公开(公告)号：US20110306812A1

公开(公告)日：2011-12-15

申请号：US13159761

申请日：2011-06-14

申请人： Wolfgang Rohde ,  Qiang Miao ,  Stefan Bitterlich ,  Gauthier Luc Maurice Averlant ,  Hans-Guenter Wagner ,  Beatrice Rößler-Feigel

发明人： Wolfgang Rohde ,  Qiang Miao ,  Stefan Bitterlich ,  Gauthier Luc Maurice Averlant ,  Hans-Guenter Wagner ,  Beatrice Rößler-Feigel

IPC分类号： C07C2/00

CPC分类号： C07C2/12 ,  C07C2523/755 ,  C07C2529/072 ,  C07C2529/70 ,  Y02P20/582 ,  C07C11/02

摘要： In a process for the cooligomerization of olefins, an olefin starting material comprising olefins having n carbon atoms and olefins having 2n carbon atoms is reacted over an olefin oligomerization catalyst to give a reaction product. The process is carried out under such conditions that the conversion of olefins having 2n carbon atoms is less than 10%. Both the cooligomer having 3n carbon atoms and the olefin having 2n carbon atoms which has been separated off from the reaction product have a high hydroformylatability.

摘要翻译： 在烯烃冷却反应的方法中，将包含具有n个碳原子的烯烃和具有2n个碳原子的烯烃的烯烃原料在烯烃低聚催化剂上反应得到反应产物。 该方法在具有2n个碳原子的烯烃的转化率小于10％的条件下进行。 具有3n个碳原子的冷聚物和已经从反应产物中分离的具有2n个碳原子的烯烃都具有高的加氢甲酰化性。

公开(公告)号：US20100190869A1

公开(公告)日：2010-07-29

申请号：US12694851

申请日：2010-01-27

申请人： Joaquim Henrique Teles ,  Beatrice Rößler-Feigel ,  Alexander Hauk ,  Christian Müller ,  Michael Schelper ,  Tanja Kirchner ,  Susanne Szeschkus

发明人： Joaquim Henrique Teles ,  Beatrice Rößler-Feigel ,  Alexander Hauk ,  Christian Müller ,  Michael Schelper ,  Tanja Kirchner ,  Susanne Szeschkus

IPC分类号： A61K8/35 ,  C07C45/28 ,  C11D3/50 ,  A61K47/08 ,  A61Q13/00

CPC分类号： C11B9/0015 ,  C07C45/28 ,  C07C45/62 ,  C07C45/82 ,  Y02P20/582 ,  C07C47/21 ,  C07C47/02

摘要： The present invention relates to a process for preparing at least one compound with Z−1 cycles and 7 to 16 carbon atoms with at least one aldehyde group, at least comprising the stages: (a1) oxidation of a composition (A), at least comprising a cyclic olefin with Z cycles and 7 to 16 carbon atoms and at least two C—C double bonds, by means of dinitrogen monoxide to give a composition (A1), (a2) separating off the at least one cyclic olefin with Z cycles and 7 to 16 carbon atoms with at least two C—C double bonds from the composition (A1) from stage (a1) in order to obtain a composition (A2), (b1) separating off the at least one cyclic compound with Z cycles and 7 to 16 carbon atoms with a keto group from the composition (A2) from step (a2), in order to obtain a composition (B1), comprising at least 50% by weight of the at least one compound with Z−1 cycles and 7 to 16 carbon atoms with at least one aldehyde group and at least two C—C double bonds, where Z may be 1, 2, 3 or 4.

摘要翻译： 本发明涉及至少一种具有Z-1个循环和7-16个碳原子的化合物与至少一个醛基的制备方法，至少包括以下步骤：（a1）组合物（A）的氧化，至少 包含具有Z循环和7至16个碳原子的环烯烃以及至少两个C-C双键的方法，通过一氧化二氮来得到组合物（A1），（a2）以Z循环分离出至少一种环状烯烃 和从碳（a1）组合物（A1）至少具有两个C-C双键的碳原子数为7〜16的碳原子，以获得组合物（A2），（b1）以Z循环分离出至少一种环状化合物 和具有来自步骤（a2）的组合物（A2）的酮基的7至16个碳原子，以获得组合物（B1），其包含至少50重量％的至少一种Z-1循环的化合物 和具有至少一个醛基和至少两个C-C双键的7至16个碳原子，其中Z可以是1,2,3或4。

公开(公告)号：US20100191018A1

公开(公告)日：2010-07-29

申请号：US12694815

申请日：2010-01-27

申请人： Joaquim Henrique Teles ,  Beatrice Rößler-Feigel ,  Alexander Hauk ,  Anton Meier ,  Christian Müller ,  Michael Schelper ,  Tanja Kirchner ,  Susanne Szeschkus ,  Rolf Pinkos ,  Gerd-Dieter Tebben

发明人： Joaquim Henrique Teles ,  Beatrice Rößler-Feigel ,  Alexander Hauk ,  Anton Meier ,  Christian Müller ,  Michael Schelper ,  Tanja Kirchner ,  Susanne Szeschkus ,  Rolf Pinkos ,  Gerd-Dieter Tebben

IPC分类号： C07C45/27

CPC分类号： C07C45/82 ,  C07C45/28 ,  C07C45/62 ,  C07C2601/20 ,  C07C49/607 ,  C07C49/413

摘要： The present invention relates to a process for preparing at least one cyclic compound with Z cycles and 7 to 16 carbon atoms with a keto group, at least comprising the stages: (a1) oxidation of a composition (A), at least comprising one cyclic olefin with Z cycles and 7 to 16 carbon atoms and at least two C—C double bonds, by means of dinitrogen monoxide to give a composition (A1), (a2) separating off the at least one cyclic olefin with Z cycles and 7 to 16 carbon atoms with at least two C—C double bonds from the composition (A1) in order to obtain a composition (A2), and (b) distillative treatment of the composition (A2) from step (a2) in order to obtain a composition (B), comprising the at least one cyclic compound with Z cycles and 7 to 16 carbon atoms with a keto group and less than 1.0% by weight of the at least one compound with Z−1 cycles and 7 to 16 carbon atoms with at least one aldehyde group, where Z can be 1, 2, 3 or 4.

摘要翻译： 本发明涉及一种制备具有Z环和至少具有7至16个碳原子的酮基的至少一种环状化合物的方法，至少包括以下步骤：（a1）组合物（A）的氧化，至少包含一个环状 烯烃，Z循环和7至16个碳原子和至少两个C-C双键，借助于一氧化二氮，得到组合物（A1），（a2）以Z循环分离至少一种环状烯烃， 16个碳原子与来自组合物（A1）的至少两个C-C双键，以获得组合物（A2），和（b）从步骤（a2）中的组合物（A2）的蒸馏处理，以获得 组合物（B），其包含至少一种Z循环的环状化合物和具有酮基的7至16个碳原子和小于1.0重量％的至少一种具有Z-1循环和7至16个碳原子的化合物， 至少一个醛基，其中Z可以是1,2,3或4个。

公开(公告)号：US20090326276A1

公开(公告)日：2009-12-31

申请号：US12306827

申请日：2007-06-27

申请人： Joaquim Henrique Teles ,  Beatrice Rößler ,  Rolf Pinkos ,  Gerd Tebben ,  Christian Müller ,  Harald Rust

发明人： Joaquim Henrique Teles ,  Beatrice Rößler ,  Rolf Pinkos ,  Gerd Tebben ,  Christian Müller ,  Harald Rust

IPC分类号： C07C45/27

CPC分类号： C07C45/28 ,  C07C45/62 ,  C07C45/80 ,  C07C45/81 ,  C07C45/82 ,  C07C45/85 ,  C07C2601/18 ,  C07C2601/20 ,  C07C49/607 ,  C07C49/413

摘要： The present invention relates to a process for preparing a cyclic ketone having from 7 to 16 carbon atoms, which comprises at least the steps(a) oxidation of a composition (I) comprising at least one cyclic alkene which has from 7 to 16 carbon atoms and at least one C—C double bond by means of dinitrogen monoxide to give a composition (A),(b) treatment of the composition (A) with at least one base to give a composition (B),(c) hydrogenation of the composition (B) in the presence of at least one catalyst to give a composition (C),(d) purification of the composition (C), comprising at least the steps(di) thermal treatment of the composition (C) with at least one acid or at least one catalyst comprising at least one transition metal,(dii) further purification by a method selected from the group consisting of distillation, extraction and crystallization.

摘要翻译： 本发明涉及一种制备具有7至16个碳原子的环酮的方法，其至少包括步骤（a）氧化包含至少一个具有7至16个碳原子的环烯烃的组合物（I） 和至少一个CC双键，得到组合物（A），（b）用至少一种碱处理组合物（A），得到组合物（B），（c）组合物的氢化 （B）在至少一种催化剂的存在下，得到组合物（C），（d）组合物（C）的纯化，至少包括步骤（ii）组合物（C）的热处理至少一种 酸或至少一种包含至少一种过渡金属的催化剂，（dii）通过选自蒸馏，萃取和结晶的方法进一步纯化。