Degradation of polycyclic aromatic hydrocarbons to render them available for biodegradation
    1.
    发明授权
    Degradation of polycyclic aromatic hydrocarbons to render them available for biodegradation 有权
    多环芳烃降解使其可用于生物降解

    公开(公告)号:US08557565B2

    公开(公告)日:2013-10-15

    申请号:US12053980

    申请日:2008-03-24

    摘要: A method for the degradation of polycyclic aromatic compounds is disclosed that involves dissolving ozone in a bipolar solvent comprising a non-polar solvent in which is of sufficiently non-polar character to solubilized the polycyclic aromatic compounds, and a polar-water-compatible solvent which is fully miscible with the non-polar solvent to form a single phase with the non-polar solvent. The bipolar solvent with dissolved ozone is contacted with the polycyclic aromatic compounds to solubilize the polycyclic aromatic compounds and react the dissolved polycyclic aromatic compounds with the ozone to degrade the dissolved polycyclic aromatic compounds to oxygenated intermediates. The bipolar solvent is then mixed with sufficient water to form separate non-polar and polar phases, the non-polar phase comprising the non-polar solvent and the polar phase comprising the non-polar solvent and the oxygenated intermediates. The polar phase is then diluted and incubated with bacteria to biodegrade the oxygenated intermediates.

    摘要翻译: 公开了一种降解多环芳族化合物的方法,其包括将臭氧溶解在包含非极性特性的非极性溶剂的双酚溶剂中,以溶解多环芳香族化合物,以及与极性 - 水相容的溶剂, 与非极性溶剂完全混溶,与非极性溶剂形成单相。 将溶解有臭氧的双极溶剂与多环芳族化合物接触,溶解多环芳族化合物,并将溶解的多环芳香族化合物与臭氧反应,将溶解的多环芳香化合物降解为含氧中间体。 然后将双极性溶剂与足量的水混合以形成分离的非极性和极性相,非极性相包含非极性溶剂和包含非极性溶剂和氧化中间体的极性相。 然后将极性相稀释并与细菌一起温育以使氧化的中间体生物降解。