公开(公告)号：US4504652A

公开(公告)日：1985-03-12

申请号：US603591

申请日：1984-04-25

申请人： Charles R. Widder ,  Don S. Wozniak

发明人： Charles R. Widder ,  Don S. Wozniak

IPC分类号： C08G18/42 ,  C08G63/20 ,  C08L27/06 ,  C08L67/00 ,  C08L75/08 ,  C08G63/70

CPC分类号： C08G63/20 ,  C08G18/4238 ,  C08L27/06 ,  C08L67/00 ,  C08L75/08

摘要： Disclosed is a method for reducing the odor and/or improving the performance of polyester plasticizers of the type made from a dibasic acid, a polyol, and a chain terminator wherein a molar excess of alcohol ingredients is used. Such improved polyester plasticizer is made by subjecting the polyester plasticizer to a second stage reaction with a treating agent reactive with hydroxyl groups to reduce the hydroxyl value to no more than about 4. Preferably, the low acid number of the initial polyester plasticizer is maintained. The treating agent can be monofunctional or poly-functional, though preferably a difunctional isocyanate is used. Conventional thermoplastic substrates, typified by polyvinyl chloride, can be plasticized with the novel polyester plasticizers of the present invention.

摘要翻译： 公开了一种降低由二元酸，多元醇和链终止剂制成的类型的聚酯增塑剂的气味和/或改进其中使用摩尔过量的醇成分的方法。 这种改进的聚酯增塑剂通过使聚酯增塑剂与与羟基反应的处理剂进行第二阶段反应来制备，以将羟基值降低至不大于约4.优选地，保持初始聚酯增塑剂的低酸值。 处理剂可以是单官能或多官能的，尽管优选使用双官能异氰酸酯。 用聚氯乙烯代表的常规热塑性基材可以用本发明的新型聚酯增塑剂增塑。