Process for precipitating compounds from zinc metal baths by means of a hollow rotary body that can be driven about an axis and is dipped into the molten zinc
    1.
    发明授权
    Process for precipitating compounds from zinc metal baths by means of a hollow rotary body that can be driven about an axis and is dipped into the molten zinc 失效
    通过可以绕轴线驱动并浸入熔融锌中空的旋转体从锌金属浴中沉淀化合物的方法

    公开(公告)号:US06364930B1

    公开(公告)日:2002-04-02

    申请号:US09402465

    申请日:1999-10-08

    Applicant: Bernd Kos

    Inventor: Bernd Kos

    Abstract: A process and device are disclosed for precipitating solid compounds from the liquid zinc or liquid zinc-based alloys of a metal bath. According to the disclosed process, partial amounts of the metal phase containing the compound(s) are exposed to an acceleration higher than the acceleration due to gravity and at least partially dissociated thereby into fractions containing heavier and/or lighter components. The molten mass depleted of solid compounds is returned to the metal bath and the part of the molten mass enriched with the desired compounds is discharged. The disclosed device is substantially characterized in that a hollow rotary body (2) is introduced into the molten mass (1). The hollow rotary body (2) can be driven about an axis and is fitted in the submerged or lower area with conveyor means (21) which project into the cavity. In its discharge or upper area, the hollow rotary body (2) is provided with at least one discharge opening (23) for the depleted molten mass (14) eccentrically arranged in its wall and with at least one further discharge opening (25) for the liquid metal enriched with the desired compounds centrally arranged and/or eccentrically arranged on the discharge side. At least one of the upper molten mass discharge openings (23, 24) in the rotary body (2) opens into a discharge area of a housing (3) which at least partially surrounds the rotary body (2).

    Abstract translation: 公开了一种用于从金属浴的液体锌或液体锌基合金中沉淀固体化合物的方法和装置。 根据所公开的方法,含有化合物的金属相的部分量暴露于比由重力加速度高的加速度,并且至少部分地离解,从而加入含较重和/或较轻组分的级分。 将固体化合物耗尽的熔融物质返回到金属浴中,并且排出富含所需化合物的部分熔融物质。 所公开的装置的基本特征在于,将中空旋转体(2)引入熔融体(1)中。 空心旋转体(2)可以围绕轴线驱动,并且通过投入到空腔中的输送装置(21)装配在浸没或下部区域中。 中空旋转体(2)在其排出口或上部区域设置有至少一个排出口(23),用于耗尽的熔融物质(14)偏心地布置在其壁上,并具有至少一个另外的排出口(25),用于 富含所需化合物的液态金属在排出侧中央排列和/或偏心地排列。 旋转体(2)中的上部熔融体排放口(23,24)中的至少一个通向至少部分地围绕旋转体(2)的壳体(3)的排放区域。

    Grain-refined austenitic manganese steel casting having microadditions of vanadium and titanium and method of manufacturing
    2.
    发明授权
    Grain-refined austenitic manganese steel casting having microadditions of vanadium and titanium and method of manufacturing 失效
    具有钒和钛的微加成的晶粒细化奥氏体锰钢铸件及其制造方法

    公开(公告)号:US06572713B2

    公开(公告)日:2003-06-03

    申请号:US09932155

    申请日:2001-08-17

    Abstract: An austenitic manganese steel microalloyed with nitrogen, vanadium and titanium used for castings such as mantles, bowls and jaws manufactured as wear components of crushers in the mining and aggregate industries, hammers used in scrap shredders, frogs and switches used in railway crossings and buckets and track shoes used in mining power shovels. These novel compositions exhibit a fine grain size having carbonitride precipitates that result in castings having a wear life 20-70% longer than prior art castings. The austenitic manganese steel includes, in weight percentages, the following: about 11.0% to 24.0% manganese, about 1.0% to 1.4% carbon, up to about 1% silicon, up to about 1.9% chromium, up to about 0.25% nickel, up to about 1.0% molybdenum, up to about 0.2% aluminum, up to about 0.25% copper, phosphorus and sulfur present as impurities in amounts of about 0.07% max and about 0.06% max. respectively, microalloying additions of titanium in the amounts of about 0.020-0.070%, optionally, microalloying additions of niobium in amounts from about 0.020-0.070%, microalloying additions of vanadium in amounts from about 0.020-0.070%, nitrogen in amounts from about 100 to 1000 ppm, and such that the total amount of the microalloying additions of titanium+niobium+vanadium+nitrogen is no less than about 0.05% and no greater than about 0.22%, the ratio of carbon to microalloying additions being in the range of about 10:1-25:1, and the balance of the alloy being essentially iron, the alloy being characterized by a substantial absence of zirconium and the presence of titanium carbonitride precipitates.

    Abstract translation: 用于采矿和集料工业中作为破碎机磨损部件制造的诸如地幔,碗和颚等铸件的氮,钒和钛的奥氏体锰钢,用于铁路路口和水桶中使用的废粉碎机,青蛙和开关中的锤子 采矿铲中使用的履带板。 这些新型组合物表现出具有碳氮化物析出物的细晶粒尺寸,导致铸件的磨损寿命比现有技术的铸件长20-70%。 奥氏体锰钢以重量百分比计包括:约11.0%至24.0%的锰,约1.0%至1.4%的碳,至多约1%的硅,至多约1.9%的铬,至多约0.25%的镍, 高达约1.0%的钼,至多约0.2%的铝,至多约0.25%的铜,磷和硫作为杂质存在,最大量为约0.07%,最大为约0.06%。 分别以约0.020-0.070%,约0.020-0.070%的量的微合金添加量,约0.020-0.070%的微量合金添加量,约0.020-0.070%的氮,以约100% 至1000ppm,并且使得钛+铌+钒+氮的微合金化添加物的总量不小于约0.05%且不大于约0.22%,碳与微合金添加量的比例在约 10:1-25:1,合金的余量基本上是铁,该合金的特征在于基本上不存在锆,并且存在碳氮化钛沉淀。

    Process for obtaining fluid light metal from a dispersed mixture
    3.
    发明授权
    Process for obtaining fluid light metal from a dispersed mixture 失效
    从分散的混合物中获得流体轻金属的方法

    公开(公告)号:US5900039A

    公开(公告)日:1999-05-04

    申请号:US790759

    申请日:1997-01-27

    Applicant: Bernd Kos

    Inventor: Bernd Kos

    CPC classification number: C22B7/04 C22B21/0092 C22B7/004 Y02P10/218

    Abstract: Process for obtaining a metallic phase from a dispersed mixture composed of one of (a) at least one metal selected from the group consisting of a light metal or an alloy of the at least one metal, and mixtures thereof, and (b) at least one non-metallic phase composed of at least one member selected from the group consisting of at least one oxide, an oxide compound, and other compounds of the at least one metal at higher temperatures. The process includes introducing the dispersed mixture into a metallurgical vessel; at least one of heating and adjusting a temperature of the dispersed mixture to between 20 and 250.degree. C. above the liquidus temperature of the metallic phase; rotating the metallurgical vessel to homogenize the dispersed mixture and to produce a pourable dispersed mixture; uniformly distributing the pourable dispersed mixture around a rotational axis of the metallurgical vessel; and increasing a radial acceleration of the pourable dispersed mixture of at least 1 g. The process further includes maintaining the radial acceleration for at least 0.015 hours to one of separate the metallic phase of the pourable dispersed mixture from the non-metallic phase of the pourable dispersed mixture and de-metallize the pourable dispersed mixture; decreasing the radial acceleration to a value of 0 in a span of time greater than 0.03 hours; pouring the metallic phase as a fluid out of the metallurgical vessel; and after pouring the metallic phase out of the metallurgical vessel, removing the at least one non-metallic phase from the metallurgical vessel.

    Abstract translation: 从由(a)至少一种选自轻金属或至少一种金属的合金的金属及其混合物中的一种组成的分散混合物中获得金属相的方法及其混合物,和(b)至少 一个非金属相由在较高温度下由至少一种氧化物,氧化物化合物和至少一种金属的其它化合物组成的组中的至少一种构成。 该方法包括将分散的混合物引入冶金容器中; 将分散混合物的温度加热至高于金属相液相线温度20至250℃的至少一种; 旋转冶金容器以均化分散的混合物并产生可倾倒的分散混合物; 将可倾倒分散的混合物均匀地分布在冶金容器的旋转轴线周围; 并且增加至少1g的可分散混合物的径向加速度。 该方法还包括将可倾倒分散的混合物的金属相与可倾倒的分散的混合物的非金属相分开的至少0.015小时的径向加速度保持在一起,并使可倾倒的分散的混合物去金属化; 在大于0.03小时的时间间隔内将径向加速度减小到0; 将金属相作为流体从冶金容器中倒出; 并且在将金属相倒出冶金容器之后,从冶金容器中除去至少一个非金属相。

    Process for the treatment of light metals
    4.
    发明授权
    Process for the treatment of light metals 失效
    轻金属处理工艺

    公开(公告)号:US5525141A

    公开(公告)日:1996-06-11

    申请号:US312901

    申请日:1994-09-30

    Abstract: Process and apparatus for the treatment of light metals. The present invention pertains to a process for the treatment of mixtures of at least one light metal and at least one nonmetallic phase, formed of at least one oxide of a light metal, particularly of slag and waste metals for a subsequent process for the separation of the metallic phase as well as an apparatus for carrying out the process or the preparation of the mixture for disintegration, wherein the mixture, slag or waste metals and, if necessary, additions for the formation of a charge, are loaded into a treatment container or receptacle, overheated a maximum of 380.degree. C. and the phases, via motion, are dispersed and/or held in dispersement, whereafter the homogenized charge, set up with the parameters for the subsequent process, is removed and subjected to separation.

    Abstract translation: 用于处理轻金属的工艺和设备。 本发明涉及一种处理至少一种轻金属和至少一种非金属相的混合物的方法,该至少一种非金属相由至少一种轻金属氧化物,特别是渣和废金属形成,用于后续的分离方法 金属相以及用于进行该方法或制备用于分解的混合物的装置,其中将混合物,炉渣或废金属以及必要时添加的用于形成电荷的装置装入处理容器或 容器过热,最高380℃,通过运动将相分散和/或保持分散,然后除去用于后续方法的参数设定的均匀化电荷并进行分离。

    Method to separate metallic phases from other phases containing same and
device to carry out the method
    5.
    发明授权
    Method to separate metallic phases from other phases containing same and device to carry out the method 失效
    分离金属相与含有相同装置的其他相的方法,以执行该方法

    公开(公告)号:US5401294A

    公开(公告)日:1995-03-28

    申请号:US989025

    申请日:1993-04-29

    CPC classification number: C22B9/02 B01D21/262 Y02P10/234

    Abstract: The invention concerns a process for de-metallization of metal-containing residues, dross, slags and the like that accumulate during thermal processes in metallurgical and scrap metal reclamation processes which consists of that the metal/non-metal phase mixture is fed into a centrifuge mold at a temperature within the mentioned temperature range or after having been fed into it is brought to the temperature mentioned, there in a first process phase, while maintaining the temperature within the mentioned range, it is subjected to radial acceleration for a specified time until a required degree of de-metallization is achieved and that in a second phase of the process by maintaining the radial acceleration by means of rotation at least the metallic phase, separated and removed from the phase mixture and arranged on the outside periphery is brought to solidification or setting by lowering its temperature, after which the metal phase when reaching the handling temperature is removed as at least one body whose outer surface corresponds essentially to the shape of the inside of the centrifuge mold and whose inside has a paraboloidal or cylindrical surface. It also includes the preferred devices for the implementation thereof.

    Abstract translation: PCT No.PCT / AT92 / 00091 Sec。 371日期:1993年4月29日 102(e)日期1993年4月29日PCT提交1992年7月10日PCT公布。 出版物WO93 / 01321 日期1993年1月21日。本发明涉及在冶金和废金属回收方法中在热处理期间积聚的含金属残渣,浮渣,炉渣等的金属化方法,其包括金属/非金属 将相混合物在所述温度范围内的温度下进料到离心机模具中,或者在进料到其中之后,在第一工艺阶段将温度提高到所提到的温度,同时将温度保持在上述范围内, 径向加速度达到规定时间,直到达到所需的去金属化程度,并且在该过程的第二阶段中,通过至少将相位混合物分离和移除的金属相的旋转维持径向加速度并且布置在 通过降低其外部温度来使外周凝固或凝固,此后金属相达到处理温度 e作为至少一个主体移除,其外表面基本上对应于离心机模具内部的形状,其内部具有抛物面或圆柱形表面。 它还包括用于实现它们的优选设备。

    Method for the extraction of the metallic phase from dispersed mixtures
of light metals and nonmetallic components
    7.
    发明授权
    Method for the extraction of the metallic phase from dispersed mixtures of light metals and nonmetallic components 失效
    从轻金属和非金属组分的分散混合物中提取金属相的方法

    公开(公告)号:US5462578A

    公开(公告)日:1995-10-31

    申请号:US247843

    申请日:1994-05-23

    CPC classification number: C22B21/0069 C22B7/04 Y02P10/212

    Abstract: Method for the extraction of the metallic phase from dispersed mixtures of light metals and nonmetallic components. The invention pertains to an advantageous method for the extraction of the metallic phase from a dispersed mixture comprised of at least one light metal and at least one nonmetallic phase and, if applicable, at least the partial separation of the nonmetallic phase. The temperature of the dispersed mixture is raised to a temperature in the region above the melting temperature of the metal or alloy; the heated mixture is then inserted into an apparatus, subjected to an acceleration, and disintegrated, with the metallic phase thereafter being coalesced, collected and allowed to proceed to solidification.

    Abstract translation: 从轻金属和非金属组分的分散混合物中提取金属相的方法。 本发明涉及从由至少一种轻金属和至少一种非金属相组成的分散混合物中提取金属相的有利方法,并且如果适用,至少部分分离非金属相。 分散混合物的温度升高到高于金属或合金的熔融温度的区域的温度; 然后将加热的混合物插入装置中,加速并分解,随后将金属相合并,收集并使其进行固化。

    Work-hardenable austenitic manganese steel and method for the production
thereof
    8.
    发明授权
    Work-hardenable austenitic manganese steel and method for the production thereof 失效
    工作可硬化的奥氏体锰钢及其制造方法

    公开(公告)号:US4531974A

    公开(公告)日:1985-07-30

    申请号:US540649

    申请日:1983-10-11

    Applicant: Bernd Kos

    Inventor: Bernd Kos

    CPC classification number: C22C38/04

    Abstract: A work-hardenable austenitic manganese steel has a base composition (each in percent by weight) of 0.7 to 1.7 carbon, 5.0 to 18.0 manganese, 0 to 3.0 chromium, 0 to 4.0 nickel, 0 to 2.5 molybdenum, 0.1 to 0.9 silicon, up to 0.1 phosphorus and contains micro-alloying elements of 0.0 to 0.20 titanium, 0.0 to 0.05 zirconium and 0.0 to 0.05 vanadium; the remainder being iron and impurities arising from the melting process. The ratio of carbon to manganese is in the range of 1:4 to 1:14 and the total amount of micro-alloying elements is limited to a range of 0.002 to 0.25 percent by weight. The melt of the base composition is tapped at 1,450.degree. C. to 1,600.degree. C. into a casting ladle in which the micro-alloying elements are added. An ingot is cast, cooled, reheated to austenitization temperatures and quenched.

    Abstract translation: 工作硬化奥氏体锰钢的基础组成(重量百分比)为0.7〜1.7,5.0〜18.0的锰,0〜3.0的铬,0〜4.0的镍,0〜2.5的钼,0.1〜0.9的硅, 至0.1磷,含有0.0〜0.20钛的微合金元素,0.0〜0.05的锆和0.0〜0.05的钒; 其余的是由熔融过程产生的铁和杂质。 碳与锰的比例在1:4至1:14的范围内,微合金元素的总量限制在0.002至0.25重量%的范围内。 将基础组合物的熔体在1450℃至1600℃点火,加入其中加入微合金元素的铸钢包中。 将铸锭铸造,冷却,再加热至奥氏体化温度并淬火。

    Work-hardenable austenitic manganese steel and method for the production
thereof
    9.
    发明授权
    Work-hardenable austenitic manganese steel and method for the production thereof 失效
    工作可硬化的奥氏体锰钢及其制造方法

    公开(公告)号:US4512804A

    公开(公告)日:1985-04-23

    申请号:US480998

    申请日:1983-03-30

    Applicant: Bernd Kos

    Inventor: Bernd Kos

    CPC classification number: C22C38/04

    Abstract: A work-hardenable austenitic manganese steel has a base composition (each in percent by weight) of 0.7 to 1.7 carbon, 5.0 to 18.0 manganese, 0 to 3.0 chromium, 0 to 4.0 nickel, 0 to 2.5 molybdenum, 0.1 to 0.9 silicon, up to 0.1 phosphorus and contains micro-alloying elements of 0.0 to 0.05 titanium, 0.0 to 0.05 zirconium and 0.0 to 0.05 vanadium; the remainder being iron and impurities arising from the melting process. The ratio of carbon to manganese is in the range of 1:4 to 1:14 and the total amount of micro-alloying elements is limited to a range of 0.002 to 0.05 percent by weight. The melt of the base composition is tapped at 1,450.degree. C. to 1,600.degree. C. into a casting ladle in which the micro-alloying elements are added. An ingot is cast, cooled, reheated to austenitization temperatures and quenched.

    Abstract translation: 工作硬化奥氏体锰钢的基础组成(重量百分比)为0.7〜1.7,5.0〜18.0的锰,0〜3.0的铬,0〜4.0的镍,0〜2.5的钼,0.1〜0.9的硅, 至0.1磷,含有0.0〜0.05的钛,0.0〜0.05的锆和0.0〜0.05的钒的微合金元素; 其余的是由熔融过程产生的铁和杂质。 碳与锰的比例在1:4至1:14的范围内,微合金元素的总量限制在0.002至0.05重量%的范围内。 将基础组合物的熔体在1450℃至1600℃点火,加入其中加入微合金元素的铸钢包中。 将铸锭铸造,冷却,再加热至奥氏体化温度并淬火。

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