PROCESS FOR THE PRODUCTION OF HYDROGEN
    1.
    发明申请
    PROCESS FOR THE PRODUCTION OF HYDROGEN 审中-公开
    生产氢过程

    公开(公告)号:US20130209905A1

    公开(公告)日:2013-08-15

    申请号:US13701275

    申请日:2011-05-31

    IPC分类号: C01B3/06 H01M8/06 B01J31/22

    摘要: The present invention relates to a process for the production of hydrogen comprising contacting at least one complex of formula (I), wherein: X− is an anion; Y is N or CR6; M is selected from Ru, Os and Fe; each of A and B is independently a saturated, unsaturated or partially unsaturated carbocyclic ring; R5, R6 and R7 are each independently selected from H, NR24R25, C1-6-alkyl and C1-6-haloalkyl, or two or more of R5, R6 and R7 are linked, together with the carbons to which they are attached, to form a saturated or unsaturated carbocyclic group; R8-R25 are each independently selected from H, C1-6-alkyl, C1-6-haloalkyl and a linker group optionally attached to a solid support; with at least one substrate of formula (II), R1R2—NH—BH—R3R4 (II), wherein R1, R2, R3 and R4 are each independently selected from H, C1-20-alkyl, fluoro-substituted-C1-20-alkyl and C6-14-aryl, or any two of R1, R2, R3 and R4 are linked to form a C2-10-alkylene group, which together with the nitrogen and/or boron atoms to which they are attached, forms a cyclic group. Further aspects of the invention relate to a hydrogen generation system comprising a complex of formula (I), a substrate of formula (II) and a solvent, and to the use of complexes of formula (I) in fuel cells. Another aspect of the invention relates to novel complexes of formula (I).

    摘要翻译: 本发明涉及一种生产氢气的方法,包括使至少一种式(I)配合物与式I化合物接触,其中:X-是阴离子; Y为N或CR6; M选自Ru,Os和Fe; A和B各自独立地为饱和的,不饱和的或部分不饱和的碳环; R 5,R 6和R 7各自独立地选自H,NR 24 R 25,C 1-6 - 烷基和C 1-6 - 卤代烷基,或者R 5,R 6和R 7中的两个或更多个与它们所连接的碳一起连接到 形成饱和或不饱和碳环基团; R8-R25各自独立地选自H,C 1-6 - 烷基,C 1-6 - 卤代烷基和任选地连接到固体载体上的连接基团; 与式(II)的至少一个底物,R1R2-NH-BH-R3R4(II),其中R1,R2,R3和R4各自独立地选自H,C1-20烷基,氟取代的C1-20 - 烷基和C 6-14 - 芳基,或R 1,R 2,R 3和R 4中的任何两个连接形成C 2-10 - 亚烷基,它们与它们所连接的氮原子和/或硼原子一起形成 循环组。 本发明的另外方面涉及包含式(I)的配合物,式(II)的底物和溶剂的氢生成系统,以及在燃料电池中使用式(I)的络合物。 本发明的另一方面涉及式(I)的新型配合物。

    Herbicidal Compositions Comprising Flufenacet
    3.
    发明申请
    Herbicidal Compositions Comprising Flufenacet 审中-公开
    除草剂组合物

    公开(公告)号:US20110152091A1

    公开(公告)日:2011-06-23

    申请号:US12971429

    申请日:2010-12-17

    摘要: Herbicidal compositions are disclosed comprising an effective amount of flufenacet, diflufenican and metribuzin. A method of controlling harmful plants is disclosed. The compositions may be used flexibly, e.g, in post-emergent and/or pre-emergent applications. The compositions may be used prior to sowing a crop. The compositions may provide enhanced compatibility with crops. The compositions may be used on different soil types, e.g., with high-organic matter soils and/or at different soil depths, e.g., at shallow soil depths. The compositions may be used against herbicide-resistant plant species, for example EMR and TSR-resistant species and/or may be used for resistance management. The compositions may be used with various irrigation techniques.

    摘要翻译: 公开了除草组合物,其包含有效量的氟草胺,二氟芬酸和赛克津。 公开了一种控制有害植物的方法。 组合物可以灵活地使用,例如在芽后和/或出苗前应用中。 组合物可以在播种作物之前使用。 组合物可以提供与作物的增强的相容性。 组合物可以用于不同的土壤类型,例如具有高有机物质土壤和/或在不同的土壤深度,例如在较浅的土壤深度。 组合物可以用于抗除草剂的植物物种,例如EMR和耐TSR的物种和/或可用于抗性管理。 组合物可以与各种灌溉技术一起使用。

    Herbicidal Compositions Comprising Flufenacet
    4.
    发明申请
    Herbicidal Compositions Comprising Flufenacet 审中-公开
    除草剂组合物

    公开(公告)号:US20110152085A1

    公开(公告)日:2011-06-23

    申请号:US12971353

    申请日:2010-12-17

    摘要: Herbicidal compositions are disclosed comprising an effective amount of flufenacet and the other herbicide trifluralin. Further, a method of controlling harmful plants is disclosed. The disclosed herbicidal compositions have an improved application profile with regard to a simplified application process which reduces costs for the user and is thus more environmentally compatible. The herbicidal action on the weed plants is increased, and there is an enhanced crop compatibility. The disclosed herbicidal compositions have an improvement of crop plant compatibility and activity on addition of a safener on PE application and incorporation. The disclosed herbicidal compositions have an improved application flexibility of the active compounds extending into post-emergence of the crop and weed plants. The herbicidal action on the weed plants is increased, and there is an enhanced crop compatibility. The disclosed herbicidal compositions have an improved application flexibility of the active compounds which allows an application prior to sowing of the crop. The herbicidal action on the weed plants is increased with comparable crop compatibility. The disclosed herbicidal compositions have an improved reliability of action on soils having different soil properties. The application flexibility of the mixture on different soil types is improved. The disclosed herbicidal compositions have an improved reliability of action on resistant weed plant species. The reliability of action against TSR- and EMR-resistant plant species is markedly improved. The mixture is suitable for an effective resistance management.

    摘要翻译: 公开了除草组合物,其包含有效量的氟草丁和其它除草剂氟乐灵。 此外,公开了一种控制有害植物的方法。 所公开的除草组合物具有关于简化的施用过程的改进的应用轮廓,其降低了用户的成本并因此更环保地兼容。 对杂草植物的除草作用增加,作物相容性提高。 所公开的除草组合物在PE施用和掺入上添加安全剂后具有作物植物相容性和活性的改善。 所公开的除草组合物具有延长到作物和杂草植物后期的活性化合物的应用灵活性的改善。 对杂草植物的除草作用增加,作物相容性提高。 所公开的除草组合物具有改进的活性化合物的应用灵活性,其允许在播种作物之前施用。 对杂草植物的除草作用增加,具有可比的作物相容性。 所公开的除草组合物具有改进的具有不同土壤性质的土壤的作用可靠性。 混合物在不同土壤类型上的应用灵活性得到改善。 所公开的除草组合物具有改进的抗性杂草植物物种作用的可靠性。 对TSR和EMR抗性植物物种的作用可靠性明显提高。 该混合物适用于有效的电阻管理。

    Herbicidal compositions comprising flufenacet
    6.
    发明申请
    Herbicidal compositions comprising flufenacet 审中-公开
    除草剂组合物,包含氟草胺

    公开(公告)号:US20110152092A1

    公开(公告)日:2011-06-23

    申请号:US12971450

    申请日:2010-12-17

    摘要: Herbicidal compositions are disclosed comprising an effective amount of flufenacet, pendimethalin and diflufenican. A method of controlling harmful plants is disclosed. The compositions may be used flexibly, e.g., in post-emergent and/or pre-emergent applications. The compositions may be used prior to sowing a crop. The compositions may provide enhanced compatibility with crops. The compositions may be used on different soil types, e.g., with high-organic matter soils and/or at different soil depths, e.g., at shallow soil depths. The compositions may be used against herbicide-resistant plant species, for example EMR and TSR-resistant species and/or may be used for resistance management. The compositions may be used with various irrigation techniques.

    摘要翻译: 公开了除草组合物,其包含有效量的氟草丁,二甲戊乐灵和二氟芬酸。 公开了一种控制有害植物的方法。 组合物可以灵活地使用,例如在出苗后和/或出苗前应用中。 组合物可以在播种作物之前使用。 组合物可以提供与作物的增强的相容性。 组合物可以用于不同的土壤类型,例如具有高有机物质土壤和/或在不同的土壤深度,例如在较浅的土壤深度。 组合物可以用于抗除草剂的植物物种,例如EMR和耐TSR的物种和/或可用于抗性管理。 组合物可以与各种灌溉技术一起使用。