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1.发明授权Lewis and bronsted-lowry acid-catalyzed production 5-hydroxymethylfurfural (HMF) from glucose 有权路易斯和青铜酸催化从葡萄糖生产5-羟甲基糠醛（HMF）公开(公告)号：US08642791B2
公开(公告)日：2014-02-04
申请号：US13313389
申请日：2011-12-07
IPC分类号： C07D307/46
CPC分类号： C07D307/48
摘要： Described is a process to make hydroxymethylfurfural (HMF) from glucose. The process includes the steps of reacting a feedstock solution comprising glucose, in the presence of a homogeneous Brønsted acid catalyst and a homogeneous Lewis acid catalyst, in a reaction vessel containing a biphasic reaction medium. The reaction medium includes an aqueous reaction solution and a substantially immiscible organic extraction solution. HMF is produced in the aqueous reaction solution and extracted into the organic extraction solution.
摘要翻译： 描述了从葡萄糖制备羟甲基糠醛（HMF）的方法。 该方法包括在含有双相反应介质的反应容器中使包含葡萄糖的原料溶液在均相布朗斯台德酸催化剂和均相路易斯酸催化剂存在下反应的步骤。 反应介质包括水性反应溶液和基本上不混溶的有机萃取溶液。 在反应溶液中生成HMF，并萃取到有机萃取溶液中。
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公开(公告)号：US5962757A
公开(公告)日：1999-10-05
申请号：US839841
申请日：1997-04-17
IPC分类号： B01J23/745 , B01J23/76 , C07B61/00 , C07C5/333 , C07C15/46 , C07C2/64 , B01J23/58 , C07C5/09
CPC分类号： B01J23/8872 , B01J23/745 , B01J23/76 , C07C5/3332 , C07C2523/745 , C07C2523/76
摘要： Dehydrogenation catalysts are prepared by a predoping process comprising, mixing iron oxide materials with a predopant to form a blend of iron oxide and predopant and heating the blend to the predoping conditions and thereafter forming a catalyst. The catalysts so prepared are useful in the dehydrogenation of a composition having at least one carbon--carbon double bond. Such catalytic uses include the conversion of ethylbenzene to styrene.
摘要翻译： 脱氢催化剂通过预处理方法制备，其包括：将氧化铁材料与预聚物混合以形成氧化铁和预掺合物的共混物，并将共混物加热至预阶段条件，然后形成催化剂。 如此制备的催化剂可用于具有至少一个碳 - 碳双键的组合物的脱氢。 这种催化用途包括将乙苯转化成苯乙烯。
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公开(公告)号：US5668075A
公开(公告)日：1997-09-16
申请号：US644694
申请日：1996-05-10
IPC分类号： C01G49/00 , B01J23/745 , B01J23/76 , B01J35/10 , C07B61/00 , C07C5/333 , C07C11/18 , C07C15/46 , B01J23/70 , C01G49/02
CPC分类号： B01J37/08 , B01J23/745 , B01J23/76 , B01J23/8872 , B01J23/8877 , B01J23/8898 , B01J35/10 , C07C5/3332 , C07C5/3337 , B01J35/1009 , B01J35/1038 , B01J35/1066 , B01J35/1071 , C07C2523/745
摘要： In one aspect of the invention, a composition is presented comprising restructured iron oxide particles. A method is also presented for restructuring iron oxide particles to form low surface area iron oxide particles. In this method, iron oxide particles are contacted with an effective mount of a restructuring agent and are then heated until restructuring occurs.
摘要翻译： 在本发明的一个方面，提供了包含重组的氧化铁颗粒的组合物。 还提出了重构氧化铁颗粒以形成低表面积氧化铁颗粒的方法。 在该方法中，氧化铁颗粒与有效安装的重组剂接触，然后加热直到发生重组。
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4.发明申请LEWIS AND BRONSTED-LOWRY ACID-CATALYZED PRODUCTION OF 5-HYDROXYMETHYLFURFURAL (HMF) FROM GLUCOSE 有权来自葡萄糖的五羟基甲基纤维素（HMF）的低温和低温酸催化生产公开(公告)号：US20130150595A1
公开(公告)日：2013-06-13
申请号：US13313389
申请日：2011-12-07
IPC分类号： C07D307/68
CPC分类号： C07D307/48
摘要： Described is a process to make hydroxymethylfurfural (HMF) from glucose. The process includes the steps of reacting a feedstock solution comprising glucose, in the presence of a homogeneous Brønsted acid catalyst and a homogeneous Lewis acid catalyst, in a reaction vessel containing a biphasic reaction medium. The reaction medium includes an aqueous reaction solution and a substantially immiscible organic extraction solution. HMF is produced in the aqueous reaction solution and extracted into the organic extraction solution.
摘要翻译： 描述了从葡萄糖制备羟甲基糠醛（HMF）的方法。 该方法包括在含有双相反应介质的反应容器中使包含葡萄糖的原料溶液在均相布朗斯台德酸催化剂和均相路易斯酸催化剂存在下反应的步骤。 反应介质包括水性反应溶液和基本上不混溶的有机萃取溶液。 在反应溶液中生成HMF，并萃取到有机萃取溶液中。
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