Process for hydrogenation of aromatics in hydrocarbon feedstocks containing thiopheneic compounds
    2.
    发明授权
    Process for hydrogenation of aromatics in hydrocarbon feedstocks containing thiopheneic compounds 有权
    含有噻吩化合物的烃原料中芳族化合物的氢化方法

    公开(公告)号:US07230148B2

    公开(公告)日:2007-06-12

    申请号:US11397063

    申请日:2006-04-04

    IPC分类号: C07C5/10

    CPC分类号: C10G45/48

    摘要: The present invention relates to an improved process for the hydrogenation of aromatics in hydrocarbon feedstocks containing thiopheneic compounds as impurities, the aromatics hydrogenation being conducted in a hydrogenation reactor in the presence of a nickel based catalyst. The improvement comprises operating the hydrogenation reactor at a reaction temperature sufficiently high from the start of a run, that the thiopheneic compounds are decomposed and substantially absorbed into the bulk of the nickel catalyst, thereby substantially extending the life of the catalyst.

    摘要翻译: 本发明涉及一种用于在含有作为杂质的噻吩化合物的烃原料中芳族化合物氢化的改进方法,所述芳族化合物在氢化反应器中在镍基催化剂存在下进行。 改进之处在于从开始运行的反应温度足够高的操作氢化反应器,使噻吩化合物分解并充分吸收到镍催化剂的主体中,从而大大延长了催化剂的使用寿命。

    PROCESS FOR THE DEEP DESULFURIZATION OF HEAVY PYROLYSIS GASOLINE
    4.
    发明申请
    PROCESS FOR THE DEEP DESULFURIZATION OF HEAVY PYROLYSIS GASOLINE 有权
    重度热解汽油的深度脱硫方法

    公开(公告)号:US20100288679A1

    公开(公告)日:2010-11-18

    申请号:US12208410

    申请日:2008-09-11

    IPC分类号: C10G45/36 C10G45/32 C10G9/16

    摘要: A process for the deep desulfurization of a heavy pyrolysis gasoline to very low levels of organic sulfur, e.g., 30 ppmv or less, with minimal octane number loss through aromatics saturation. The deep desulfurization is accomplished by contacting the heavy pyrolysis gasoline feedstock, partially in liquid and partially in gaseous phase, with a hydrogen treat gas containing a minimum H2S level in the presence of a hydrogenation catalyst in a one or two reactor system operated in trickle flow, using a low temperature, moderate pressure operating condition.

    摘要翻译: 将重质热解汽油深度脱硫至非常低水平的有机硫(例如30ppmv或更低)的方法,通过芳烃饱和度具有最小的辛烷值损失。 通过在氢化催化剂存在下在一个或两个在滴流中操作的反应器系统中使重质裂解汽油原料部分地在液态和部分气相中与氢气处理气体接触,从而实现深度脱硫 ,使用低温,中等压力的操作条件。

    Process for the deep desulfurization of heavy pyrolysis gasoline
    6.
    发明授权
    Process for the deep desulfurization of heavy pyrolysis gasoline 有权
    重质裂解汽油深度脱硫工艺

    公开(公告)号:US08163167B2

    公开(公告)日:2012-04-24

    申请号:US12208410

    申请日:2008-09-11

    IPC分类号: C10G45/36 C10G45/32 C10G9/16

    摘要: A process for the deep desulfurization of a heavy pyrolysis gasoline to very low levels of organic sulfur, e.g., 30 ppmv or less, with minimal octane number loss through aromatics saturation. The deep desulfurization is accomplished by contacting the heavy pyrolysis gasoline feedstock, partially in liquid and partially in gaseous phase, with a hydrogen treat gas containing a minimum H2S level in the presence of a hydrogenation catalyst in a one or two reactor system operated in trickle flow, using a low temperature, moderate pressure operating condition.

    摘要翻译: 将重质热解汽油深度脱硫至非常低水平的有机硫(例如30ppmv或更低)的方法,通过芳烃饱和度具有最小的辛烷值损失。 通过在氢化催化剂存在下在一个或两个在滴流中操作的反应器系统中使重质裂解汽油原料部分地在液态和部分气相中与氢气处理气体接触,从而实现深度脱硫 ,使用低温,中等压力的操作条件。

    Process for hydrogenation of aromatics in hydrocarbon feedstocks containing thiopheneic compounds
    8.
    发明授权
    Process for hydrogenation of aromatics in hydrocarbon feedstocks containing thiopheneic compounds 失效
    含有噻吩化合物的烃原料中芳族化合物的氢化方法

    公开(公告)号:US07081555B2

    公开(公告)日:2006-07-25

    申请号:US10213996

    申请日:2002-08-07

    IPC分类号: C07C5/10

    CPC分类号: C10G45/48

    摘要: The present invention relates to an improved process for the hydrogenation of aromatics in hydrocarbon feedstocks containing thiopheneic compounds as impurities, the aromatics hydrogenation being conducted in a hydrogenation reactor in the presence of a nickel based catalyst. The improvement comprises operating the hydrogenation reactor at a reaction temperature sufficiently high from the start of a run, that the thiopheneic compounds are decomposed and substantially absorbed into the bulk of the nickel catalyst, thereby substantially extending the life of the catalyst.

    摘要翻译: 本发明涉及一种用于在含有作为杂质的噻吩化合物的烃原料中芳族化合物氢化的改进方法,所述芳族化合物在氢化反应器中在镍基催化剂存在下进行。 改进之处在于从开始运行的反应温度足够高的操作氢化反应器,使噻吩化合物分解并充分吸收到镍催化剂的主体中,从而大大延长了催化剂的使用寿命。