摘要:
A method and system for solid reactant based thermochemical process are disclosed. A metal oxide or solid reactant having a crystal structure associated with a characteristic state of high temperature engendering creation of oxygen vacancies is identified. The metal oxide is heated to the high temperature corresponding to the state of oxygen vacancies. Subsequently, the solid reactant is cooled to a temperature conducive to water splitting reaction. Steam is then introduced to react with the solid reactant to thereby re-oxidize the solid reactant producing hydrogen gas. Finally, the re-oxidized solid reactant is reheated to a reduction temperature completing the process of solid based reactant thermochemical solar power generation.The system includes one or more processors adapted to configure a solar absorption system, a thermochemical system, a gas storage system for storing product gases and a power generation system for processing the stored product gases into electrical power.
摘要:
Solar receivers which produce heat at very high temperatures (in excess of 1000° C.) are described herein. The receiver produces the high temperature heat and radiates the heat to a containment element (e.g., pipe) that contains a heat transfer fluid which absorbs the heat. The fluid is preferably a material which is thermally and chemically stable at the temperatures involved. The heat transfer fluid absorbs the heat and can deliver it to a reactor system to drive an endothermic reaction, such as thermochemical water splitting, CO2 capture, and/or syngas production. Alternatively, the heat can be used to directly generate electricity through a high temperature heat engine such as a Brayton or combined Brayton+Rankine cycle.