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    Process and systems for the epoxidation of an olefin
    1.
    发明授权
    Process and systems for the epoxidation of an olefin 有权
    用于烯烃环氧化的方法和系统

    公开(公告)号：US07193094B2

    公开(公告)日：2007-03-20

    申请号：US10404829

    申请日：2003-04-01

    Applicant: Peter Ingraham Chipman ,  Jeffrey Michael Kobe ,  Arjan Jan Te Raa ,  Leonid Isaakovich Rubinstein ,  Brian Scott Vanderwilp ,  Thijs Wermink

    Inventor： Peter Ingraham Chipman ,  Jeffrey Michael Kobe ,  Arjan Jan Te Raa ,  Leonid Isaakovich Rubinstein ,  Brian Scott Vanderwilp ,  Thijs Wermink

    IPC: C07D301/10

    CPC classification number: C07D301/10

    Abstract: A process for the epoxidation of an olefin, which process comprises reacting a feed comprising the olefin, oxygen and a reaction modifier in the presence of a highly selective silver-based catalyst at a reaction temperature T, and with the reaction modifier being present in a relative quantity Q which is the ratio of an effective molar quantity of active species of the reaction modifier present in the feed to an effective molar quantity of hydrocarbons present in the feed, and which process comprises the steps of: operating at a first operating phase wherein the value of T is T1 and the value of Q is Q1, and subsequently operating at a second operating phase at a reaction temperature which is different from the reaction temperature employed in the first operating phase, such that the value of T is T2 and the value of Q is substantially Q2, whereby Q2 is determined by calculation and Q2 is defined by the formula Q2=Q1+B(T2−T1), wherein B denotes a constant factor which is greater than 0; a reaction system suitable for performing the process for the epoxidation of an olefin; a computer program product which comprises a computer readable program recorded on a computer readable medium, suitable for instructing a data processing system of a computer system to execute calculations for the process for the epoxidation of an olefin; and a computer system which comprises the computer program product and a data processing system.

    Abstract translation: 一种烯烃环氧化方法，该方法包括在高反应温度T下在高度选择性的银基催化剂存在下使包含烯烃，氧和反应调节剂的进料反应，并且反应改性剂存在于 相对量Q是进料中存在的反应改性剂的活性物质的有效摩尔量与进料中存在的有效摩尔量的烃的比例，该方法包括以下步骤：在第一操作阶段 T的值为T 1 N且Q的值为Q 1 N 1，随后在与所用反应温度不同的反应温度下在第二操作阶段 在第一操作阶段中，使得T的值为T 2，并且Q的值基本上为Q 2，其中Q 2是 通过计算确定，并且Q <2>由公式<β在线定义 -formulae description =“In-line Formulas”end =“lead”？> Q＆lt; 2＆gt; = Q 1＆lt; 1＆gt; + B（T 2＆lt; 2＆gt; <？in-line-formula description =“In-line formula”end =“tail”？>其中B表示大于0的常数因子; 适于进行烯烃环氧化方法的反应体系; 计算机程序产品，其包括记录在计算机可读介质上的计算机可读程序，适于指示计算机系统的数据处理系统执行烯烃的环氧化方法的计算; 以及包括计算机程序产品和数据处理系统的计算机系统。

    Process and systems for the epoxidation of an olefin
    2.
    发明授权
    Process and systems for the epoxidation of an olefin 失效
    用于烯烃环氧化的方法和系统

    公开(公告)号：US07657332B2

    公开(公告)日：2010-02-02

    申请号：US11670338

    申请日：2007-02-01

    Applicant: Peter Ingraham Chipman ,  Jeffrey Michael Kobe ,  Arjan Jan Te Raa ,  Leonid Isaakovich Rubinstein ,  Brian Scott Vanderwilp ,  Thijs Wermink

    Inventor： Peter Ingraham Chipman ,  Jeffrey Michael Kobe ,  Arjan Jan Te Raa ,  Leonid Isaakovich Rubinstein ,  Brian Scott Vanderwilp ,  Thijs Wermink

    IPC: G05B13/00

    CPC classification number: C07D301/10

    Abstract: A process for the epoxidation of an olefin, which process comprises reacting a feed comprising the olefin, oxygen and a reaction modifier in the presence of a highly selective silver-based catalyst at a reaction temperature T, and with the reaction modifier being present in a relative quantity Q which is the ratio of an effective molar quantity of active species of the reaction modifier present in the feed to an effective molar quantity of hydrocarbons present in the feed, and which process comprises the steps of: operating at a first operating phase wherein the value of T is T1 and the value of Q is Q1, and subsequently operating at a second operating phase at a reaction temperature which is different from the reaction temperature employed in the first operating phase, such that the value of T is T2 and the value of Q is substantially Q2, whereby Q2 is determined by calculation and Q2 is defined by the formula Q2=Q1+B(T2−T1), wherein B denotes a constant factor which is greater than 0; a reaction system suitable for performing the process for the epoxidation of an olefin; a computer program product which comprises a computer readable program recorded on a computer readable medium, suitable for instructing a data processing system of a computer system to execute calculations for the process for the epoxidation of an olefin; and a computer system which comprises the computer program product and a data processing system.

    Abstract translation: 一种烯烃环氧化方法，该方法包括在高反应温度T下，在高度选择性的银基催化剂存在下使包含烯烃，氧和反应调节剂的进料反应，并且反应改性剂存在于 相对量Q是进料中存在的反应改性剂的活性物质的有效摩尔量与进料中存在的有效摩尔量的烃的比例，该方法包括以下步骤：在第一操作阶段 T的值为T1，Q值为Q1，随后在与第一运行阶段中使用的反应温度不同的反应温度下在第二运行阶段运行，使得T的值为T2， Q值基本上为Q2，由此通过计算确定Q2，Q2由公式Q2 = Q1 + B（T2-T1）定义，其中B表示大于0的常数因子 ; 适于进行烯烃环氧化方法的反应体系; 计算机程序产品，其包括记录在计算机可读介质上的计算机可读程序，适于指示计算机系统的数据处理系统执行烯烃的环氧化方法的计算; 以及包括计算机程序产品和数据处理系统的计算机系统。

    PROCESS FOR THE SELECTIVE HYDROGENATION AND HYDRODESULFERIZATION OF A PYROLYSIS GASOLINE FEEDSTOCK
    4.
    发明申请
    PROCESS FOR THE SELECTIVE HYDROGENATION AND HYDRODESULFERIZATION OF A PYROLYSIS GASOLINE FEEDSTOCK 有权
    热分解氢化反应的选择性加氢和加氢处理

    公开(公告)号：US20120108866A1

    公开(公告)日：2012-05-03

    申请号：US13376531

    申请日：2010-06-09

    Applicant: Dane Clark Grenoble ,  Paul Bejerman Himelfarb ,  Michael Norris Treybig ,  Brian Scott Vanderwilp

    Inventor： Dane Clark Grenoble ,  Paul Bejerman Himelfarb ,  Michael Norris Treybig ,  Brian Scott Vanderwilp

    IPC: C07C7/163

    CPC classification number: C10G45/32 ,  C10G45/02 ,  C10G69/06 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2300/4018 ,  C10G2300/4081 ,  C10G2400/30

    Abstract: Disclosed is a process for the selective hydrogenation of diolefins and sulfur compounds that are contained in a pyrolysis gasoline feedstream. The process includes utilizing a single hydrotreating reaction stage by introducing the pyrolysis gasoline feedstock that includes a diolefin concentration and an organic sulfur concentration into a reactor that is loaded with a high activity hydrotreating catalyst and which is operated under selective hydrogenation conditions. A reactor effluent having a reduced diolefin concentration and a reduced organic sulfur concentration is yielded from the reactor and is separated into a portion that is recycled as a reactor feed. The remaining portion of the reactor effluent is passed downstream for further processing or handling.

    Abstract translation: 公开了一种用于选择氢化包含在热解汽油原料流中的二烯烃和硫化合物的方法。 该方法包括通过将包含二烯烃浓度和有机硫浓度的裂解汽油原料引入装载有高活性加氢处理催化剂并在选择性氢化条件下操作的反应器中来利用单一加氢处理反应阶段。 从反应器产生具有降低的二烯烃浓度和降低的有机硫浓度的反应器流出物，并将其分离成作为反应器进料循环的部分。 反应器流出物的剩余部分通过下游进行进一步处理或处理。

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