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    Process for production of dihydric phenols
    2.
    发明授权
    Process for production of dihydric phenols 失效
    二元酚生产工艺

    公开(公告)号：US4560808A

    公开(公告)日：1985-12-24

    申请号：US688377

    申请日：1985-01-02

    申请人： Victor Mark ,  Charles V. Hedges

    发明人： Victor Mark ,  Charles V. Hedges

    IPC分类号： C07C37/48 ,  C07C39/16

    CPC分类号： C07C37/48 ,  C07C319/22

    摘要： A transalkylation process for the preparation of dihydric phenols comprising reacting, in the presence of an acid or base catalyst, at least one mole of an aromatic monohydroxy compound such as a phenol with at least one mole of an aromatic dihydroxy compound such as a dihydric phenol, thereby forming at least one dihydric phenol which is different than said aromatic dihydroxy compound.

    摘要翻译： 一种用于制备二元酚的烷基转移方法，包括在酸或碱催化剂存在下使至少一摩尔芳族单羟基化合物如苯酚与至少一摩尔芳族二羟基化合物如二元酚反应 从而形成与所述芳族二羟基化合物不同的至少一种二元酚。

    Flame retardant aromatic polycarbonate compositions made from fluorinated diphenols
    4.
    发明授权
    Flame retardant aromatic polycarbonate compositions made from fluorinated diphenols 失效
    由氟化二酚制成的阻燃芳族聚碳酸酯组合物

    公开(公告)号：US4379910A

    公开(公告)日：1983-04-12

    申请号：US221460

    申请日：1980-12-31

    申请人： Victor Mark ,  Charles V. Hedges

    发明人： Victor Mark ,  Charles V. Hedges

    IPC分类号： C08L67/02 ,  C08G63/00 ,  C08G64/00 ,  C08L67/00 ,  C08L69/00 ,  C08G63/62

    CPC分类号： C08L69/00

    摘要： Improved flame retardance is imparted to high molecular weight aromatic polycarbonate resins by selecting appropriate fluorinated diphenols and incorporating them in homopolymers or copolymers. The fluorinated diphenols have at least one fluorinated alkyl or fluorinated aryl group upon the methylene carbon atom positioned between the two phenol ring structures. The polycarbonates having improved flame retardance are made from fluorinated diphenols and halogen-containing carbonate precursors. Copolycarbonates having improved flame retardance are derived from the fluorinated diphenols and non-fluorinated diphenols. The flame retardant polycarbonates may be used in films and molded articles where improved resistance to flame is desirable.

    摘要翻译： 通过选择适当的氟化二酚并将其并入均聚物或共聚物中，可以对高分子量芳族聚碳酸酯树脂赋予更好的阻燃性。 氟化二酚在位于两个酚环结构之间的亚甲基碳原子上具有至少一个氟化烷基或氟化芳基。 具有改善的阻燃性的聚碳酸酯由氟化二酚和含卤素的碳酸酯前体制成。 具有改善的阻燃性的共聚碳酸酯衍生自氟化二酚和非氟化二酚。 阻燃聚碳酸酯可以用于薄膜和模塑制品中，其中希望提高耐火焰性。

    Fluorinated monophenols and diphenols and method for their preparation
    5.
    发明授权
    Fluorinated monophenols and diphenols and method for their preparation 失效
    氟化单酚和二酚及其制备方法

    公开(公告)号：US4358624A

    公开(公告)日：1982-11-09

    申请号：US221703

    申请日：1980-12-31

    申请人： Victor Mark ,  Charles V. Hedges

    发明人： Victor Mark ,  Charles V. Hedges

    IPC分类号： C07C27/00 ,  C07C37/11 ,  C07C37/16 ,  C07C37/20 ,  C07C39/24 ,  C07C39/26 ,  C07C39/367 ,  C07C67/00 ,  C07C39/14

    CPC分类号： C07C37/20 ,  C07C37/115 ,  C07C37/16 ,  C07C39/24 ,  C07C39/26 ,  C07C39/367

    摘要： Phenol reactants and fluorinated aldehydes or fluorinated ketones are reacted in the presence of organic sulfonic acid catalysts to yield fluorinated monophenols and fluorinated diphenols. Fluorinated monophenols can be isolated and reacted with additional phenol reactant in the presence of organic sulfonic acid catalysts to yield asymmetrical, as well as symmetrical, fluorinated diphenols. A preferred organic sulfonic acid catalyst is methanesulfonic acid. The novel fluorinated monophenols have a hydroxy group and a fluorinated aryl radical or fluorinated alkyl radical substituted upon the benzylic carbon atom. The novel fluorinated diphenols have at least one fluorinated aryl radical or fluorinated alkyl radical substituted upon the methylene carbon atom of the bisphenol.

    摘要翻译： 苯酚反应物和氟化醛或氟化酮在有机磺酸催化剂的存在下反应，得到氟化单酚和氟化二酚。 在有机磺酸催化剂的存在下，可以分离氟化单酚并与另外的酚反应物反应，以产生不对称以及对称的氟化二酚。 优选的有机磺酸催化剂是甲磺酸。 该新型氟化单酚具有在苄基碳原子上取代的羟基和氟化芳基或氟化烷基。 该新型氟化二酚具有在双酚的亚甲基碳原子上取代的至少一个氟化芳基或氟化烷基。

    Dihydric phenols
    8.
    发明授权
    Dihydric phenols 失效
    二元酚

    公开(公告)号：US4535191A

    公开(公告)日：1985-08-13

    申请号：US582946

    申请日：1984-02-23

    申请人： Victor Mark ,  Charles V. Hedges

    发明人： Victor Mark ,  Charles V. Hedges

    IPC分类号： C08G64/06 ,  C07C39/16 ,  C07C39/24

    CPC分类号： C08G64/06 ,  C07C39/16

    摘要： Novel polycarbonates are provided which exhibit rubbery and elastomeric properties which are the polymerized reaction products of:(i) a carbonate precursor; and(ii) at least one dihydric phenol represented by the general formula ##STR1## wherein R is selected from straight chain alkyl radicals containing from 8 to about 30 carbon atoms;each R.sup.1 is independently selected from halogen monovalent hydrocarbon, and monovalent hydrocarbonoxy radicals;each R.sup.2 is independently selected from halogen, monovalent hydrocarbon, and monovalent hydrocarbonoxy radicals; andn and n' are independently selected from whole numbers having a value of from 0 to 4 inclusive.

    摘要翻译： 提供新的聚碳酸酯，其表现出橡胶和弹性体性质，其是以下的聚合反应产物：（i）碳酸酯前体; 和（ii）由通式“IMAGE”表示的至少一种二元酚，其中R选自含有8至约30个碳原子的直链烷基; 每个R 1独立地选自卤素一价烃和一价烃氧基; 每个R 2独立地选自卤素，一价烃和一价烃氧基; n和n'独立地选自0〜4的整数。

    Fluorinated diphenols and method for their preparation
    9.
    发明授权
    Fluorinated diphenols and method for their preparation 失效
    氟化二酚及其制备方法

    公开(公告)号：US4467121A

    公开(公告)日：1984-08-21

    申请号：US402165

    申请日：1982-07-26

    申请人： Victor Mark ,  Charles V. Hedges

    发明人： Victor Mark ,  Charles V. Hedges

    IPC分类号： C07C37/11 ,  C07C37/20 ,  C07C39/367 ,  C07C39/16

    CPC分类号： C07C37/115 ,  C07C37/16 ,  C07C37/20 ,  C07C39/367

    摘要： Fluorinated bisphenols having a fluorinated alkyl group and a hydrogen atom upon the methylene carbon atom are prepared at atmospheric pressure or at low pressures from a phenol reactant and a fluorinated aldehyde compound in the presence of gaseous hydrogen chloride or gaseous hydrogen bromide catalyst. The fluorinated bisphenols having the fluorinated alkyl group and a hydrogen atom upon the methylene carbon atom are produced in excellent yields and are used for making flame-retardant polycarbonates and polyester-carbonate copolymers.

    摘要翻译： 在气态氯化氢或溴化氢气体气体催化剂存在下，在大气压或低压下由苯酚反应物和氟化醛化合物制备具有氟代烷基和亚甲基碳原子上的氢原子的氟化双酚。 具有氟代烷基和亚甲基碳原子上的氢原子的氟化双酚以优异的收率生产，并用于制备阻燃聚碳酸酯和聚酯 - 碳酸酯共聚物。