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公开(公告)号:US4237204A
公开(公告)日:1980-12-02
申请号:US88828
申请日:1979-10-29
Applicant: Arthur H. Thompson , Charles R. Symon , Allan J. Jacobson
Inventor: Arthur H. Thompson , Charles R. Symon , Allan J. Jacobson
Abstract: The present invention is directed to an electric current-producing cell which contains:(a) an anode having as its anode-active material one or more metals selected from a group consisting of Periodic Table Group Ia metals, Group Ib metals, Group IIa metals and Group IIb metals;a cathode, comprising:(i) metalized containment means having a plurality of apertures therein, said apertures having an average cross-sectional dimension of about 1 to about 100 microns; and(ii) cathode-active molybdenum sulfide contained within said metalized containment means; and(c) an electrolyte which is chemically inert with respect to said anode and said cathode and which permits the migration of ions between said anode and said cathode.
Abstract translation: 本发明涉及一种电流产生电池,其包含:(a)阳极,其具有作为其阳极活性材料的一种或多种金属,其选自周期表第Ia族金属,第Ib族金属,第IIa族金属 和IIb族金属; 阴极,包括:(i)金属化的容纳装置,其中具有多个孔,所述孔具有约1至约100微米的平均横截面尺寸; 和(ii)包含在所述金属化容纳装置内的阴极活性硫化钼; 和(c)相对于所述阳极和所述阴极化学惰性的电解质,并允许离子在所述阳极和所述阴极之间迁移。
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2.
公开(公告)号:US5767037A
公开(公告)日:1998-06-16
申请号:US516890
申请日:1995-08-18
Applicant: Teh Chung Ho , Charles R. Symon , Viktor Buchholz , Michel Daage
Inventor: Teh Chung Ho , Charles R. Symon , Viktor Buchholz , Michel Daage
IPC: B01J31/18 , B01J23/28 , B01J23/30 , B01J23/88 , B01J37/08 , B01J37/18 , C10G45/46 , C10G45/50 , C10G65/08 , B01J27/051 , C07C5/10 , C10G47/02
CPC classification number: B01J23/8898 , B01J23/28 , B01J23/30 , B01J23/88 , B01J37/086 , B01J37/18 , C10G45/46 , C10G45/50 , C10G65/08
Abstract: The present invention is directed toward a highly active aromatics hydrogenation catalyst and its use. The catalyst composition is prepared by: (a) decomposing a catalyst precursor selected from the group consisting of metal amine molybdates, metal amine tungstates and mixtures thereof, wherein said metal amine catalyst precursor has the general formula ML(Mo.sub.y W.sub.1-y O.sub.4)a where M is Cr and/or one or more divalent promoter metals selected from the group consisting of Mn, Fe, Co, Ni, Cu and Zn; L is one or more neutral nitrogen containing ligands at least one of which is a chelating polydentate ligand; 0.ltoreq.y.ltoreq.1; and a=1 for non-chromium containing catalysts and wherein 0.5.ltoreq.a.ltoreq.3 for chromium containing catalysts, at a temperature of about 200.degree. to about 400.degree. C. in an inert atmosphere; and (b) reducing at a temperature of about 300.degree. to about 450.degree. C. said metal amine catalyst precursor to form a catalyst. The catalyst as prepared above may be used in an aromatics hydrogenation process. The invention is further directed to the use of such catalysts in aromatics hydrogenation processes.
Abstract translation: 本发明涉及高活性芳烃氢化催化剂及其用途。 催化剂组合物通过以下步骤制备:(a)分解选自钼酸金属胺,钨酸金属胺及其混合物的催化剂前体,其中所述金属胺催化剂前体具有通式ML(MoyW1-yO4)a其中M 是选自Mn,Fe,Co,Ni,Cu和Zn中的Cr和/或一种或多种二价助催化剂金属; L是一种或多种中性含氮配体,其中至少一种是螯合多齿配体; 0 = y = 1; 对于不含铬的催化剂,a = 1,对于含铬催化剂,在惰性气氛中在约200℃至约400℃的温度下,其中0.5 3; 和(b)在约300℃至约450℃的温度下还原所述金属胺催化剂前体以形成催化剂。 上述制备的催化剂可用于芳族化合物氢化方法。 本发明进一步涉及这种催化剂在芳族化合物加氢方法中的用途。
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