Process for eliminating mercury and possibly arsenic in hydrocarbons
    1.
    发明授权
    Process for eliminating mercury and possibly arsenic in hydrocarbons 失效
    消除碳氢化合物中汞和可能的砷的方法

    公开(公告)号:US5401392A

    公开(公告)日:1995-03-28

    申请号:US148543

    申请日:1993-11-08

    摘要: For removing mercury and any arsenic in hydrocarbon charges containing mercury and sulfur, the charge is contacted with an arsenic collecting material having catalytic properties ("catalyst") in hydrogen, the material containing at least one metal selected from the group consisting of nickel, cobalt, iron, palladium, and platinum; at least one metal selected from the group consisting of chromium, molybdenum, tungsten, and uranium; and an active phase carrier. Downstream of the catalyst or mixed therewith is a mercury collecting material containing a sulfide of at least one metal selected from the group consisting of copper, iron, and silver or sulfur, and an active phase carrier.

    摘要翻译: 为了除去含有汞和硫的烃装料中的汞和任何砷,电荷与氢气中具有催化性质(“催化剂”)的砷收集材料接触,该材料含有选自镍,钴中的至少一种金属 ,铁,钯和铂; 选自铬,钼,钨和铀中的至少一种金属; 和活性载体。 催化剂的下游或与其混合的是含有选自铜,铁和银或硫的至少一种金属的硫化物的汞收集材料和活性相载体。

    Process for regenerating used catalysts by means of hydrogen peroxide
aqueous solution stabilized with an organic compound
    3.
    发明授权
    Process for regenerating used catalysts by means of hydrogen peroxide aqueous solution stabilized with an organic compound 失效
    通过用有机化合物稳定的过氧化氢水溶液再生所用催化剂的方法

    公开(公告)号:US4714688A

    公开(公告)日:1987-12-22

    申请号:US836866

    申请日:1986-03-07

    摘要: The process has as an object the regeneration catalysts containing at least one contaminating metal of the vanadium, nickel and iron group. The operation is conducted as follows:(a) The catalyst (1) is roasted in the presence of an oxygen-containing gas so as to remove at least 90% of the sulfur;(b) The catalyst obtained in step (a) is contacted with a hydrogen peroxide aqueous solution containing at least one organic compound including a polar functional group, so as to remove at least 10% of the deposited metals of the vanadium, nickel and iron group; and(c) The regenerated catalyst (11) is separated from the aqueous solution of metal ions (5). The latter can be regenerated by passage over a complexing resin (6).The process is applicable to the regerneration of used catalysts, particularly to hydrotreatment catalysts in the oil industry.

    摘要翻译: 该方法的目的是含有至少一种钒,镍和铁基团的污染金属的再生催化剂。 操作如下进行:(a)催化剂(1)在含氧气体存在下焙烧,以除去至少90%的硫; (b)将步骤(a)中获得的催化剂与含有至少一种包含极性官能团的有机化合物的过氧化氢水溶液接触,以除去至少10%的钒,镍和铁的沉积金属 组; 和(c)将再生催化剂(11)与金属离子(5)的水溶液分离。 后者可以通过复合树脂(6)再生。 该方法适用于二手催化剂的再生,特别是石油工业中的加氢处理催化剂。

    Catalysts for catalytic hydroreforming or for producing aromatic
hydrocarbons
    6.
    发明授权
    Catalysts for catalytic hydroreforming or for producing aromatic hydrocarbons 失效
    用于催化加氢成型或生产芳烃的催化剂

    公开(公告)号:US4239652A

    公开(公告)日:1980-12-16

    申请号:US53156

    申请日:1979-06-29

    摘要: Catalyst for a process of hydroreforming or aromatic hydrocarbon production, comprising an alumina carrier, at least one noble metal of the platinum family, antimony, a metal selected from gallium, indium and thallium and halogen, said catalyst being used in a series of successive reaction zones as a moving bed, transferred from one reaction zone to the next, from the last reaction zone to a regeneration zone and from the latter to the first reaction zone, said process being preferably conducted at a temperature from 510.degree. to 600.degree. C. and under a pressure from 1 to 18 kg/cm.sup.2.

    摘要翻译: 用于加氢精制或芳烃生产方法的催化剂,包括氧化铝载体,至少一种铂族贵金属,锑,选自镓,铟和铊和卤素的金属,所述催化剂用于一系列连续反应 作为移动床的区域,从一个反应区转移到下一个反应区,从最后一个反应区转移到再生区,从后一个反应区转移到第一个反应区,所述方法优选在510-600℃的温度下进行。 并在1至18kg / cm2的压力下进行。