Abstract:
In accordance with an exemplary embodiment of the present invention, an abrasion resistant transparent armor composite may comprise an elastomer facing layer and a urethane backing layer, wherein the facing layer comprises a Shore A hardness from about 45 to about 80, a tensile strength from about 4000 to about 8000 psi., a Bashore hardness of about 46, and a softening point at least about 380° F. The elastomer may comprise a polyester based urethane polymer. Disclosed features and specifications may be variously controlled, adapted or otherwise optionally modified to improve and/or modify the performance characteristics of the abrasion resistant transparent armor composite. Exemplary embodiments of the present invention generally provide abrasion resistant transparent armor for use as, for example, a composite to layer over a vehicular window, an airplane canopy, and building windows.
Abstract:
In accordance with an exemplary embodiment of the present invention, an optically clear polyurethane/polyurea polymer may be prepared by reacting a cycloaliphatic diisocyanate with polyesters, polyethers, and polycarbonates which may comprise hydroxyl groups and/or primary amine groups. This reaction may be carried out using 0.5 to 0.9 equivalents of the hydroxyl/amine groups followed by the reaction of 0.1 to 0.5 equivalents of water. The glycol, amine, and water may then be reacted with a cycloaliphatic diisocyanate in a ratio of about 1.77 to about 3.5 NCO for each OH, HOH, NH2. The resulting prepolymer may then be reacted with an aromatic diamine curing agent such as diethyltoluene diamine in an equivalent ratio of about 0.85 NH2/1.0 NCO to about 1.1 NH2/1.0 NCO, and in one embodiment, from about 0.90 NH2/1.0 NCO to 0.98 NH2/1.0 NCO. In one embodiment, 0.2 to 0.3 comprises the range of water equivalents for the water diisocyanate reaction.
Abstract:
A polyurea/urethane material and method for making it provides for improved optical parts. The material allows for ease of manufacture of parts having good optical properties, high hardness, low density, and good impact resistance. The method provides for related manufacturing advantages.