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公开(公告)号：US20120302783A1
公开(公告)日：2012-11-29
申请号：US13437093
申请日：2012-04-02
申请人： Robert BAUMANN , Markus Christian Biel , Axel Franzke , Alfred Oftring , Friedhelm Teich , Paul Klingelhoefer , Marie Katrin Schröter
发明人： Robert BAUMANN , Markus Christian Biel , Axel Franzke , Alfred Oftring , Friedhelm Teich , Paul Klingelhoefer , Marie Katrin Schröter
IPC分类号： C07C227/02
CPC分类号： C07C227/02
摘要： What is proposed is a process for preparing aminopolycarboxylates proceeding from the corresponding polyalkanolamines by oxidative dehydrogenation in the presence of a catalyst comprising 1 to 90% by weight of copper, based on the total weight of the catalyst, using a base, which comprises first performing a partial conversion of the polyalkanolamine to a reaction mixture comprising the aminopolycarboxylate at a temperature in the range from 140 to 180° C. until at least 10 to 90 mol % of the polyalkanolamine has been depleted, and then continuing the conversion at elevated temperature.
摘要翻译： 提出的是一种制备在相应的聚链烷醇胺上通过氧化脱氢在催化剂存在下进行的氨基多羧酸盐的方法，所述催化剂包含1至90重量％的铜，基于催化剂的总重量，使用碱，其包括首先进行 在140〜180℃的温度范围内将聚链烷醇胺部分转化成含有氨基多羧酸盐的反应混合物，直到聚链烷醇胺的至少10〜90摩尔％已经耗尽，然后在升高的温度下继续转化。
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公开(公告)号：US20120245377A1
公开(公告)日：2012-09-27
申请号：US13513460
申请日：2010-11-30
IPC分类号： C07C263/04
CPC分类号： C07C263/04 , C07C265/14
摘要： A process is proposed for preparing isocyanates by thermally cleaving carbamates to obtain a carbamate cleavage gas comprising the corresponding isocyanate and the corresponding alcohol, which comprises quenching the carbamate cleavage gas in the presence of an ether which functions as an inhibitor for the reverse reaction of the isocyanate with the alcohol.
摘要翻译： 提出了通过热裂解氨基甲酸酯制备异氰酸酯以获得包含相应的异氰酸酯和相应的醇的氨基甲酸酯裂解气体的方法，该方法包括在醚的存在下猝灭氨基甲酸酯裂解气体，该醚用作反应的反应的抑制剂 异氰酸酯与醇。
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公开(公告)号：US08680333B2
公开(公告)日：2014-03-25
申请号：US13513752
申请日：2010-12-01
申请人： Axel Franzke , Torsten Mattke , Julia Leschinski , Radwan Abdallah , Michael Bock , Robert Baumann , Eckhard Stroefer
发明人： Axel Franzke , Torsten Mattke , Julia Leschinski , Radwan Abdallah , Michael Bock , Robert Baumann , Eckhard Stroefer
IPC分类号： C07C231/02 , C07C233/03
CPC分类号： C07C231/02 , C07C233/03 , C07C233/43
摘要： The invention relates to a process for the preparation of formamides by reacting aromatic amines with a formic acid ester in the presence of a catalyst, wherein the catalyst is a phosphorus-containing acid or a Lewis-acidic metal salt.
摘要翻译： 本发明涉及一种在催化剂存在下使芳族胺与甲酸酯反应制备甲酰胺的方法，其中催化剂是含磷酸或路易斯酸性金属盐。
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公开(公告)号：US08609894B2
公开(公告)日：2013-12-17
申请号：US13437093
申请日：2012-04-02
申请人： Robert Baumann , Markus Christian Biel , Axel Franzke , Alfred Oftring , Friedhelm Teich , Paul Klingelhoefer , Marie Katrin Schroeter
发明人： Robert Baumann , Markus Christian Biel , Axel Franzke , Alfred Oftring , Friedhelm Teich , Paul Klingelhoefer , Marie Katrin Schroeter
IPC分类号： C07C51/21
CPC分类号： C07C227/02
摘要： A process for preparing aminopolycarboxylates proceeding from the corresponding polyalkanolamines by oxidative dehydrogenation in the presence of a catalyst comprising 1 to 90% by weight of copper, based on the total weight of the catalyst, using a base, which comprises first performing a partial conversion of the polyalkanolamine to a reaction mixture comprising the aminopolycarboxylate at a temperature in the range from 140 to 180° C. until at least 10 to 90 mol% of the polyalkanolamine has been depleted, and then continuing the conversion at elevated temperature.
摘要翻译： 在催化剂存在下，通过氧化脱氢从相应的聚链烷醇胺制备氨基多羧酸盐的方法，所述催化剂包含1至90重量％的铜，基于催化剂的总重量，使用碱，其包括首先进行部分转化 将聚烷醇胺加入到包含氨基多羧酸盐的反应混合物中，温度范围为140-180℃，直到聚链烷醇胺的至少10至90摩尔％已经耗尽，然后在升高的温度下继续转化。
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5.发明申请HETEROGENEOUSLY CATALYZED CARBAMATE DISSOCIATION FOR SYNTHESIS OF ISOCYANATES OVER SOLID LEWIS ACIDS 审中-公开用于合成异柠檬酸盐的非均相催化的氨基甲酸酯脱水物公开(公告)号：US20110313192A1
公开(公告)日：2011-12-22
申请号：US13163928
申请日：2011-06-20
IPC分类号： C07C263/04
CPC分类号： C07C263/04 , C07C265/14
摘要： Proposed is a process for preparing isocyanates by dissociating the corresponding carbamates, which comprises dissociating the carbamates in the presence of a heterogeneous Lewis-acidic catalyst.
摘要翻译： 提出了通过解离相应的氨基甲酸酯来制备异氰酸酯的方法，其包括在异质路易斯酸性催化剂存在下使氨基甲酸酯解离。
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公开(公告)号：US20110257431A1
公开(公告)日：2011-10-20
申请号：US13050495
申请日：2011-03-17
申请人： Robert Baumann , Markus Christian Biel , Gordon Brasche , Axel Franzke , Thomas Heidenfelder , Paul Klingelhoefer , Alfred Oftring , Marie Katrin Schroter
发明人： Robert Baumann , Markus Christian Biel , Gordon Brasche , Axel Franzke , Thomas Heidenfelder , Paul Klingelhoefer , Alfred Oftring , Marie Katrin Schroter
IPC分类号： C07C227/02
CPC分类号： C07C227/02 , C07C229/16
摘要： The present invention relates to a process for preparing aminocarboxylates, proceeding from amines, by employing a reaction sequence composed of ethoxylation to amino alcohols and subsequent oxidative dehydrogenation to the corresponding aminocarboxylates, especially the alkali metal or alkaline earth metal salts of the complexing agents MGDA (methylglycinediacetic acid), EDTA (ethylenediaminetetra-acetic acid) and GLDA (glutamic acid diacetic acid) or the free acids thereof.
摘要翻译： 本发明涉及一种通过使用由乙氧基化氨基醇组成的反应顺序并随后氧化脱氢至相应的氨基羧酸盐，特别是络合剂MGDA的碱金属或碱土金属盐来制备氨基羧酸盐的方法， 甲基甘氨酸二乙酸），EDTA（乙二胺四乙酸）和GLDA（谷氨酸二乙酸）或其游离酸。
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7.发明申请METHOD FOR PRODUCING URETHANES COMPOSED OF DI-FUNCTIONAL AROMATIC AMINES AND DIALKYL CARBONATES 有权用于生产由二官能芳族氨基和碳酸二烷基酯构成的尿素的方法公开(公告)号：US20110137067A1
公开(公告)日：2011-06-09
申请号：US13058026
申请日：2009-08-18
申请人： Axel Franzke , Robert Baumann , Michael Bock , Roderich Roettger , Andreas Leitner , Matthias Kloetzer
发明人： Axel Franzke , Robert Baumann , Michael Bock , Roderich Roettger , Andreas Leitner , Matthias Kloetzer
IPC分类号： C07C269/04
CPC分类号： C07C269/04 , C07C271/28
摘要： A process for preparing urethanes by reacting aromatic diamines with a dialkyl carbonate, wherein the alkyl radical of the organic dialkyl carbonate comprises 2-18 carbon atoms and one or more heteroatoms and the reaction is performed in the presence of a catalyst.
摘要翻译： 通过使芳族二胺与碳酸二烷基酯反应来制备聚氨酯的方法，其中有机碳酸二烷基酯的烷基包含2-18个碳原子和一个或多个杂原子，反应在催化剂存在下进行。
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公开(公告)号：US08822718B2
公开(公告)日：2014-09-02
申请号：US13513460
申请日：2010-11-30
IPC分类号： C07C263/04
CPC分类号： C07C263/04 , C07C265/14
摘要： A process is proposed for preparing isocyanates by thermally cleaving carbamates to obtain a carbamate cleavage gas comprising the corresponding isocyanate and the corresponding alcohol, which comprises quenching the carbamate cleavage gas in the presence of an ether which functions as an inhibitor for the reverse reaction of the isocyanate with the alcohol.
摘要翻译： 提出了通过热裂解氨基甲酸酯制备异氰酸酯以获得包含相应的异氰酸酯和相应的醇的氨基甲酸酯裂解气体的方法，该方法包括在醚的存在下猝灭氨基甲酸酯裂解气体，该醚用作反应的反应的抑制剂 异氰酸酯与醇。
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公开(公告)号：US20130144080A1
公开(公告)日：2013-06-06
申请号：US13693281
申请日：2012-12-04
CPC分类号： C07C68/08 , C07C29/82 , Y02P20/127 , Y02P20/582 , C07C69/96 , C07C31/202
摘要： The invention relates to a process for obtaining a dialkyl carbonate and an alkylene glycol from a stream comprising dialkyl carbonate, alkylene carbonate, alkylene glycol and alcohol, comprising the following steps: (a) distillatively removing a stream (5) comprising dialkyl carbonate and alkylene glycol as a heteroazeotrope from the stream comprising dialkyl carbonate, alkylene carbonate, alkylene glycol and alcohol in a first distillation stage (1), (b) separating the stream (5) comprising dialkyl carbonate and alkylene glycol as a heteroazeotrope into a first crude product stream (27) comprising essentially di-alkyl carbonate and a second crude product stream (29) comprising essentially alkylene glycol in an apparatus for phase separation (25).
摘要翻译： 本发明涉及从包含碳酸二烷基酯，亚烷基碳酸酯，亚烷基二醇和醇的物流中获得碳酸二烷基酯和亚烷基二醇的方法，包括以下步骤：（a）蒸馏除去包含碳酸二烷基酯和亚烷基 在第一蒸馏阶段（1）中，将包含碳酸二烷基酯，亚烷基碳酸酯，亚烷基二醇和醇的物流作为杂化物二醇，（b）将包含碳酸二烷基酯和亚烷基二醇的物流（5）分离成第一粗产物 包含基本上二烷基碳酸酯的流（27）和在用于相分离的装置（25）中基本上包含亚烷基二醇的第二粗产物流（29）。
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公开(公告)号：US20120203022A1
公开(公告)日：2012-08-09
申请号：US13501621
申请日：2010-10-20
申请人： Axel Franzke , Robert Baumann , Michael Bock
发明人： Axel Franzke , Robert Baumann , Michael Bock
IPC分类号： C07C269/04 , C07C263/04
CPC分类号： C07C269/04 , C07C263/04 , C07C265/14 , C07C271/28
摘要： The content of the invention is a process for preparing urethanes by reaction of aromatic amines with a dialkyl carbonate, wherein the alkyl radical of the organic dialkyl carbonate comprises 4-18 carbon atoms and is branched in the 2 position, and the reaction is performed in the presence of a substoichiometric amount of base, based on the amino groups.
摘要翻译： 本发明的内容是通过芳族胺与碳酸二烷基酯的反应制备氨基甲酸酯的方法，其中有机碳酸二烷基酯的烷基包含4-18个碳原子并在2位上分支，并且反应在 基于氨基的亚化学计量量的碱的存在。
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