公开(公告)号：US08921584B2

公开(公告)日：2014-12-30

申请号：US13512845

申请日：2010-12-03

申请人： Atsuro Yoneda ,  Makoto Saito ,  Aki Tsukajima ,  Daisuke Michitaka ,  Mitsuaki Makino

发明人： Atsuro Yoneda ,  Makoto Saito ,  Aki Tsukajima ,  Daisuke Michitaka ,  Mitsuaki Makino

IPC分类号： C07C43/188 ,  C07C43/178 ,  C11D3/37 ,  C08F216/14 ,  C07C217/28 ,  C08F216/12 ,  C08F290/06 ,  C07D303/24 ,  C07D303/22 ,  C07D303/20 ,  C02F1/28

CPC分类号： C07C43/178 ,  C02F1/285 ,  C07C43/188 ,  C07C217/28 ,  C07D303/20 ,  C07D303/22 ,  C07D303/24 ,  C08F216/125 ,  C08F216/1416 ,  C08F290/062 ,  C11D3/3746 ,  C11D3/3757

摘要： A composition is provided that contains an intermediate for a water-soluble monomer, wherein this intermediate is suitable for producing a water-soluble polyalkylene glycol-type monomer that has a polymerizable terminal double bond, and suitable for the production of water-soluble polymer, and moreover allows the high-yield production of water-soluble polymer. A process of producing this composition and a water-soluble monomer-containing composition obtained therefrom are also provided. A water-soluble monomer is also provided that can be used as a starting material for a water-soluble polymer that even at high hardnesses exhibits an excellent capacity to capture metal ions such as the calcium ion and magnesium ion, an excellent anti-gelation performance, an excellent anti-soil redeposition performance, a better anti-dye transfer performance than in the past, and also an excellent compatibility with surfactants. A production process is also provided that can produce such a water-soluble monomer at higher yields and higher selectivities (higher purities) than in the past. A composition containing an intermediate for a water-soluble monomer, that contains a compound (A) having a specified structure and that contains a specified amount of a compound (B) having a specified structure. Also, a water-soluble monomer having a specified structure is provided.

摘要翻译： 提供了含有水溶性单体中间体的组合物，其中该中间体适用于生产具有可聚合端基双键的水溶性聚亚烷基二醇型单体，适用于生产水溶性聚合物， 而且允许高产量生产水溶性聚合物。 还提供了制备该组合物的方法和由其获得的含水溶性单体的组合物。 还提供了可用作水溶性聚合物的起始材料的水溶性单体，即使在高硬度下也显示出优异的俘获金属离子的能力，例如钙离子和镁离子，优异的抗胶凝性能 ，优异的抗土壤再沉积性能，比过去更好的抗染料转移性能，以及与表面活性剂的优异相容性。 还提供了一种生产方法，其可以以比过去更高的产率和更高的选择性（更高的纯度）生产这种水溶性单体。 含有水溶性单体中间体的组合物，其含有具有规定结构且含有规定量的具有规定结构的化合物（B）的化合物（A）。 另外，提供具有特定结构的水溶性单体。

公开(公告)号：US08916678B2

公开(公告)日：2014-12-23

申请号：US12088629

申请日：2006-09-26

申请人： Atsuro Yoneda ,  Akiko Hemmi

发明人： Atsuro Yoneda ,  Akiko Hemmi

IPC分类号： C08G65/04 ,  C08L51/08 ,  C11D3/37 ,  B01F17/00 ,  C08F290/06 ,  C04B24/26 ,  C11D3/00 ,  C04B24/16 ,  C08F283/06 ,  C04B24/32 ,  C08G65/26

CPC分类号： C08F283/065 ,  B01F17/0028 ,  C04B24/161 ,  C04B24/2605 ,  C04B24/32 ,  C08F290/06 ,  C08F290/062 ,  C08G65/2609 ,  C08L51/08 ,  C11D3/0036 ,  C11D3/3746 ,  C08L2666/02

摘要： To provide: a monomer having a polyalkylene glycol chain preferably used in various industrial applications such as detergent builder compositions for clothes and bodies, water-treatment agents, and pigment dispersants; and a polyalkylene glycol polymer using such a monomer as a raw material. A polyalkylene glycol monomer having a polymerizable double bond and a polyalkylene glycol chain, wherein the polyalkylene glycol monomer has a hydrophobic part in the polyalkylene glycol chain and/or at a terminal of the chain, and the polymerizable double bond is derived from allyl glycidyl ether, and a polyalkylene glycol monomer having a monomer unit derived from the above-mentioned polyalkylene glycol monomer, wherein the polyalkylene glycol polymer is a polyalkylene glycol polymer having a carboxylic acid group and/or a sulfonic acid group.

摘要翻译： 提供：具有优选用于各种工业应用的聚亚烷基二醇链的单体，例如用于衣服和身体的洗涤剂助洗剂组合物，水处理剂和颜料分散剂; 和使用这种单体作为原料的聚亚烷基二醇聚合物。 具有可聚合双键和聚亚烷基二醇链的聚亚烷基二醇单体，其中聚亚烷基二醇单体在聚亚烷基二醇链中和/或末端具有疏水部分，并且可聚合双键衍生自烯丙基缩水甘油醚 和具有源自上述聚亚烷基二醇单体的单体单元的聚亚烷基二醇单体，其中聚亚烷基二醇聚合物是具有羧酸基和/或磺酸基的聚亚烷基二醇聚合物。

公开(公告)号：US08450262B2

公开(公告)日：2013-05-28

申请号：US13061532

申请日：2009-09-01

申请人： Jeffrey Scott Dupont ,  Atsuro Yoneda ,  Akiko Hemmi

发明人： Jeffrey Scott Dupont ,  Atsuro Yoneda ,  Akiko Hemmi

IPC分类号： C11D1/12 ,  C11D3/3707 ,  C11D3/3757

CPC分类号： C11D3/3757 ,  C08F220/10 ,  C08F220/26 ,  C08F222/10

摘要： [Objective] This invention is to provide a novel copolymer suitably applicable to a detergent composition having an excellent precipitation inhibitory ability and showing a good washing effect even under severe conditions of washing with water used to take Japanese bath. [Solution] A laundry detergent or cleaning composition which comprises a hydrophobic group-containing copolymer characterized by having 1 wt % or more but below 50 wt % of a structural unit (a) derived from at least one kind of monomer (A) selected from ether bond-containing monomers.

摘要翻译： [目的]本发明提供一种适用于具有优异的沉淀抑制能力的洗涤剂组合物的新型共聚物，即使在用于日本浴的水洗涤的苛刻条件下也显示出良好的洗涤效果。 [解决方案]一种衣物洗涤剂或清洁组合物，其包含含疏水基团的共聚物，其特征在于具有1重量％以上但低于50重量％的衍生自选自以下的至少一种单体（A）的结构单元（a）： 含醚键的单体。

公开(公告)号：US20120157655A1

公开(公告)日：2012-06-21

申请号：US12971416

申请日：2010-12-17

申请人： Atsuro Yoneda ,  Akiko Hemmi ,  Sachiko Nakanishi ,  Daisuke Michitaka

发明人： Atsuro Yoneda ,  Akiko Hemmi ,  Sachiko Nakanishi ,  Daisuke Michitaka

IPC分类号： C08G63/66

CPC分类号： C11D3/3707 ,  C08F216/1416 ,  C08F220/06

摘要： The present invention has an object to provide a polyalkylene glycol-based polymer having high anti-soil redeposition ability in washing treatment and having high compatibility with surfactants. The polyalkylene glycol-based polymer includes: a structure unit (a) derived from a polyalkylene glycol-based monomer (A) of a specific structure, and a structure unit (b) derived from a carboxyl group-containing monomer (B) at specific ratios.

摘要翻译： 本发明的目的是提供一种在洗涤处理中具有高抗污垢再沉积能力并且与表面活性剂具有高相容性的聚亚烷基二醇类聚合物。 聚亚烷基二醇类聚合物包括：由特定结构的聚亚烷基二醇类单体（A）衍生的结构单元（a）和由特定结构的含羧基单体（B）衍生的结构单元（b） 比率。

公开(公告)号：US20110251115A1

公开(公告)日：2011-10-13

申请号：US13061532

申请日：2009-09-01

申请人： Jeffrey Scott Dupont ,  Atsuro Yoneda ,  Akiko Hemmi

发明人： Jeffrey Scott Dupont ,  Atsuro Yoneda ,  Akiko Hemmi

IPC分类号： C11D3/37 ,  B08B1/00 ,  C08F220/06 ,  C08F216/18 ,  C11D3/60 ,  C11D17/00

CPC分类号： C11D3/3757 ,  C08F220/10 ,  C08F220/26 ,  C08F222/10

摘要： [Objective] This invention is to provide a novel copolymer suitably applicable to a detergent composition having an excellent precipitation inhibitory ability and showing a good washing effect even under severe conditions of washing with water used to take Japanese bath.[Solution] A laundry detergent or cleaning composition which comprises a hydrophobic group-containing copolymer characterized by having 1 wt % or more but below 50 wt % of a structural unit (a) derived from at least one kind of monomer (A) selected from ether bond-containing monomers.

摘要翻译： [目的]本发明提供一种适用于具有优异的沉淀抑制能力的洗涤剂组合物的新型共聚物，即使在用于日本浴的水洗涤的苛刻条件下也显示出良好的洗涤效果。 [解决方案]一种衣物洗涤剂或清洁组合物，其包含含疏水基团的共聚物，其特征在于具有1重量％以上但低于50重量％的衍生自选自以下的至少一种单体（A）的结构单元（a）： 含醚键的单体。

公开(公告)号：US07285611B2

公开(公告)日：2007-10-23

申请号：US11518654

申请日：2006-09-11

申请人： Atsuro Yoneda ,  Takahiro Tsumori ,  Yoshikazu Fujii ,  Shigeru Yamaguchi

发明人： Atsuro Yoneda ,  Takahiro Tsumori ,  Yoshikazu Fujii ,  Shigeru Yamaguchi

IPC分类号： C08F2/00

CPC分类号： C08F20/06 ,  C08F290/062

摘要： This invention concerns a (meth)acrylic acid type polymer, wherein the value S representing the quantity of an sulfur element introduced which is defined by the formula, S=(quantity of S contained in polymer)/(total quantity of S)×100, is not less than 35. This (meth)acrylic acid type polymer is a water-soluble polymer of a low molecular weight which has only a small impurity content, entails no precipitation of an impurity during the preservation at a low temperature, and excels in dispersibility, chelating ability, and an anti-gelling property.

摘要翻译： 本发明涉及一种（甲基）丙烯酸型聚合物，其中代表由式S =（聚合物中所含的S的量）/（S的总量）×100所定义的引入的硫元素的量的值S， 不小于35.这种（甲基）丙烯酸类聚合物是低分子量的水溶性聚合物，其杂质含量小，在低温保存期间不会产生杂质沉淀，并且在 分散性，螯合能力和抗胶凝性。

公开(公告)号：US08076434B1

公开(公告)日：2011-12-13

申请号：US12976242

申请日：2010-12-22

申请人： Atsuro Yoneda ,  Daisuke Michitaka

发明人： Atsuro Yoneda ,  Daisuke Michitaka

IPC分类号： C08F26/02

CPC分类号： C08F220/06 ,  C08F220/36 ,  C11D3/3796

摘要： The present invention has an object to provide an amphoteric polymer having high anti-soil redeposition ability and solubility with surfactants, and a process for producing the same. The amphoteric polymer includes: a structure unit (a) derived from a cationic group-containing monomer (A); and a structure unit (b) derived from a carboxyl group-containing monomer (B). The structure unit (a) is present at a level of 1 to 99% by mass based on 100% by mass of all structure units derived from all monomers in the amphoteric polymer, and the structure unit (b) is present at a level of 1 to 99% by mass based on 100% by mass of all the structure units derived from all the monomers in the amphoteric polymer.

摘要翻译： 本发明的目的是提供一种具有高抗污垢再沉积能力和与表面活性剂的溶解性的两性聚合物及其制造方法。 两性聚合物包括：衍生自含阳离子基团的单体（A）的结构单元（a）; 和由含羧基的单体（B）衍生的结构单元（b）。 相对于两性聚合物中的全部单体衍生的全部结构单元100质量％，结构单元（a）的含量为1〜99质量％，结构单元（b）的含量为 相对于两性聚合物中全部的单体衍生的全部结构单元100质量％，为1〜99质量％。

公开(公告)号：US20110245130A1

公开(公告)日：2011-10-06

申请号：US13061527

申请日：2009-09-01

申请人： Jeffrey Scott Dupont ,  Atsuro Yoneda ,  Daisuke Michitaka

发明人： Jeffrey Scott Dupont ,  Atsuro Yoneda ,  Daisuke Michitaka

IPC分类号： C11D3/60 ,  C11D17/00

CPC分类号： C08F283/06 ,  A61K8/91 ,  A61Q5/02 ,  A61Q19/10 ,  C08L51/08 ,  C08L53/00 ,  C11D3/2017 ,  C11D3/2079 ,  C11D3/2093 ,  C11D3/3757 ,  C11D3/378 ,  C11D3/3784 ,  C11D3/3788 ,  C11D17/049 ,  C08L2666/02 ,  C08L2666/24

摘要： [Objective] The objective is to provide a polymer composition having an improved lime soap dispersibility from the prior art in the case of detergent applications and process for the production of it.[Solution] A laundry detergent or cleaning composition, which comprises a polymer composition obtainable by carrying out polymerization reaction of a polyoxyalkylene compound and an acid group-containing unsaturated monomer in the presence of a polymerization initiator, the polyoxyalkylene compound having at least one of aryl group with 8 or more carbon atoms, alkyl group having 8 or more carbon atoms and alkenyl group of 8 or more carbon atoms and oxyalkylene group, a content of an oxyalkylene-origin structure per mol of the polyoxyalkylene compound being in the range of 10-100 mol; a ratio by weight of a polyoxyalkylene compound-origin structure to the acid group-containing unsaturated monomer-origin structure being in the range of 80:20 to 50:50 (provided 80:20 not included), and the composition containing 0.3-20 parts by weight of at least one compound selected from the following compounds 1-3 per 100 parts by weight of the acid group-containing unsaturated monomer. 1-3 per 100 parts by weight of acid group-containing unsaturated monomer.

摘要翻译： [目的]本发明的目的是提供一种在洗涤剂用途及其生产方法中具有改进的来自现有技术的钙皂分散性的聚合物组合物。 [解决方案]一种衣物洗涤剂或清洁组合物，其包含通过在聚合引发剂存在下进行聚氧化烯化合物和含酸基的不饱和单体的聚合反应获得的聚合物组合物，所述聚氧化烯化合物具有至少一个芳基 具有8个或更多个碳原子的烷基，具有8个或更多个碳原子的烷基和8个或更多个碳原子的链烯基和氧化烯基，每摩尔聚氧化烯化合物的氧亚烷基起始结构的含量为10- 100摩尔; 聚氧化烯化合物起始结构与含酸基的不饱和单体来源结构的重量比在80:20至50:50（不包括80:20）的范围内，组合物含有0.3-20 重量份的至少一种选自以下化合物1-3的化合物/ 100重量份的含酸基的不饱和单体。 1-3每100重量份含酸基的不饱和单体。

公开(公告)号：US20080227949A1

公开(公告)日：2008-09-18

申请号：US12088646

申请日：2006-09-26

申请人： Atsuro Yoneda ,  Akiko Hemmi

发明人： Atsuro Yoneda ,  Akiko Hemmi

IPC分类号： C08G65/02

CPC分类号： C07C305/10 ,  B01F17/0028 ,  C08G65/334 ,  C08G65/335 ,  C08L71/02 ,  C11D3/3707

摘要： To provide: a hydrophilized polyalkylene glycol which is preferably used in various applications, and sufficiently exhibits high performances such as detergency; a production method thereof; and an application thereof. A hydrophilized polyalkylene glycol represented by the following formula (1): in the formula, X1 and Y1 being different from each other, and each representing a hydrogen atom, —SO3M, —S—CH2—CH2—SO3M, —PO3M2, or —S—(CH2)t—COOM; R1 to R6 representing a hydrogen atom or an alkyl group; R7 representing a hydrogen atom, an alkyl group, an aryl group, a polyhydric alcohol group, Z1 or Z2 represented by the following formula (2-2) or (2-2); p, q, r, and s representing a valency; in the formula, X2 and Y2 being different from each other, and each representing a hydrogen atom, —SO3M, —S—CH2—CH2—SO3M, —PO3M2, or —S—(CH2)t—COOM; R8 and R9 representing a hydrogen atom or an alkyl group; and R10 representing an alkyl group or an aryl group.

摘要翻译： 提供：亲水化的聚亚烷基二醇，其优选用于各种应用，并且充分显示出诸如去污力的高性能; 其制造方法; 及其应用。 由下式（1）表示的亲水化聚亚烷基二醇：在式中，X 1和Y 1彼此不同，并且各自表示氢原子， SO 3 M，-S-CH 2 -CH 2 -SO 3 M，-PO 3 或者-S-（CH 2）2 -COOM;或者-S-（CH 2）2 -COOM; 表示氢原子或烷基的R 1至R 6; R 7表示由下列各项表示的氢原子，烷基，芳基，多元醇基，Z 1或Z 2， 式（2-2）或（2-2）; p，q，r和s表示化合价; 在式中，X 2和Y 2彼此不同，并且各自表示氢原子，-SO 3 M，-S -CH 2 CH 2，-SO 3 M，-PO 3，M 2，...，N 2 >或-S-（CH 2）2 -COOM; R 8和R 9代表氢原子或烷基; 和R 10代表烷基或芳基。

公开(公告)号：US20070049710A1

公开(公告)日：2007-03-01

申请号：US11512284

申请日：2006-08-30

申请人： Hidekazu Kozuki ,  Noboru Sakamoto ,  Takahiro Tsumori ,  Atsuro Yoneda ,  Kaori Nakatani ,  Hideo Wakami

发明人： Hidekazu Kozuki ,  Noboru Sakamoto ,  Takahiro Tsumori ,  Atsuro Yoneda ,  Kaori Nakatani ,  Hideo Wakami

IPC分类号： C08F2/00

CPC分类号： C08F2/00 ,  B01J14/00 ,  B01J19/0013 ,  B01J2219/0011 ,  B01J2219/00123 ,  C08F220/06

摘要： To provide a continuous production method for producing a water-soluble polymer with a narrow molecular weight distribution with high efficiency. A continuous production method of a water-soluble polymer, comprising the steps of: circulating a circulation liquid containing a monomer having a polymerizable unsaturated bond through a reaction apparatus: having a tank and a circulation line comprising a piping circulating outside the tank, and thereby producing a water-soluble polymer continuously; and discharging part of the circulation liquid from a discharge line, wherein the circulation line is provided with a cooling device at least at one position.

摘要翻译： 提供具有高效率的分子量分布窄的水溶性聚合物的连续制造方法。 一种水溶性聚合物的连续制造方法，其特征在于，包括以下步骤：使具有聚合性不饱和键的单体的循环液通过反应装置循环，所述反应装置具有罐和循环管线，所述循环管路包括在罐外循环的管道， 连续生产水溶性聚合物; 以及从排出管排出所述循环液的一部分，其中所述循环管线至少在一个位置处设置有冷却装置。