公开(公告)号：US4645752A

公开(公告)日：1987-02-24

申请号：US748809

申请日：1985-06-25

申请人： Pierre Dufresne ,  Christian Marcilly ,  Dinh Chan Trinh

发明人： Pierre Dufresne ,  Christian Marcilly ,  Dinh Chan Trinh

IPC分类号： C10G11/05 ,  B01J23/22 ,  B01J29/076 ,  B01J29/72 ,  B01J31/28 ,  C10G11/00 ,  C10G45/12 ,  C10G47/16 ,  C10G47/20 ,  B01J29/12 ,  B01J29/22

CPC分类号： B01J29/076 ,  C10G47/20

摘要： The invention concerns a new catalyst containing (a) a zeolite carrier, (b) a metal from group VIII and (c) an additional metal selected from tin, germanium and lead, forming an alloy with the metal of group VIII, said additional metal being introduced as organic compound.The catalyst can be used, in particular, in hydrocarbon hydrocracking reactions.The figure of the accompanying drawing illustrates the conversion of n-heptane in the presence of a catalyst containing palladium and tin. Curve (A) illustrates this conversion at different temperatures, curves (B) and (C) giving the results after ageing of the catalyst.

摘要翻译： 本发明涉及一种新的催化剂，其包含（a）沸石载体，（b）来自VIII族的金属和（c）另一种选自锡，锗和铅的金属，与第VIII族金属形成合金，所述附加金属 作为有机化合物引入。 催化剂特别可用于烃类加氢裂化反应中。 附图示出了在含有钯和锡的催化剂存在下正庚烷的转化率。 曲线（A）示出了在不同温度下的转化，曲线（B）和（C）给出催化剂老化后的结果。

公开(公告)号：US4830997A

公开(公告)日：1989-05-16

申请号：US93273

申请日：1987-09-04

申请人： Dinh Chan Trinh ,  Alain Desvard ,  Germain Martino

发明人： Dinh Chan Trinh ,  Alain Desvard ,  Germain Martino

IPC分类号： C10G45/04 ,  B01J23/92 ,  B01J23/94 ,  B01J27/30 ,  B01J38/48 ,  B01J38/50 ,  C10G45/08

CPC分类号： B01J23/94 ,  B01J27/30 ,  Y10S502/516 ,  Y10S502/517

摘要： The process has as an object the regeneration of catalysts containing at least one contaminating metal of the vanadium, nickel and iron group. The operation is conducted as follows:(a) The catalyst (1) is roasted in the presence of an oxygen-containing gas so as to remove at least 90% of the sulfur;(b) The catalyst obtained in step (a) is contacted with a hydrogen peroxide aqueous solution containing at least one organic compound comprising an acidic functional group, so as to remove at least 10% of the deposited metals of the vanadium, nickel and iron group; and(c) The regenerated catalyst (11) is separated from the aqueous solution of metal ions (5). The latter can be regenerated by passage over a complexing resin (6).The process is applicable to the regeneration of used catalysts, particularly to hydrotreatment catalysts in the oil industry.

摘要翻译： 该方法的目的是使含有至少一种钒，镍和铁基团的污染金属的催化剂再生。 操作如下进行：（a）催化剂（1）在含氧气体存在下焙烧，以除去至少90％的硫; （b）将步骤（a）中获得的催化剂与含有至少一种包含酸性官能团的有机化合物的过氧化氢水溶液接触，以除去至少10％的钒，镍和铁的沉积金属 组; 和（c）将再生催化剂（11）与金属离子（5）的水溶液分离。 后者可以通过复合树脂（6）再生。 该方法适用于所用催化剂的再生，尤其适用于石油工业中的加氢处理催化剂。