公开(公告)号：US08193296B2

公开(公告)日：2012-06-05

申请号：US12827360

申请日：2010-06-30

申请人： Hideyuki Ishii ,  Hsin Cheng ,  Chien-Hsin Chou ,  Chung-Yu Huang ,  Yasushi Ichikawa ,  Chen-Tai Liu

发明人： Hideyuki Ishii ,  Hsin Cheng ,  Chien-Hsin Chou ,  Chung-Yu Huang ,  Yasushi Ichikawa ,  Chen-Tai Liu

IPC分类号： A63B37/12 ,  A63B37/00 ,  C08G18/67 ,  C08G18/86

CPC分类号： A63B37/0087 ,  A63B37/0003 ,  A63B37/0024 ,  A63B37/0031 ,  A63B37/0041 ,  A63B37/0086 ,  A63B37/12 ,  C08G18/3206 ,  C08G18/4854 ,  C08G18/6511 ,  C08G18/6705

摘要： This disclosure relates to golf balls made from a crosslinked thermoplastic polyurethane elastomer. The crosslinked thermoplastic polyurethane elastomer includes crosslinks located in the hard segments, where the crosslinks being the reaction product of unsaturated bonds located in the hard segments as catalyzed by a free radical initiator. The crosslinks may be formed from an unsaturated diol as a chain extender. The unsaturated diol may be trimethylolpropane monoallylether (TMPME). The golf ball may include the crosslinked thermoplastic polyurethane elastomer in the cover layer, in which case the cover layer may exhibit a high degree of scuff resistance.

摘要翻译： 本公开涉及由交联的热塑性聚氨酯弹性体制成的高尔夫球。 交联的热塑性聚氨酯弹性体包括位于硬链段中的交联，其中交联作为由自由基引发剂催化的位于硬链段中的不饱和键的反应产物。 交联物可以由不饱和二醇作为扩链剂形成。 不饱和二醇可以是三羟甲基丙烷单烯丙基醚（TMPME）。 高尔夫球可以在覆盖层中包括交联的热塑性聚氨酯弹性体，在这种情况下，覆盖层可以表现出高度的抗磨损性。

公开(公告)号：US20120004351A1

公开(公告)日：2012-01-05

申请号：US12827352

申请日：2010-06-30

申请人： Chung-Yu Huang ,  Kuo-I Lee

发明人： Chung-Yu Huang ,  Kuo-I Lee

IPC分类号： C08L75/04 ,  C08K3/04 ,  C08K3/34 ,  C08L1/02 ,  C08K3/22 ,  C08G18/71 ,  C08K5/3492

CPC分类号： C08G18/4854 ,  C08G18/675 ,  C08G18/7671 ,  C08K3/011 ,  C08K3/04 ,  C08K3/041 ,  C08K3/045 ,  C08G18/48 ,  C08L75/04

摘要： This disclosure is directed to crosslinked thermoplastic polyurethane elastomers that include allyl ether side groups in the urethane structure, specifically in the hard segments of the polyurethane polymer, and a free radical source. This disclosure is also directed to methods of synthesizing the crosslinked thermoplastic polyurethane elastomers having allyl ether side groups in the hard segments. The solvent resistance, water resistance, weather resistance, and heat resistance are improved as a result of the urethanes elastomers being prepared according to this disclosure. As a result of these improved properties, the finished crosslinked polyurethane elastomers can be applied in articles such as footwear parts or soles, tubes, hoses, cables, films and sheets.

摘要翻译： 本公开涉及在聚氨酯结构中包括烯丙基醚侧基的交联热塑性聚氨酯弹性体，特别是聚氨酯聚合物的硬链段和自由基源。 本公开还涉及在硬链段中合成具有烯丙基醚侧基的交联的热塑性聚氨酯弹性体的方法。 作为根据本公开制备的聚氨酯弹性体的结果，耐溶剂性，耐水性，耐候性和耐热性得到改善。 作为这些改进的性能的结果，成品交联的聚氨酯弹性体可以应用于诸如鞋类部件或鞋底，管，软管，电缆，薄膜和片材的制品中。

公开(公告)号：US20120225738A1

公开(公告)日：2012-09-06

申请号：US13470703

申请日：2012-05-14

申请人： Hideyuki Ishii ,  Hsin Cheng ,  Chien-Hsin Chou ,  Chung-Yu Huang ,  Yasushi Ichikawa ,  Chen-Tai Liu

发明人： Hideyuki Ishii ,  Hsin Cheng ,  Chien-Hsin Chou ,  Chung-Yu Huang ,  Yasushi Ichikawa ,  Chen-Tai Liu

IPC分类号： A63B37/12 ,  C08G18/32

CPC分类号： A63B37/0087 ,  A63B37/0003 ,  A63B37/0024 ,  A63B37/0031 ,  A63B37/0041 ,  A63B37/0086 ,  A63B37/12 ,  C08G18/3206 ,  C08G18/4854 ,  C08G18/6511 ,  C08G18/6705

摘要： This disclosure relates to golf balls made from a crosslinked thermoplastic polyurethane elastomer. The crosslinked thermoplastic polyurethane elastomer includes crosslinks located in the hard segments, where the crosslinks being the reaction product of unsaturated bonds located in the hard segments as catalyzed by a free radical initiator. The crosslinks may be formed from an unsaturated diol as a chain extender. The unsaturated diol may be trimethylolpropane monoallylether (TMPME). The golf ball may include the crosslinked thermoplastic polyurethane elastomer in the cover layer, in which case the cover layer may exhibit a high degree of scuff resistance.

摘要翻译： 本公开涉及由交联的热塑性聚氨酯弹性体制成的高尔夫球。 交联的热塑性聚氨酯弹性体包括位于硬链段中的交联，其中交联作为由自由基引发剂催化的位于硬链段中的不饱和键的反应产物。 交联物可以由不饱和二醇作为扩链剂形成。 不饱和二醇可以是三羟甲基丙烷单烯丙基醚（TMPME）。 高尔夫球可以在覆盖层中包括交联的热塑性聚氨酯弹性体，在这种情况下，覆盖层可以表现出高度的抗磨损性。

公开(公告)号：US20120077621A1

公开(公告)日：2012-03-29

申请号：US13193391

申请日：2011-07-28

申请人： Hideyuki Ishii ,  Hsin Cheng ,  Chien-Hsin Chou ,  Chung-Yu Huang ,  Yasushi Ichikawa ,  Chen-Tai Liu

发明人： Hideyuki Ishii ,  Hsin Cheng ,  Chien-Hsin Chou ,  Chung-Yu Huang ,  Yasushi Ichikawa ,  Chen-Tai Liu

IPC分类号： A63B37/06 ,  A63B37/12

CPC分类号： A63B37/12 ,  A63B37/0003 ,  A63B37/0024 ,  A63B37/0031 ,  A63B37/0041 ,  A63B37/0045 ,  A63B37/0064 ,  A63B37/0086 ,  A63B37/0087 ,  C08F290/147 ,  C08G18/4854 ,  C08G18/6674 ,  C08G18/675 ,  C08G18/7671 ,  C08L75/14

摘要： This disclosure relates to four-piece golf balls having an outer cover layer made from a crosslinked thermoplastic polyurethane elastomer. The crosslinked thermoplastic polyurethane elastomer includes crosslinks located in the hard segments, where the crosslinks being the reaction product of unsaturated bonds located in the hard segments catalyzed by a free radical initiator. The crosslinks may be formed from an unsaturated diol as a chain extender. The unsaturated diol may be trimethylolpropane monoallylether (TMPME). The four-piece golf ball may include an inner core layer formed from a highly neutralized acid polymer composition. The four-piece golf ball may also include an outer core layer formed from a polybutadiene rubber. The golf ball may exhibit a high degree of scuff resistance.

摘要翻译： 本公开涉及具有由交联的热塑性聚氨酯弹性体制成的外覆层的四片高尔夫球。 交联的热塑性聚氨酯弹性体包括位于硬链段中的交联，其中交联作为由自由基引发剂催化的硬链段中的不饱和键的反应产物。 交联物可以由不饱和二醇作为扩链剂形成。 不饱和二醇可以是三羟甲基丙烷单烯丙基醚（TMPME）。 四片高尔夫球可以包括由高度中和的酸性聚合物组合物形成的内芯层。 四件式高尔夫球还可以包括由聚丁二烯橡胶形成的外芯层。 高尔夫球可能表现出高度的抗磨损性。

公开(公告)号：US20120004052A1

公开(公告)日：2012-01-05

申请号：US12827360

申请日：2010-06-30

申请人： Chien-Hsin Chou ,  Chung-Yu Huang ,  Chen-Tai Liu ,  Hsin Cheng ,  Yasushi Ichikawa

发明人： Chien-Hsin Chou ,  Chung-Yu Huang ,  Chen-Tai Liu ,  Hsin Cheng ,  Yasushi Ichikawa

IPC分类号： A63B37/12 ,  A63B37/00 ,  A63B37/06

CPC分类号： A63B37/0087 ,  A63B37/0003 ,  A63B37/0024 ,  A63B37/0031 ,  A63B37/0041 ,  A63B37/0086 ,  A63B37/12 ,  C08G18/3206 ,  C08G18/4854 ,  C08G18/6511 ,  C08G18/6705

摘要： This disclosure relates to golf balls made from a crosslinked thermoplastic polyurethane elastomer. The crosslinked thermoplastic polyurethane elastomer includes crosslinks located in the hard segments, where the crosslinks being the reaction product of unsaturated bonds located in the hard segments as catalyzed by a free radical initiator. The crosslinks may be formed from an unsaturated diol as a chain extender. The unsaturated diol may be trimethylolpropane monoallylether (TMPME). The golf ball may include the crosslinked thermoplastic polyurethane elastomer in the cover layer, in which case the cover layer may exhibit a high degree of scuff resistance.

公开(公告)号：US20120115637A1

公开(公告)日：2012-05-10

申请号：US13193289

申请日：2011-07-28

申请人： Hideyuki Ishii ,  Chien-Hsin Chou ,  Hsin Cheng ,  Chung-Yu Huang ,  Yasushi Ichikawa ,  Chen-Tai Liu

发明人： Hideyuki Ishii ,  Chien-Hsin Chou ,  Hsin Cheng ,  Chung-Yu Huang ,  Yasushi Ichikawa ,  Chen-Tai Liu

IPC分类号： A63B37/12

CPC分类号： B29C70/70 ,  A63B37/0003 ,  A63B37/0023 ,  A63B37/0024 ,  A63B37/0031 ,  A63B37/0037 ,  A63B37/0039 ,  A63B37/0059 ,  A63B37/0061 ,  A63B37/0076 ,  A63B37/12 ,  B29C45/14819 ,  C08F299/065 ,  C08G18/4854 ,  C08G18/6674 ,  C08G18/675 ,  C08G18/7671 ,  C08G18/86 ,  C08L75/14

摘要： This disclosure relates to golf balls having a cover layer made from a crosslinked thermoplastic polyurethane elastomer. The crosslinked thermoplastic polyurethane elastomer includes crosslinks located in the hard segments, where the crosslinks being the reaction product of unsaturated bonds located in the hard segments catalyzed by a free radical initiator. The crosslinks may be formed from an unsaturated diol as a chain extender. The unsaturated diol may be trimethylolpropane monoallylether (TMPME). The cover layer may have certain properties, such as a desirable flexural modulus value and a desirable Shore D hardness value, that further contribute to the golf ball having a high degree of scuff resistance.

摘要翻译： 本公开涉及具有由交联热塑性聚氨酯弹性体制成的覆盖层的高尔夫球。 交联的热塑性聚氨酯弹性体包括位于硬链段中的交联，其中交联作为由自由基引发剂催化的硬链段中的不饱和键的反应产物。 交联物可以由不饱和二醇作为扩链剂形成。 不饱和二醇可以是三羟甲基丙烷单烯丙基醚（TMPME）。 覆盖层可以具有某些特性，例如期望的弯曲模量值和期望的肖氏D硬度值，其进一步有助于具有高抗磨损性的高尔夫球。