fast-drying aqueous compositions with hollow particle binders and traffic paints made therewith 有权具有中空颗粒粘合剂和交通漆的快干水性组合物公开(公告)号：US07645815B2
公开(公告)日：2010-01-12
申请号：US12008003
申请日：2008-01-08
IPC分类号： F21V7/22
CPC分类号： C09D133/08 , C08L2207/53 , C09D5/004 , C09D7/68 , C09D7/70
摘要： The present invention provides fast-drying aqueous compositions that lower the cost of making roadway markings without impairing the quality or appearance of the markings made therewith. The aqueous compositions comprise one or more hollow core binder having an average particle size of from 200 to 500 nanometers (nm), preferably from 300 to 470 nm, and made of a first polymer having a glass transition temperature (Tg) of 50° C. or more and containing one or more void, the first polymer being substantially encapsulated by one or more second polymer having a Tg of −30° C. or more, preferably, −20° C. or more. Fast-drying aqueous compositions may be one component or two component compositions. One component compositions comprise one or more volatile base, one or more polyfunctional amine, and one or more hollow core binder with a second polymer chosen from, for example, an anionically stabilized emulsion polymer, a polyamine functional polymer, a polymer having strong pendant cationic groups containing and mixtures thereof. The polyfunctional amine can be part of the hollow core binder. Two component compositions comprise one or more aqueous hollow core binder and an absorber component. The present invention also provides coatings and roadway markings made from the fast-drying aqueous compositions.
摘要翻译： 本发明提供了快速干燥的含水组合物，其降低了制作道路标记的成本，而不损害由此制成的标记的质量或外观。 含水组合物包含平均粒径为200-500纳米（nm），优选为300-470nm的一种或多种中空芯粘合剂，并由玻璃化转变温度（Tg）为50℃的第一聚合物制成 或更多且含有一个或多个空隙的第一聚合物，所述第一聚合物基本上被Tg为-30℃或更高，优选-20℃或更高的一种或多种第二聚合物包封。 快干水性组合物可以是一种组分或两种组分。 一种组分组合物包含一种或多种挥发性碱，一种或多种多官能胺，以及一种或多种中空芯粘合剂，其具有第二种聚合物，其选自例如阴离子稳定的乳液聚合物，多胺官能聚合物，具有强阳离子阳离子 基团和其混合物。 多官能胺可以是中空芯粘合剂的一部分。 双组分组合物包含一种或多种水性中空芯粘合剂和吸收剂组分。 本发明还提供了由快干水性组合物制成的涂层和道路标记。
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2.发明授权Methods for improving the dirt-resistance and gloss retention of a coalescent-free coating composition 失效提高无聚结剂涂料组合物的耐污性和光泽保留性的方法公开(公告)号：US06303186B1
公开(公告)日：2001-10-16
申请号：US08467631
申请日：1995-06-06
IPC分类号： B05D500
CPC分类号： C09D133/062
摘要： A method for improving the dirt pick-up resistance and the retention of gloss on exposure to light of a dried coating formed from a coalescent-free aqueous coating composition is provided. The coalescent-free composition composition contains an aqueous emulsion-polymerized polymeric binder having a glass transition temperature from about −35 C. to about +25 C. with from about 2% to about 20%, by weight based on the weight of the polymeric binder, of at least one copolymerized ethylenically-unsaturated active methylene monomer.
摘要翻译： 提供了一种用于提高由无聚结剂水性涂料组合物形成的干燥涂层的耐污垢性和保持光泽的方法。 无聚结剂组合物组合物含有玻璃化转变温度为约-35℃至约+ 25℃的水乳液聚合的聚合物粘合剂，约2％至约20％，基于聚合物的重量 粘合剂，至少一种共聚的烯属不饱和活性亚甲基单体。
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公开(公告)号：US07893149B2
公开(公告)日：2011-02-22
申请号：US12004301
申请日：2007-12-20
CPC分类号： C08F275/00 , B60R13/08 , C08F220/14 , C08F220/18 , C08F230/02 , C09D143/02
摘要： A liquid applied sound dampening composition with a binder having from 0.03% to 3% phosphorus present as copolymerized pendant phosphorus acid groups.
摘要翻译： 一种具有0.03％至3％磷的粘合剂的液体防声组合物作为共聚侧链酸基团存在。
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公开(公告)号：US07235595B2
公开(公告)日：2007-06-26
申请号：US10910212
申请日：2004-08-03
IPC分类号： F21V7/22
CPC分类号： C09D5/004 , C08F265/04 , C08F265/06 , C08F291/00 , C09D151/003 , C08F212/08 , C08F2/22 , C08L2666/04
摘要： An aqueous traffic paint including hard-soft polymer particles, polyfunctional amine, and volatile base is provided. The hard-soft polymer particles, which contain soft polymer and hard polymer, have a hydrophobicity characterized by a Hansch parameter of at least 3. Also provided is a method of producing a traffic marking on a road surface using the aqueous paint. The aqueous traffic paint is suitable for application to road surfaces, including oily road surfaces, and may be applied at temperatures below 15° C.
摘要翻译： 提供了包含硬质聚合物颗粒，多官能胺和挥发性碱的含水交通漆。 包含软聚合物和硬聚合物的硬质聚合物颗粒具有由Hansch参数至少为3表征的疏水性。还提供了使用水性涂料在路面上生成交通标记的方法。 含水交通漆适用于路面，包括油性路面，可在低于15°C的温度下使用
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5.发明授权Method for improving the dirt-resistance and gloss retention of a coalescent-free coating 失效提高无聚结涂层的耐污性和光泽保留性的方法公开(公告)号：US06303188B1
公开(公告)日：2001-10-16
申请号：US08272438
申请日：1994-07-08
IPC分类号： B05D500
CPC分类号： C09D133/062
摘要： A method for improving the dirt pick-up resistance and the retention of gloss on exposure to light of a dried coating formed from a coalescent-free aqueous coating composition is provided. The coalescent-free composition composition contains an aqueous emulsion-polymerized polymeric binder having a glass transition temperature from about −35 C. to about +25 C. with from about 2% to about 20%, by weight based on the weight of the polymeric binder, of at least one copolymerized ethylenically-unsaturated active methylene monomer.
摘要翻译： 提供了一种用于提高由无聚结剂水性涂料组合物形成的干燥涂层的耐污垢性和保持光泽的方法。 无聚结剂组合物组合物含有玻璃化转变温度为约-35℃至约+ 25℃的水乳液聚合的聚合物粘合剂，约2％至约20％，基于聚合物的重量 粘合剂，至少一种共聚的烯属不饱和活性亚甲基单体。
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公开(公告)号：US20080153969A1
公开(公告)日：2008-06-26
申请号：US12004301
申请日：2007-12-20
IPC分类号： C08L85/02
CPC分类号： C08F275/00 , B60R13/08 , C08F220/14 , C08F220/18 , C08F230/02 , C09D143/02
摘要： A liquid applied sound dampening composition with a binder having from 0.03% to 3% phosphorus present as copolymerized pendant phosphorus acid groups
摘要翻译： 一种具有0.03％至3％磷的粘合剂的液体防声组合物作为共聚侧链酸基团存在
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7.发明申请High PVC Fast-Drying Aqueous Binder Compositions With Small Particle Binders And Traffic Markings Made Therewith 审中-公开高PVC快干干燥水性粘合剂组合物与小颗粒粘合剂和交通标记公开(公告)号：US20110136936A1
公开(公告)日：2011-06-09
申请号：US12956001
申请日：2010-11-30
CPC分类号： C09D5/004 , C09D5/02 , C09D133/16 , C08L33/14
摘要： The present invention provides fast dry binder compositions comprising one or more anionically stabilized emulsion polymer having a weight average particle size of from 100 to 165 nm, one or more polyamine, one or more volatile base and one or more filler, extender and/or pigment in a composition having a % PVC of from 63 to 80. The invention provides surprisingly stable fast dry binder compositions for such a high extender or filler loading and the compositions dry far faster than binders made with waterborne polymers having a larger particle size. The invention provides high performance traffic paints at a reduced cost in use and coated substrates, such as traffic markings or exterior insulation finishes (EIFS).
摘要翻译： 本发明提供快速干粘合剂组合物，其包含一种或多种重均粒径为100至165nm的阴离子稳定的乳液聚合物，一种或多种多胺，一种或多种挥发性碱和一种或多种填料，增量剂和/或颜料 在具有63至80的％PVC的组合物中。本发明提供令人惊奇的稳定的快速干燥粘合剂组合物用于这种高增量剂或填料负载，并且组合物比具有较大粒度的水性聚合物制备的粘合剂干得更快。 本发明以降低的使用成本和涂覆的基底（例如交通标记或外部绝缘整理剂（EIFS））提供高性能交通涂料。
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8.发明申请Fast-drying aqueous compositions with hollow particle binders and traffic paints made therewith 有权具有中空颗粒粘合剂和交通漆的快干水性组合物公开(公告)号：US20080171810A1
公开(公告)日：2008-07-17
申请号：US12008003
申请日：2008-01-08
IPC分类号： C08F283/00
CPC分类号： C09D133/08 , C08L2207/53 , C09D5/004 , C09D7/68 , C09D7/70
摘要： The present invention provides fast-drying aqueous compositions that lower the cost of making roadway markings without impairing the quality or appearance of the markings made therewith. The aqueous compositions comprise one or more hollow core binder having an average particle size of from 200 to 500 nanometers (nm), preferably from 300 to 470 nm, and made of a first polymer having a glass transition temperature (Tg) of 50° C. or more and containing one or more void, the first polymer being substantially encapsulated by one or more second polymer having a Tg of −30° C. or more, preferably, −20° C. or more. Fast-drying aqueous compositions may be one component or two component compositions. One component compositions comprise one or more volatile base, one or more polyfunctional amine, and one or more hollow core binder with a second polymer chosen from, for example, an anionically stabilized emulsion polymer, a polyamine functional polymer, a polymer having strong pendant cationic groups containing and mixtures thereof. The polyfunctional amine can be part of the hollow core binder. Two component compositions comprise one or more aqueous hollow core binder and an absorber component. The present invention also provides coatings and roadway markings made from the fast-drying aqueous compositions.
摘要翻译： 本发明提供了快速干燥的含水组合物，其降低了制作道路标记的成本，而不损害由此制成的标记的质量或外观。 含水组合物包含平均粒径为200-500纳米（nm），优选为300-470nm的一种或多种中空芯粘合剂，并由玻璃化转变温度（Tg）为50℃的第一聚合物制成 或更多且含有一个或多个空隙的第一聚合物，所述第一聚合物基本上被Tg为-30℃或更高，优选-20℃或更高的一种或多种第二聚合物包封。 快干水性组合物可以是一种组分或两种组分。 一种组分组合物包含一种或多种挥发性碱，一种或多种多官能胺，以及一种或多种中空芯粘合剂，其具有第二种聚合物，其选自例如阴离子稳定的乳液聚合物，多胺官能聚合物，具有强阳离子阳离子 基团和其混合物。 多官能胺可以是中空芯粘合剂的一部分。 双组分组合物包含一种或多种水性中空芯粘合剂和吸收剂组分。 本发明还提供了由快干水性组合物制成的涂层和道路标记。
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