公开(公告)号：US4339458A

公开(公告)日：1982-07-13

申请号：US147728

申请日：1980-05-08

申请人： George Holan ,  David F. O'Keefe

发明人： George Holan ,  David F. O'Keefe

IPC分类号： C07C69/74 ,  A01N33/20 ,  A01N37/08 ,  A01N37/10 ,  A01N37/34 ,  A01N37/38 ,  A01N37/48 ,  A01N43/08 ,  A01N43/30 ,  C07C51/00 ,  C07C61/15 ,  C07C61/39 ,  C07C61/40 ,  C07C62/12 ,  C07C62/34 ,  C07C67/00 ,  C07C69/753 ,  C07C69/757 ,  C07C201/00 ,  C07C205/55 ,  C07C253/00 ,  C07C255/38 ,  C07C313/00 ,  C07C323/62 ,  C07D307/42 ,  C07D317/60 ,  C07D317/68 ,  A01N43/16

CPC分类号： A01N37/48 ,  A01N37/08 ,  A01N37/10 ,  A01N37/34 ,  A01N37/38 ,  A01N43/08 ,  A01N43/30 ,  C07C61/15 ,  C07C61/40 ,  C07C62/12 ,  C07C62/34 ,  C07C69/753 ,  C07C69/757 ,  C07D317/60

摘要： Compounds of the general formula I ##STR1## wherein R.sup.1 is hydrogen or a methoxy, ethoxy, propoxy, butoxy, tetrafluoroethoxy, methylthio, ethylthio, propylthio, fluoro, chloro, bromo, methyl, ethyl, or nitro group, and R.sup.2 is hydrogen or a methyl group, or R.sup.1 and R.sup.2 together form a methylenedioxy group;R.sup.3 is hydrogen, or a lower alkyl group, or one of the following groups (a) to (f):(a) 3-phenoxybenzyl(b) 2-benzyl-4-furylmethyl(c) .alpha.-cyano-3-phenoxybenzyl(d) 3,4-methylenedioxybenzyl(e) .alpha.-ethynyl-3-phenoxybenzyl(f) .alpha.-cyano-3-(4'-chlorophenoxy)-benzyland Y.sup.1, Y.sup.2, Y.sup.3, Y.sup.4, Y.sup.5 and Y.sup.6 are the same or different groups and each is hydrogen or a fluoro, bromo or chloro group, with the proviso that when R.sup.1 is hydrogen, fluoro, chloro, bromo or methyl and R.sup.2 is hydrogen, then one of Y.sup.1 to Y.sup.6 is other than hydrogen.The compounds in which R.sup.3 is one of groups (a) to (f) are insecticides.

公开(公告)号：US4235926A

公开(公告)日：1980-11-25

申请号：US969862

申请日：1978-12-15

申请人： George Holan ,  David F. O'Keefe

发明人： George Holan ,  David F. O'Keefe

IPC分类号： C07C69/74 ,  A01N33/20 ,  A01N37/08 ,  A01N37/10 ,  A01N37/34 ,  A01N37/38 ,  A01N37/48 ,  A01N43/08 ,  A01N43/30 ,  C07C51/00 ,  C07C61/15 ,  C07C61/39 ,  C07C61/40 ,  C07C62/12 ,  C07C62/34 ,  C07C67/00 ,  C07C69/753 ,  C07C69/757 ,  C07C201/00 ,  C07C205/55 ,  C07C253/00 ,  C07C255/38 ,  C07C313/00 ,  C07C323/62 ,  C07D307/42 ,  C07D317/60 ,  C07D317/68 ,  A01N43/16 ,  C07D317/44

CPC分类号： A01N37/48 ,  A01N37/08 ,  A01N37/10 ,  A01N37/34 ,  A01N37/38 ,  A01N43/08 ,  A01N43/30 ,  C07C61/15 ,  C07C61/40 ,  C07C62/12 ,  C07C62/34 ,  C07C69/753 ,  C07C69/757 ,  C07D317/60

摘要： Compounds of the general formula I ##STR1## wherein R.sup.1 is hydrogen or a methoxy, ethoxy, propoxy, butoxy, tetrafluoroethoxy, methylthio, ethylthio, propylthio, fluoro, chloro, bromo, methyl, ethyl, or nitro group, and R.sup.2 is hydrogen or a methyl group, or R.sup.1 and R.sup.2 together form a methylenedioxy group;R.sup.3 is hydrogen, or a lower alkyl group, or one of the following groups (a) to (f):(a) 3-phenoxybenzyl(b) 2-benzyl-4-furylmethyl(c) .alpha.-cyano-3-phenoxybenzyl(d) 3,4-methylenedioxybenzyl(e) .alpha.-ethynyl-3-phenoxybenzyl(f) .alpha.-cyano-3-(4'-chlorophenoxy)-benzyland Y.sup.1, Y.sup.2, Y.sup.3, Y.sup.4, Y.sup.5 and Y.sup.6 are the same or different groups and each is hydrogen or a fluoro, bromo or chloro group, with the proviso that when R.sup.1 is hydrogen, fluoro, chloro, bromo or methyl and R.sup.2 is hydrogen, then one of Y.sup.1 to Y.sup.6 is other than hydrogen.The compounds in which R.sup.3 is one of groups (a) to (f) are insecticides.

摘要翻译： 通式I的化合物其中R 1是氢或甲氧基，乙氧基，丙氧基，丁氧基，四氟乙氧基，甲硫基，乙硫基，丙硫基，氟，氯，溴，甲基，乙基或硝基，R 2是氢或 甲基或R1和R2一起形成亚甲二氧基; R3是氢或低级烷基，或下列基团之一（a）至（f）：（a）3-苯氧基苄基（b）2-苄基-4-呋喃基甲基（c）α-氰基-3-苯氧基苄基 （d）（e）α-乙炔基-3-苯氧基苄基（f）α-氰基-3-（4'-氯苯氧基） - 苄基和Y1，Y2，Y3，Y4，Y5和Y6的3,4-亚甲二氧基苄基是相同的 或不同的基团，并且各自为氢或氟，溴或氯基团，条件是当R 1为氢，氟，氯，溴或甲基且R 2为氢时，则Y 1至Y 6中的一个不是氢。 R3（a）〜（f）中的一种化合物是杀虫剂。

公开(公告)号：US4348409A

公开(公告)日：1982-09-07

申请号：US050209

申请日：1979-06-20

申请人： George Holan ,  David F. O'Keefe

发明人： George Holan ,  David F. O'Keefe

IPC分类号： C07C69/74 ,  A01N33/20 ,  A01N37/08 ,  A01N37/10 ,  A01N37/34 ,  A01N37/38 ,  A01N37/48 ,  A01N43/08 ,  A01N43/30 ,  C07C51/00 ,  C07C61/15 ,  C07C61/39 ,  C07C61/40 ,  C07C62/12 ,  C07C62/34 ,  C07C67/00 ,  C07C69/753 ,  C07C69/757 ,  C07C201/00 ,  C07C205/55 ,  C07C253/00 ,  C07C255/38 ,  C07C313/00 ,  C07C323/62 ,  C07D307/42 ,  C07D317/60 ,  C07D317/68 ,  C07C149/40

CPC分类号： A01N37/48 ,  A01N37/08 ,  A01N37/10 ,  A01N37/34 ,  A01N37/38 ,  A01N43/08 ,  A01N43/30 ,  C07C61/15 ,  C07C61/40 ,  C07C62/12 ,  C07C62/34 ,  C07C69/753 ,  C07C69/757 ,  C07D317/60

摘要： Compounds of the general formula I ##STR1## wherein R.sup.1 is hydrogen or a methoxy, ethoxy, propoxy, butoxy, tetrafluoroethoxy, methylthio, ethylthio, propylthio, fluoro, chloro, bromo, methyl, ethyl, or nitro group, and R.sup.2 is hydrogen or a methyl group, or R.sup.1 and R.sup.2 together form a methylenedioxy group; R.sup.3 is hydrogen, or a lower alkyl group, or one of the following groups (a) to (f):(a) 3-phenoxybenzyl(b) 2-benzyl-4-furylmethyl(c) .alpha.-cyano-3-phenoxybenzyl(d) 3,4-methylenedioxybenzyl(e) .alpha.-ethynyl-3-phenoxybenzyl(f) .alpha.-cyano-3-(4'-chlorophenoxy)-benzyland Y.sup.1, Y.sup.2, Y.sup.3, Y.sup.4, Y.sup.5 and Y.sup.6 are the same or different groups and each is hydrogen or a fluoro, bromo or chloro group, with the proviso that when R.sup.1 is hydrogen, fluoro, chloro, bromo or methyl and R.sup.2 is hydrogen, then one of Y.sup.1 to Y.sup.6 is other than hydrogen.The compounds in which R.sup.3 is one of groups (a) to (f) are insecticides.

公开(公告)号：US4390715A

公开(公告)日：1983-06-28

申请号：US282190

申请日：1981-07-10

申请人： George Holan ,  David F. O'Keefe

发明人： George Holan ,  David F. O'Keefe

IPC分类号： C07C69/753 ,  A01N37/08 ,  A01N37/38 ,  A01N43/30 ,  A01N53/00 ,  A01N53/06 ,  C07C69/757 ,  C07D317/60 ,  C07C69/76

CPC分类号： A01N37/38 ,  A01N37/08 ,  A01N53/00

摘要： The (+), (-) and (.+-.) forms of the compounds of the general formula (I) ##STR1## characterized in that R.sup.1 is a halo group; or a lower alkyl, lower alkoxy or lower alkylthio group, each of which may be substituted with one or more halo groups;R.sup.2 is hydrogen or a methyl group; or R.sup.1 and R.sup.2 together form a methylenedioxy, or a difluoromethylenedioxy group or, with the carbon atoms to which they are attached, an aromatic or heteroaromatic ring; andA is one of the groups X or Y ##STR2## wherein X.sup.1 and X.sup.2 are the same or different and each is hydrogen or a fluoro, chloro, bromo or methyl group, with the proviso that if X.sup.1 is a fluoro group, then X.sup.2 should not be a bromo group; and X.sup.3 and X.sup.4 are the same or different and each is hydrogen or a fluoro group; andY.sup.1, Y.sup.2, Y.sup.3, Y.sup.4, Y.sup.5 and Y.sup.6 are the same or different groups and each is hydrogen or a fluoro, bromo, chloro, or methyl group.The compounds (I) are insecticidally active.

摘要翻译： 通式（I）化合物（I）的（+），（ - ）和（+/-）形式，其特征在于R1为卤素基团; 或低级烷基，低级烷氧基或低级烷硫基，每一个可被一个或多个卤素基团取代; R2是氢或甲基; 或R 1和R 2一起形成亚甲二氧基或二氟亚甲二氧基，或与其连接的碳原子一起形成芳族或杂芳族环; 并且A是X或Y之一，其中X 1和X 2相同或不同，并且各自是氢或氟，氯，溴或甲基，条件是如果X 1是氟基，则X 2 不应该是溴族; X3和X4相同或不同，各自为氢或氟基; Y 1，Y 2，Y 3，Y 4，Y 5和Y 6为相同或不同的基团，各自为氢或氟，溴，氯或甲基。

公开(公告)号：US4355042A

公开(公告)日：1982-10-19

申请号：US195600

申请日：1980-10-09

申请人： George Holan ,  David F. O'Keefe

发明人： George Holan ,  David F. O'Keefe

IPC分类号： C07C69/74 ,  A01N33/20 ,  A01N37/08 ,  A01N37/10 ,  A01N37/34 ,  A01N37/38 ,  A01N37/48 ,  A01N43/08 ,  A01N43/30 ,  C07C51/00 ,  C07C61/15 ,  C07C61/39 ,  C07C61/40 ,  C07C62/12 ,  C07C62/34 ,  C07C67/00 ,  C07C69/753 ,  C07C69/757 ,  C07C201/00 ,  C07C205/55 ,  C07C253/00 ,  C07C255/38 ,  C07C313/00 ,  C07C323/62 ,  C07D307/42 ,  C07D317/60 ,  C07D317/68 ,  C07D307/40

CPC分类号： A01N37/48 ,  A01N37/08 ,  A01N37/10 ,  A01N37/34 ,  A01N37/38 ,  A01N43/08 ,  A01N43/30 ,  C07C61/15 ,  C07C61/40 ,  C07C62/12 ,  C07C62/34 ,  C07C69/753 ,  C07C69/757 ,  C07D317/60

摘要： Compounds of the general formula I ##STR1## wherein R.sup.1 is hydrogen or a methoxy, ethoxy, propoxy, butoxy, tetrafluoroethoxy, methylthio, ethylthio, propylthio, fluoro, chloro, bromo, methyl, ethyl, or nitro group, and R.sup.2 is hydrogen or a methyl group, orR.sup.1 and R.sup.2 together form a methylenedioxy group;R.sup.3 is hydrogen, or a lower alkyl group, or one of the following groups (a) to (f):(a) 3-phenoxybenzyl(b) 2-benzyl-4-furylmethyl(c) .alpha.-cyano-3-phenoxybenzyl(d) 3,4-methylenedioxybenzyl(e) .alpha.-ethynyl-3-phenoxybenzyl(f) .alpha.-cyano-3-(4'-chlorophenoxy)-benzyland Y.sup.1, Y.sup.2, Y.sup.3, Y.sup.4, Y.sup.5 and Y.sup.6 are the same or different groups and each is hydrogen or a fluoro, bromo or chloro group, with the proviso that when R.sup.1 is hydrogen, fluoro, chloro, bromo or methyl and R.sup.2 is hydrogen, then one of Y.sup.1 to Y.sup.6 is other than hydrogen.The compounds in which R.sup.3 is one of groups (a) to (f) are insecticides.