公开(公告)号：US4661525A

公开(公告)日：1987-04-28

申请号：US728636

申请日：1985-04-29

申请人： Michael V. Grazioso ,  Edwin R. Kerr, deceased

发明人： Michael V. Grazioso ,  Edwin R. Kerr, deceased

IPC分类号： C07C29/156 ,  C07C27/06

CPC分类号： C07C29/156 ,  C12C11/02

摘要： A method is provided for preparing a mixture of lower aliphatic alcohols characterized by containing a substantial proportion of aliphatic alcohols having from 2 to 6 carbon atoms by reacting a mixture of carbon monoxide and hydrogen under suitable conditions of temperature and pressure in the presence of a catalyst comprising molybdenum and a metal from the group consisting of cobalt, iron and nickel, said catalyst being modified by the addition of a promoter from the class consisting of potassium, cesium and rubidium, said promoter being employed at a concentration ranging from about 1.8 to 13.0 micromoles of said alkali per square meter of surface area of said catalyst.

摘要翻译： 提供了一种制备低级脂族醇的混合物的方法，其特征在于在合适的温度和压力条件下，在催化剂存在下，通过使一氧化碳和氢气的混合物反应，含有大量的具有2至6个碳原子的脂族醇 包括钼和由钴，铁和镍组成的组中的金属，所述催化剂通过从由钾，铯和铷组成的类中加入助催化剂来修饰，所述促进剂以约1.8至13.0的浓度使用 所述碱的平均米表面积为所述碱的微摩尔数。

公开(公告)号：US4616040A

公开(公告)日：1986-10-07

申请号：US757408

申请日：1985-07-22

申请人： Michael V. Grazioso ,  Edwin R. Kerr, deceased ,  Richard F. Love ,  David A. Storm

发明人： Michael V. Grazioso ,  Edwin R. Kerr, deceased ,  Richard F. Love ,  David A. Storm

IPC分类号： C07C29/156 ,  C07C27/06

CPC分类号： C07C29/156

摘要： A method is provided for preparing a mixture of lower aliphatic alcohols characterized by containing a substantial proportion of aliphatic alcohols having from 2 to 6 carbon atoms by reacting a mixture of carbon monoxide and hydrogen under suitable conditions of temperature and pressure in the presence of a catalyst comprising molybdenum, a metal from the group consisting of cobalt, iron and nickel, and copper, said catalyst being modified by the addition of a promoter from the class consisting of potassium, cesium and rubidium, said promoter being employed at a concentration ranging from about 1.8 to 13.0 micromoles of said alkali per square meter of surface area of said catalyst.

摘要翻译： 提供了一种制备低级脂族醇的混合物的方法，其特征在于在合适的温度和压力条件下，在催化剂存在下，通过使一氧化碳和氢气的混合物反应，含有大量的具有2至6个碳原子的脂族醇 包括钼，由钴，铁和镍组成的组中的金属和铜，所述催化剂通过从由钾，铯和铷组成的类中加入助催化剂来修饰，所述促进剂的使用浓度范围为约 每平方米所述催化剂表面积为1.8至13.0微摩尔所述碱。