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    In-mold decorated articles and methods
    1.
    发明授权
    In-mold decorated articles and methods 有权
    模内装饰物品和方法

    公开(公告)号：US07364677B2

    公开(公告)日：2008-04-29

    申请号：US10849277

    申请日：2004-05-18

    申请人： Joseph P. Vadala, Jr. ,  Levi A. Kishbaugh ,  Kevin J. Levesque ,  David E. Pierick

    发明人： Joseph P. Vadala, Jr. ,  Levi A. Kishbaugh ,  Kevin J. Levesque ,  David E. Pierick

    IPC分类号： B29C44/06

    CPC分类号： B29C44/12 ,  B29C44/348 ,  B32B3/26 ,  B32B5/18 ,  Y10T428/249978

    摘要： The invention provides in-mold decorated articles and methods to form the articles. The in-mold decorated articles include a polymeric portion having a substrate material adhered to a surface of the polymeric portion. The substrate material may be, for example, a film or a fabric. In some embodiments, the polymeric portion may be a foam and, particularly, a microcellular polymeric material. The articles are formed by injecting a mixture of blowing agent and polymeric material into a mold cavity in which the substrate material is disposed, so that the substrate material is forced against a wall of the mold cavity. The blowing agent, which in certain preferred cases is a supercritical fluid, decreases the viscosity of the polymeric material and, therefore, enables reductions in injection pressures and temperatures. Reduced injection temperature and pressure may widen the processing window, increase flexibility in the selection of substrate materials, and can eliminate the need for a barrier layer that is sometimes used in conventional processes. The method may be used to produce a variety of in-mold decorated articles.

    摘要翻译： 本发明提供了模内装饰的物品和形成物品的方法。 模内装饰制品包括具有粘附到聚合物部分的表面上的基底材料的聚合物部分。 衬底材料可以是例如膜或织物。 在一些实施方案中，聚合物部分可以是泡沫，特别是微孔聚合材料。 通过将发泡剂和聚合物材料的混合物注入到其中设置有基底材料的模腔中而形成制品，使得基底材料被迫抵靠模腔的壁。 在某些优选情况下是超临界流体的发泡剂降低了聚合物材料的粘度，因此能够降低注射压力和温度。 降低的注射温度和压力可以加宽加工窗口，增加衬底材料选择的灵活性，并且可以消除对有时在常规工艺中使用的阻挡层的需要。 该方法可用于生产各种模内装饰物品。

    IN-MOLD DECORATED ARTICLES AND METHODS
    2.
    发明申请
    IN-MOLD DECORATED ARTICLES AND METHODS 审中-公开
    IN-MOLD装饰文章和方法

    公开(公告)号：US20080187741A1

    公开(公告)日：2008-08-07

    申请号：US12101355

    申请日：2008-04-11

    申请人： Joseph P. Vadala ,  Levi A. Kishbaugh ,  Kevin J. Levesque ,  David E. Pierick

    发明人： Joseph P. Vadala ,  Levi A. Kishbaugh ,  Kevin J. Levesque ,  David E. Pierick

    IPC分类号： B32B3/26 ,  B29C45/14 ,  C08J9/00

    CPC分类号： B29C44/12 ,  B29C44/348 ,  B32B3/26 ,  B32B5/18 ,  Y10T428/249978

    摘要： The invention provides in-mold decorated articles and methods to form the articles. The in-mold decorated articles include a polymeric portion having a substrate material adhered to a surface of the polymeric portion. The substrate material may be, for example, a film or a fabric. In some embodiments, the polymeric portion may be a foam and, particularly, a microcellular polymeric material. The articles are formed by injecting a mixture of blowing agent and polymeric material into a mold cavity in which the substrate material is disposed, so that the substrate material is forced against a wall of the mold cavity. The blowing agent, which in certain preferred cases is a supercritical fluid, decreases the viscosity of the polymeric material and, therefore, enables reductions in injection pressures and temperatures. Reduced injection temperature and pressure may widen the processing window, increase flexibility in the selection of substrate materials, and can eliminate the need for a barrier layer that is sometimes used in conventional processes. The method may be used to produce a variety of in-mold decorated articles.

    摘要翻译： 本发明提供了模内装饰的物品和形成物品的方法。 模内装饰制品包括具有粘附到聚合物部分的表面上的基底材料的聚合物部分。 衬底材料可以是例如膜或织物。 在一些实施方案中，聚合物部分可以是泡沫，特别是微孔聚合材料。 通过将发泡剂和聚合物材料的混合物注入到其中设置有基底材料的模腔中而形成制品，使得基底材料被迫抵靠模腔的壁。 在某些优选情况下是超临界流体的发泡剂降低了聚合物材料的粘度，因此能够降低注射压力和温度。 降低的注射温度和压力可以加宽加工窗口，增加衬底材料选择的灵活性，并且可以消除对有时在常规工艺中使用的阻挡层的需要。 该方法可用于生产各种模内装饰物品。

    Embrittlement-resistant polyolefin composition and flexible articles therefrom
    7.
    发明授权
    Embrittlement-resistant polyolefin composition and flexible articles therefrom 失效
    耐脆性聚烯烃组合物及其柔性制品

    公开(公告)号：US5929147A

    公开(公告)日：1999-07-27

    申请号：US665785

    申请日：1996-06-18

    申请人： David E. Pierick ,  Thomas J. O'Neal

    发明人： David E. Pierick ,  Thomas J. O'Neal

    IPC分类号： A61L2/08 ,  C08K5/00 ,  C08K5/103 ,  C08K5/3435 ,  C08K5/5419 ,  C08K5/544 ,  C08L23/08 ,  C08L23/10 ,  C08L23/16

    CPC分类号： C08K5/0008 ,  C08K5/5442 ,  C08L23/10 ,  C08L23/0815 ,  C08L23/16 ,  Y10T428/139

    摘要： An embrittlement-resistant polyolefin composition, including: (a) at least 80% by weight, based on the total weight of the polyolefin composition, of a crystalline polymer comprising either a propylene homopolymer having an isotactic index greater than 90 or a random copolymer of propylene and either ethylene or C.sub.4 -C.sub.10 1-olefins, (b) an elastomeric copolymer of ethylene and either propylene or butene-1, where the elastomeric copolymer is present in an amount sufficient to enhance the flexibility of the polyolefin composition, without adversely affecting the clarity of the polyolefin composition, and where the polyolefin composition has a heat distortion temperature of at least 60.degree. C. Optional components include a stabilizing amount of a hindered amine light stabilizer, an acid neutralizing agent, and a sorbitol-based compound. The composition may be used to manufacture medical articles and food packaging material which must be sterilized, either by irradiation or by autoclaving.

    摘要翻译： 一种耐脆性聚烯烃组合物，包括：（a）基于聚烯烃组合物的总重量，至少80重量％的结晶聚合物包含全同立构指数大于90的丙烯均聚物或无规共聚物 丙烯和乙烯或C 4 -C 10 1-烯烃，（b）乙烯和丙烯或丁烯-1的弹性共聚物，其中弹性共聚物的存在量足以增强聚烯烃组合物的柔韧性，而不会不利地影响 聚烯烃组合物的透明度，以及聚烯烃组合物的热变形温度为至少60℃的任何组分，包括稳定量的受阻胺光稳定剂，酸中和剂和山梨糖醇基化合物。 组合物可用于制造必须通过照射或通过高压灭菌消毒的医疗制品和食品包装材料。