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    Condensation polymer containing copolymerized colorants derived from indigo and articles produced therefrom
    3.
    发明授权
    Condensation polymer containing copolymerized colorants derived from indigo and articles produced therefrom 失效
    含有衍生自靛蓝的共聚着色剂和由其制备的制品的缩合聚合物

    公开(公告)号：US4808677A

    公开(公告)日：1989-02-28

    申请号：US153635

    申请日：1988-02-08

    申请人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

    发明人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Wayne P. Pruett ,  Samuel D. Hilbert

    IPC分类号： C08G63/685 ,  C09B69/10 ,  C08G63/20

    CPC分类号： C09B69/109 ,  C08G63/685

    摘要： Disclosed are colored compositions useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising condensation polymer having reacted therewith or copolymerized therein a coloring amount of the residue of a colorant compound having the formula; ##STR1## wherein R.sup.1 is ##STR2## carbonyl halide or an unsubstituted or substituted carbocyclic or hetrocyclic aryl radical;R.sup.2 is hydrogen or an unsubstituted or substituted alkyl or acyl radical;R.sup.3 is any of the substituents which R.sup.1 may represent; andA.sup.1 and A.sup.2 each is the residue of a fused benzene ring; whereinR.sup.4 is hydrogen, allyl or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical; andR.sup.5 is hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical; provided the colorant compound bears at least one substituent that is reactive with one of the monomers from which the condensation polymer is derived.The colorant compound residues are present in the polymer chain and impart a red color to the polymer. The residues are nonextractable from the polymer and stable at the condition at which the polymers are prepared and processed.

    摘要翻译： 公开了可用于模制成诸如食品容器，饮料瓶，固化的结构塑料等制品的着色组合物，其包含与其反应或与其共聚的具有下式的着色剂化合物的着色量的缩聚物; 或者其中R 1为羰基卤或未取代或取代的碳环或杂环芳基的“IMAGE”或“IMAGE” R2是氢或未取代或取代的烷基或酰基; R3是R1可以表示的任何取代基; A1和A2各自为稠合苯环的残基; 其中R4是氢，烯丙基或未取代或取代的烷基，环烷基或芳基; 并且R 5是氢或未取代或取代的烷基，环烷基或芳基; 只要着色剂化合物具有至少一个与衍生缩合聚合物的单体之一反应的取代基。 着色剂化合物残基存在于聚合物链中并赋予聚合物红色。 残余物不可聚合，并且在制备和加工聚合物的条件下是稳定的。

    Thiophen-2-ylazopyrazole compounds as colorants for textile fibers
    4.
    发明授权
    Thiophen-2-ylazopyrazole compounds as colorants for textile fibers 失效
    噻吩-2-基吡唑化合物作为纺织纤维的着色剂

    公开(公告)号：US4568738A

    公开(公告)日：1986-02-04

    申请号：US590809

    申请日：1984-03-19

    申请人： Max A. Weaver ,  Clarence A. Coates, Jr.

    发明人： Max A. Weaver ,  Clarence A. Coates, Jr.

    IPC分类号： C09B29/00 ,  C09B29/46 ,  C09B29/033 ,  C09B29/36 ,  D06P3/26 ,  D06P3/36

    CPC分类号： C09B29/3652 ,  C09B29/0059

    摘要： Thiophen-2-ylazopyrazole dyes useful for dyeing polyesters, cellulose acetate esters, and polyamides in fast yellow shades have the general formula: ##STR1## wherein: X is alkyl, allyloxy, alkoxy, aryl, aryloxy, amino, alkylamino, arylamino, cyclohexyloxy,, thienyl, cycloalkylamino, N,N-dialkylamino, or N-alkyl-N-arylamino; Y is hydrogen, alkyl, or aryl; Z is alkyl, aryl, alkylsulfonyl, 2-benzothiazolyl, cyano or COX; R and R.sub.1 are alkyl or aryl; R.sub.2 is hydrogen, alkyl, aryl, acyl, benzothiazolyl, pyridyl, sulfolanyl, quinolyl, thiocarbamyl, carbamyl, alkoxycarbonyl, aroyl, aryl-carbamyl and alkanoyl; and wherein the hydrocarbon moieties of the above radicals may be substituted with up to three of --OH, alkoxy, hydroxyalkoxy, carbamyl, and similar groups conventionally used in the azo dye art.

    摘要翻译： 用于染色聚酯，乙酸纤维素酯和聚酰胺的噻吩-2-基吡唑类染料具有以下通式：其中：X为烷基，烯丙氧基，烷氧基，芳基，芳氧基，氨基，烷基氨基，芳基氨基，环己氧基 ，噻吩基，环烷基氨基，N，N-二烷基氨基或N-烷基-N-芳基氨基; Y是氢，烷基或芳基; Z是烷基，芳基，烷基磺酰基，2-苯并噻唑基，氰基或COX; R和R 1是烷基或芳基; R2是氢，烷基，芳基，酰基，苯并噻唑基，吡啶基，环丁砜基，喹啉基，硫代氨基甲酰基，氨基甲酰基，烷氧基羰基，芳酰基，芳基 - 氨基甲酰基和烷酰基。 并且其中上述基团的烃部分可被至多三个-OH，烷氧基，羟基烷氧基，氨基甲酰基以及常规用于偶氮染料领域的类似基团取代。

    AZO Dyes from 2-sulfonated, sulfated or thiosulfated organothiothiadiazole and aniline, tetrahydroquinoline, or benzomorpholine couplers
    5.
    发明授权
    AZO Dyes from 2-sulfonated, sulfated or thiosulfated organothiothiadiazole and aniline, tetrahydroquinoline, or benzomorpholine couplers 失效
    AZO来自2-磺化，硫酸化或硫代硫酸化的有机硫代二唑和苯胺，四氢喹啉或苯并吗啉成色剂的染料

    公开(公告)号：US4407749A

    公开(公告)日：1983-10-04

    申请号：US383885

    申请日：1982-06-01

    申请人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  John G. Fisher

    发明人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  John G. Fisher

    IPC分类号： C09B29/00 ,  C09B29/08 ,  C09B29/36 ,  C09B29/44

    CPC分类号： C09B29/0803 ,  C09B29/0092 ,  C09B29/3643 ,  C09B29/3686

    摘要： Disclosed are azo dyes having the general formula ##STR1## in which A is the residue of an aniline, tetrahydroquinoline or benzomorpholine disperse dye coupling component, R is a divalent organic radical such as straight or branched, lower or cyclic aliphatic or arylene, each of which may be substituted, Z is SO.sub.3, SO.sub.4 or SSO.sub.3, and M is hydrogen, an alkali metal or ammonium. These dyes produce orange to bluish red shades and exhibit one or more improved properties such as dyeability, light fastness, blooming, pH stability, build, and the like on, for example, polyamide, wool, and cellulose ester fibers.

    摘要翻译： 公开了具有通式“IMAGE”的偶氮染料，其中A是苯胺，四氢喹啉或苯并吗啉分散染料偶联组分的残基，R是二价有机基团，例如直链或支链，低级或环状脂族或亚芳基 其可以被取代，Z是SO 3，SO 4或SSO 3，M是氢，碱金属或铵。 这些染料产生橙色至蓝紫色的色调，并且在例如聚酰胺，羊毛和纤维素酯纤维上表现出一种或多种改进的性能，例如可染性，耐光性，起霜，pH稳定性，结构等。

    Azo dyes from 2-amino-5-organothio-1,3,4-thiadiazoles and N-cyanoethyl-m-acylamidoanilines
    6.
    发明授权
    Azo dyes from 2-amino-5-organothio-1,3,4-thiadiazoles and N-cyanoethyl-m-acylamidoanilines 失效
    来自2-氨基-5-有机硫代-1,3,4-噻二唑和N-氰乙基-m-酰基氨基苯胺的偶氮染料

    公开(公告)号：US4395368A

    公开(公告)日：1983-07-26

    申请号：US315108

    申请日：1981-10-26

    申请人： Max A. Weaver ,  Clarence A. Coates, Jr.

    发明人： Max A. Weaver ,  Clarence A. Coates, Jr.

    IPC分类号： C09B29/00 ,  C09B29/08 ,  C09B29/02 ,  C09B29/36

    CPC分类号： C09B29/0092 ,  C09B29/0823

    摘要： Disclosed are novel azo dyes from 2-amino-5-organothio-1,3,4-thiadiazoles and N-cyanoethyl-m-acylamidoanilines. These dyes are useful for dyeing synthetic hydrophobic fibers and particularly polyester. The dyes have the general formula: ##STR1## wherein R is alkyl, aryl or cycloalkyl; X is hydrogen, or alkyl; R.sub.1 is hydrogen, alkyl or aralkyl; and R.sub.2 is formyl or alkanoyl; and wherein the alkyl, aryl and cycloalkyl moieties of R and R.sub.2 may be substituted with a large variety of groups such as --OH, OOC-alkyl, --COO-alkyl, succinimido, phthalimido, alkoxy, carbamoyl and the like.

    摘要翻译： 公开了2-氨基-5-有机硫代-1,3,4-噻二唑和N-氰乙基-m-酰氨基苯胺的新偶氮染料。 这些染料可用于染色合成疏水性纤维，特别是聚酯。 染料具有以下通式：其中R是烷基，芳基或环烷基; X是氢或烷基; R1是氢，烷基或芳烷基; R2是甲酰基或烷酰基; 并且其中R和R 2的烷基，芳基和环烷基部分可以被大量各种基团取代，例如-OH，OOC-烷基，-COO-烷基，琥珀酰亚胺基，苯二甲酰亚氨基，烷氧基，氨基甲酰基等。

    Azo dyes from aminophthalimides and aniline, tetrahydroquinoline, and benzomorpholine couplers having thiosulfate groups
    7.
    发明授权
    Azo dyes from aminophthalimides and aniline, tetrahydroquinoline, and benzomorpholine couplers having thiosulfate groups 失效
    具有硫代硫酸盐基团的氨基邻苯二甲酰亚胺和苯胺的偶氮染料，四氢喹啉和苯并吗啉成色剂

    公开(公告)号：US4324719A

    公开(公告)日：1982-04-13

    申请号：US159093

    申请日：1980-06-13

    申请人： Max A. Weaver ,  Clarence A. Coates, Jr.

    发明人： Max A. Weaver ,  Clarence A. Coates, Jr.

    IPC分类号： C09B29/00 ,  C09B29/08 ,  C09B29/36 ,  C09B29/44 ,  C09B29/036 ,  D06P3/26

    CPC分类号： C09B29/3686 ,  C09B29/0033 ,  C09B29/0803 ,  C09B29/3643

    摘要： Disclosed are azo dyes suitable for coloring polyamide material, particularly nylon carpet and which are prepared from aminophthalimides and couplers which are ##STR1## substituted with a thiosulfate ester group. These dyes produce yellow to blue shades and also color cellulose acetate fabrics and wool. The dyes have the general formula: ##STR2## wherein R.sup.2 and R.sup.4 are each selected from hydrogen and a large variety of organic substituents, the coupler C is an aniline, 1,2,3,4-tetrahydroquinoline, or benzomorpholine derivative wherein a Q-SSO.sub.3 M group is attached to the nitrogen thereof, Q being a lower alkylene or similar linking group, and M is Na.sup.+, K.sup.+, NH.sub.4.sup.+, or H.sup.+. The present dyes are superior in such properties as fastness to light, oxides of nitrogen, wash, ozone, sublimation, perspiration and crock, and exhibit good dyeability including migration, leveling, pH stability, and build.

    摘要翻译： 公开了适用于着色聚酰胺材料，特别是尼龙地毯的偶氮染料，其由氨基邻苯二甲酰亚胺和由硫代硫酸酯基取代的成色剂制备。 这些染料产生黄色至蓝色的色调，并且还会着色醋酸纤维素织物和羊毛。 染料具有以下通式：其中R 2和R 4各自选自氢和大量有机取代基，成色剂C是苯胺，1,2,3,4-四氢喹啉或苯并吗啉衍生物，其中Q -SSO 3 M基团连接到其氮上，Q是低级亚烷基或类似的连接基团，M是Na +，K +，NH 4 +或H +。 本发明的染料具有如光牢度，氮氧化物，洗涤剂，臭氧，升华，排汗和烘干等特性的优异性，并且显示出良好的染色性，包括迁移，流平，pH稳定性和构建。

    Azo dyes derived from 5-membered heterocyclic amines and aromatic amine couplers containing sulfo groups, or salts thereof
    8.
    发明授权
    Azo dyes derived from 5-membered heterocyclic amines and aromatic amine couplers containing sulfo groups, or salts thereof 失效
    衍生自5元杂环胺和含有磺基的芳族胺成色剂的偶氮染料或其盐

    公开(公告)号：US4282144A

    公开(公告)日：1981-08-04

    申请号：US44446

    申请日：1979-06-01

    申请人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Jean C. Fleischer

    发明人： Max A. Weaver ,  Clarence A. Coates, Jr. ,  Jean C. Fleischer

    IPC分类号： C09B29/033 ,  C09B29/08 ,  C09B29/09 ,  C09B29/36 ,  C09B29/44 ,  C09B29/22 ,  C09B31/14 ,  C09B31/28 ,  C09B62/08

    CPC分类号： C09B29/0803 ,  C09B29/0025 ,  C09B29/3643 ,  C09B29/3686

    摘要： Disclosed are mono azo dyes derived from diazotized 5-membered heterocyclic amines and certain aniline, 1,2,3,4-tetrahydroquinoline, and benzomorpholine couplers containing sulfoalkyl groups. These dyes impart fast violet to blue shades on polyamide fibers and have the general formulaD--N.dbd.N--Couplerwherein D is a thiadiazol, isothiazol, pyrazol or thiophene type radical, and the Coupler is an aniline, tetrahydroquinoline, or benzomorpholine derivative wherein a --Z--SO.sub.3 M group is attached to the nitrogen thereof, the coupler ring may contain one or more substituents selected from lower alkyl, lower alkoxy, halogen, acylamido, alkylthio or aryloxy, the remaining hydrogen of the aniline coupler may be replaced by a substituent such as lower alkyl, substituted lower alkyl, lower alkenyl, aryl, or cycloalkyl, M is Na.sup.+, K.sup.+, NH.sub.4.sup.+ or H.sup.+, and Z is a linking group such as ethylene.

    摘要翻译： 公开了衍生自重氮化的5元杂环胺和某些苯胺，1,2,3,4-四氢喹啉和含有磺基烷基的苯并吗啉成色剂的单偶氮染料。 这些染料赋予聚酰胺纤维上的蓝色紫色，并具有通式DN = N-对映体，其中D是噻二唑，异噻唑，吡唑或噻吩型自由基，并且所述成色剂是苯胺，四氢喹啉或苯并吗啉衍生物，其中α- Z-SO 3 M基团连接到其氮上，成色剂环可以含有一个或多个选自低级烷基，低级烷氧基，卤素，酰氨基，烷硫基或芳氧基的取代基，苯胺偶合剂的剩余氢可以被取代基 作为低级烷基，取代的低级烷基，低级烯基，芳基或环烷基，M是Na +，K +，NH4 +或H +，Z是连接基团，例如乙烯。