Method for photolytic liquid phase synthesis of silicon and germanium
nanocrystalline materials
    1.
    发明授权
    Method for photolytic liquid phase synthesis of silicon and germanium nanocrystalline materials 失效
    硅和锗纳米晶体材料的光解液相合成方法

    公开(公告)号:US5850064A

    公开(公告)日:1998-12-15

    申请号:US840301

    申请日:1997-04-11

    摘要: A method is described for the liquid phase synthesis of particles. The particles are composed of silicon or germanium and are optionally produced at sizes such that the particles exhibit quantum size effects. The particles are produced from an organometallic (tetra-organosilicon or tetra-organogermanium) precursors which is dissolved in a solvent that transmits a wavelength of light that photolyzes the precursor. The reaction is carried out under an inert atmosphere. A passivating agent is added to arrest particle growth and impart solubility to the particle. Optionally, a dopant is incorporated into the particle in the course of production so as to modify the electronic properties of the semiconductor particle.

    摘要翻译: 描述了用于液相合成颗粒的方法。 颗粒由硅或锗组成,并且任选地以使得颗粒显示量子尺寸效应的尺寸产生。 颗粒由有机金属(四有机硅或四有机锗)前体制成,其前体溶解在透过光前驱体的光的波长的溶剂中。 反应在惰性气氛下进行。 加入钝化剂以阻止颗粒生长并赋予颗粒溶解性。 任选地,在生产过程中将掺杂剂掺入颗粒中以改变半导体颗粒的电子性质。

    Narrow size distribution silicon and germanium nanocrystals
    2.
    发明授权
    Narrow size distribution silicon and germanium nanocrystals 失效
    窄尺寸分布硅和锗纳米晶体

    公开(公告)号:US06268041B1

    公开(公告)日:2001-07-31

    申请号:US09211651

    申请日:1998-12-15

    IPC分类号: B32B516

    摘要: A method is described for the liquid phase synthesis of particles. The particles are composed of silicon or germanium and are optionally produced at sizes such that the particles exhibit quantum size effects. The particles are produced from an organometallic (tetra-organosilicon or tetra-organogermanium) precursors which is dissolved in a solvent that transmits a wavelength of light that photolyzes the precursor. The reaction is carried out under an inert atmosphere. A passivating agent is added to arrest particle growth and impart solubility to the particle. Optionally, a dopant is incorporated into the particle in the course of production so as to modify the electronic properties of the semiconductor particle.

    摘要翻译: 描述了用于液相合成颗粒的方法。 颗粒由硅或锗组成,并且任选地以使得颗粒显示量子尺寸效应的尺寸产生。 颗粒由有机金属(四有机硅或四有机锗)前体制成,其前体溶解在透过光前驱体的光的波长的溶剂中。 反应在惰性气氛下进行。 加入钝化剂以阻止颗粒生长并赋予颗粒溶解性。 任选地,在生产过程中将掺杂剂掺入颗粒中以改变半导体颗粒的电子性质。