摘要:
For removing mercury and any arsenic in hydrocarbon charges containing mercury and sulfur, the charge is contacted with an arsenic collecting material having catalytic properties ("catalyst") in hydrogen, the material containing at least one metal selected from the group consisting of nickel, cobalt, iron, palladium, and platinum; at least one metal selected from the group consisting of chromium, molybdenum, tungsten, and uranium; and an active phase carrier. Downstream of the catalyst or mixed therewith is a mercury collecting material containing a sulfide of at least one metal selected from the group consisting of copper, iron, and silver or sulfur, and an active phase carrier.
摘要:
A process for obtaining a tertiary olefin, e.g. isobutylene in a very pure state by decomposing the corresponding ether, e.g. methyl tert. butyl ether, in the presence of a catalyst constituted by silica, modified by the addition of at least one element or compound of an element preferably chosen from the group constituted by rubidium, cesium, magnesium, calcium, strontium, barium, gallium, lanthanum, cerium, praseodymium, neodymium and uranium and optionally by the addition of at least one element or compound of an element chosen from the group constituted by aluminium, titanium and zirconium.
摘要:
The process has as an object the regeneration catalysts containing at least one contaminating metal of the vanadium, nickel and iron group. The operation is conducted as follows:(a) The catalyst (1) is roasted in the presence of an oxygen-containing gas so as to remove at least 90% of the sulfur;(b) The catalyst obtained in step (a) is contacted with a hydrogen peroxide aqueous solution containing at least one organic compound including a polar functional group, so as to remove at least 10% of the deposited metals of the vanadium, nickel and iron group; and(c) The regenerated catalyst (11) is separated from the aqueous solution of metal ions (5). The latter can be regenerated by passage over a complexing resin (6).The process is applicable to the regerneration of used catalysts, particularly to hydrotreatment catalysts in the oil industry.
摘要:
Process for the production of a liquid effluent comprising at least 75% of aromatic hydrocarbons from a naphtha feed charge of high sulfur, nitrogen or oxygen content; said process comprises two steps: (a) hydrotreatment of the charge to decrease its sulfur, nitrogen or oxygen content to selected values, and (b) dehydrogenation of the product of step (a) in the presence of a supported catalyst whose neutralization heat by ammonia adsorption is lower than about 40 joules per gram at 300 mm Hg.
摘要翻译:用于生产包含至少75%的来自高硫,氮或氧含量的石脑油进料的芳烃的液体流出物的方法; 所述方法包括两个步骤:(a)加氢处理电荷以将其硫,氮或氧含量降低至所选值,和(b)步骤(a)的产物在负载型催化剂的存在下脱氢,所述催化剂的中和热由 氨吸附在300 mm Hg下低于约40焦耳/克。
摘要:
Reforming process operated in the presence of a catalyst comprising a carrier, platinum, rhodium or osmium, an additional metal consisting of chromium, tungsten, molybdenum, manganese, rhenium, germanium, tin, gallium, indium, thallium, thorium, cerium, samarium, lanthanum, zinc, cadmium, titanium or zirconium, and halogen.
摘要:
Catalyst for a process of hydroreforming or aromatic hydrocarbon production, comprising an alumina carrier, at least one noble metal of the platinum family, antimony, a metal selected from gallium, indium and thallium and halogen, said catalyst being used in a series of successive reaction zones as a moving bed, transferred from one reaction zone to the next, from the last reaction zone to a regeneration zone and from the latter to the first reaction zone, said process being preferably conducted at a temperature from 510.degree. to 600.degree. C. and under a pressure from 1 to 18 kg/cm.sup.2.
摘要:
New catalyst containing a carrier, platinum, iridium, manganese and optionally halogen. This catalyst is useful for reforming and dehydrogenation of hydrocarbons.
摘要:
A process for the regeneration of a sulfur containing catalysts, wherein the catalyst is stripped of sulfur before the oxychlorination treatment of the regeneration process, typically before the catalyst is sent to the regeneration zone. The process is particularly useful for catalyst employed in hydrocarbon conversions such as dehydrogenation reactions, particularly those which comprise the injection of sulfur and/or at least one sulfur compound before or simultaneously to the introduction of the charge into the first reaction zone.
摘要:
The invention relates to a process for producing an alkylbenzene from benzene and an aliphatic mono-olefin in the presence of a catalyst based on a dealuminized Y zeolite with a molar ratio SiO.sub.2 /Al.sub.2 O.sub.3 ranging from 8 to 70, the product of this reaction being afterwards fractionated into a first fraction containing non converted benzene and a mono-alkylbenzene and a second fraction containing a poly-alkylbenzene, said second fraction reacting then with benzene in the presence of a catalyst based on a dealuminized mordenite with a total atomic ratio Si/Al ranging from 30 to 80. The invention especially applies to the production of ethylbenzene and cumene respectively from ethylene and propene.
摘要翻译:本发明涉及一种在基于SiO 2 / Al 2 O 3的摩尔比为8至70的脱铝Y沸石的催化剂存在下由苯和脂族单烯烃生产烷基苯的方法,该反应产物之后 分馏成含有未转化的苯和单烷基苯的第一馏分和含有聚烷基苯的第二馏分,所述第二馏分在基于脱铝丝光沸石的催化剂存在下与苯反应,总原子比Si / Al 范围从30到80.本发明特别适用于从乙烯和丙烯生产乙苯和枯烯。
摘要:
A heavy hydrocarbon charge containing sulfur, asphaltenes and/or resins is hydrotreated in the liquid phase at 250.degree.-500.degree. C. under a pressure of 20-350 bars in the presence of a catalyst previously obtained by reacting an organic compound of a transition metal with an organic aluminum compound, in a hydrocarbon free of asphaltene and resin.The transition metal organic compound is advantageously an iron, nickel, cobalt, molybdenum, tungsten or vanadium acetylacetonate or carboxylate.