公开(公告)号：US08513463B2

公开(公告)日：2013-08-20

申请号：US12988052

申请日：2009-04-15

申请人： Michael Christian Maximilian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Frank Roessner ,  Tawanda Stephen Sango

发明人： Michael Christian Maximilian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Frank Roessner ,  Tawanda Stephen Sango

IPC分类号： C07C231/00 ,  C07C233/00 ,  C07F9/02

CPC分类号： C07C231/10 ,  C07C253/00 ,  C07F9/505 ,  C07C233/03 ,  C07C255/03

摘要： A process is described for the production of one or more of linear nitriles, amides and formamides which includes reacting a nitrogen containing compound, such as ammonia or NOx, and a synthesis gas over a catalyst at a temperature of between 160° C. and 400° C. and a pressure of between 1 bar and 50 bar. A further process for the production of one or more of linear phosphorous containing compounds is also described, which includes reacting a phosphorous containing compound, such as a phosphine, and a synthesis gas over a catalyst at a temperature of between 160° C. and 400° C. and a pressure of between 1 bar and 50 bar. A supported cobalt, iron, ruthenium or rhodium catalyst or an unsupported (bulk) promoted iron catalyst, modified with a promoter is used. The synthesis gas is a mixture of hydrogen and carbon monoxide, in a ratio from 0.5:1 to 5:1; or a mixture of hydrogen and carbon dioxide; or a mixture of water and carbon monoxide. The suppression of the formation of oxygenates in the process is a feature of the invention and oxygenates may even be included in the feed to become converted to corresponding nitrogen containing compounds in the process.

摘要翻译： 描述了用于生产线性腈，酰胺和甲酰胺中的一种或多种的方法，其包括在160℃和400℃之间的温度下使含氮化合物如氨或NO x与合成气在催化剂上反应 °C和1巴与50巴之间的压力。 还描述了用于生产一种或多种含有线性磷的化合物的另外的方法，其包括在160℃和400℃之间的温度下使含磷化合物如磷化氢与合成气在催化剂上反应 °C和1巴与50巴之间的压力。 使用经助催化剂改性的负载型钴，铁，钌或铑催化剂或未负载（体积）促进的铁催化剂。 合成气是氢和一氧化碳的混合物，其比例为0.5:1至5:1; 或氢和二氧化碳的混合物; 或水和一氧化碳的混合物。 在该过程中抑制含氧化合物的形成是本发明的一个特征，并且氧化物甚至可以包含在进料中以在该方法中转化成相应的含氮化合物。

公开(公告)号：US20130210160A1

公开(公告)日：2013-08-15

申请号：US13643253

申请日：2011-04-26

申请人： Frank Roessner ,  Stefan Schoenen

发明人： Frank Roessner ,  Stefan Schoenen

IPC分类号： G01N30/68

CPC分类号： G01N30/68 ,  G01N27/626 ,  G01N33/0013 ,  G01N33/005 ,  Y10T436/22

摘要： The invention relates to a device and to a method for the detection of hydrogen in a gas mixture, wherein the device comprises a catalyst unit which is connected to a source and a supply device for CO and/or CO2, respectively, or comprises these and wherein the catalyst unit is connected to a flame ionization detector by a feed line, such that the gas mixture, especially containing an inert carrier gas after passing through the catalyst unit is conducted to the FID. The FID is operated with hydrogen as fuel gas.

摘要翻译： 本发明涉及一种用于检测气体混合物中的氢的装置和方法，其中所述装置包括分别连接到源和用于CO和/或CO 2的供应装置的催化剂单元，或包括这些和/ 其中催化剂单元通过进料管线连接到火焰离子化检测器，使得通过催化剂单元之后特别是含有惰性载气的气体混合物被引导到FID。 FID以氢气为燃料气体运行。

公开(公告)号：US06682673B1

公开(公告)日：2004-01-27

申请号：US10030037

申请日：2002-06-24

申请人： Michael Skwiercz ,  Bernhardt Gutsche ,  Frank Roessner ,  Doris Elberfeld

发明人： Michael Skwiercz ,  Bernhardt Gutsche ,  Frank Roessner ,  Doris Elberfeld

IPC分类号： D04H164

CPC分类号： C08J5/045 ,  C08G59/027 ,  C08G59/1461 ,  C08J2333/06 ,  C08J2391/00

摘要： A process for making a fiber composite involving: (a) providing a natural fiber; (b) providing a matrix material produced by a radical polymerization reaction of: (i) a monomer selected from the group consisting of ring opening products of epoxidized fatty compounds with olefinically unsaturated carboxylic acids, and (ii) a comonomer selected from the group consisting of olefinically unsaturated carboxylic acids; (c) providing a radical initiator; and (d) conducting the radical polymerization reaction of (i) and (ii) in the presence of the natural fiber so that the matrix material envelops the natural fiber, thus producing the fiber composite.

摘要翻译： 一种制备纤维复合材料的方法，涉及：（a）提供天然纤维; （b）提供通过自由基聚合反应制备的基质材料：（i）选自环氧化脂肪族化合物与烯属不饱和羧酸的开环产物的单体，和（ii）选自以下的共聚单体： 的烯属不饱和羧酸; （c）提供自由基引发剂; 和（d）在天然纤维存在下进行（i）和（ii）的自由基聚合反应，使得基质材料包裹天然纤维，从而生产纤维复合材料。

公开(公告)号：US20110160510A1

公开(公告)日：2011-06-30

申请号：US12937694

申请日：2009-04-15

申请人： Michael Christian Maximillian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Frank Roessner ,  Andreas Karl Rausch

发明人： Michael Christian Maximillian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Frank Roessner ,  Andreas Karl Rausch

IPC分类号： C07C1/20

CPC分类号： C10G2/50 ,  C10G2/32 ,  C10G2300/202 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2400/22 ,  Y02P20/142

摘要： A process is provided for the production of hydrocarbons that include olefins from synthesis gas containing at least one of carbon monoxide and or carbon dioxide wherein the synthesis gas is fed to a reactor in which a catalyst acts on the feed at a temperature of between 160° C. and 400° C. and a pressure of between 1 bar and 50 bar. The feed includes a compound containing one or both of nitrogen and phosphorous, such as ammonia and a phosphine, added to the reactor with the synthesis gas. The compound containing nitrogen typically constitutes at least 1 vol % and preferably of the order of 4 to 20 vol % or more of the feed. The carbonaceous gas may be carbon monoxide with a ratio of hydrogen to carbon monoxide in the synthesis gas of from 0.5:1 to 5:1. The catalyst is preferably a supported cobalt catalyst and may be modified with a promoter. The process produces an enhanced proportion of olefins, especially linear olefins, in the hydrocarbons produced.

摘要翻译： 提供了一种用于生产包含含有一氧化碳和/或二氧化碳中的至少一种的合成气的烯烃的方法，其中将合成气进料到反应器中，其中催化剂在160℃的温度下作用在进料上 和400℃的压力和1巴与50巴之间的压力。 进料包括一种含有氮和磷中的一种或两种的化合物，例如氨和膦，并与合成气一起加入到反应器中。 含有氮的化合物通常构成进料的至少1体积％，优选为4〜20体积％以上。 含碳气体可以是合成气中氢与一氧化碳的比例为0.5:1至5:1的一氧化碳。 催化剂优选为负载型钴催化剂，并可用助催化剂进行改性。 该方法在所生产的烃中产生较高比例的烯烃，特别是直链烯烃。

公开(公告)号：US20110092728A1

公开(公告)日：2011-04-21

申请号：US12988052

申请日：2009-04-15

申请人： Michael Christian Maximilian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Frank Roessner ,  Tawanda Stephen Sango

发明人： Michael Christian Maximilian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Frank Roessner ,  Tawanda Stephen Sango

IPC分类号： C07C253/00 ,  C07C231/10 ,  C07F9/02

CPC分类号： C07C231/10 ,  C07C253/00 ,  C07F9/505 ,  C07C233/03 ,  C07C255/03

摘要： A process is described for the production of one or more of linear nitriles, amides and formamides which includes reacting a nitrogen containing compound, such as ammonia or NOx, and a synthesis gas over a catalyst at a temperature of between 160° C. and 400° C. and a pressure of between 1 bar and 50 bar. A further process for the production of one or more of linear phosphorous containing compounds is also described, which includes reacting a phosphorous containing compound, such as a phosphine, and a synthesis gas over a catalyst at a temperature of between 160° C. and 400° C. and a pressure of between 1 bar and 50 bar. A supported cobalt, iron, ruthenium or rhodium catalyst or an unsupported (bulk) promoted iron catalyst, modified with a promoter is used. The synthesis gas is a mixture of hydrogen and carbon monoxide, in a ratio from 0.5:1 to 5:1; or a mixture of hydrogen and carbon dioxide; or a mixture of water and carbon monoxide. The suppression of the formation of oxygenates in the process is a feature of the invention and oxygenates may even be included in the feed to become converted to corresponding nitrogen containing compounds in the process.

摘要翻译： 描述了用于生产线性腈，酰胺和甲酰胺中的一种或多种的方法，其包括在160℃和400℃之间的温度下使含氮化合物如氨或NO x与合成气在催化剂上反应 °C和1巴与50巴之间的压力。 还描述了用于生产一种或多种含有线性磷的化合物的另外的方法，其包括在160℃和400℃之间的温度下使含磷化合物如磷化氢与合成气在催化剂上反应 °C和1巴与50巴之间的压力。 使用经助催化剂改性的负载型钴，铁，钌或铑催化剂或未负载（体积）促进的铁催化剂。 合成气是氢和一氧化碳的混合物，其比例为0.5:1至5:1; 或氢和二氧化碳的混合物; 或水和一氧化碳的混合物。 在该过程中抑制含氧化合物的形成是本发明的一个特征，并且氧化物甚至可以包含在进料中以在该方法中转化成相应的含氮化合物。

公开(公告)号：US08558047B2

公开(公告)日：2013-10-15

申请号：US12937694

申请日：2009-04-15

申请人： Michael Christian Maximillian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Frank Roessner ,  Andreas Karl Rausch

发明人： Michael Christian Maximillian Claeys ,  Eric Wilhelmus Josephus Van Steen ,  Frank Roessner ,  Andreas Karl Rausch

IPC分类号： C07C1/00

CPC分类号： C10G2/50 ,  C10G2/32 ,  C10G2300/202 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2400/22 ,  Y02P20/142

摘要： A process is provided for the production of hydrocarbons from synthesis gas wherein the synthesis gas is fed to a reactor in which a catalyst acts on the feed at a temperature of between 160° C. and 400° C. and a pressure of between 1 bar and 5 bar. The feed includes a compound containing one or both nitrogen and phosphorus added to the reactor with the synthesis gas. The compound containing nitrogen typically constitutes at least 1 vol % and preferably of the order of 4 to 20 vol % or more of the feed. The carbonaceous gas may be carbon monoxide with a ratio of hydrogen to carbon monoxide in the synthesis gas of from 0.5:1 to 5:1. The catalyst is preferably a supported cobalt catalyst and may be modified with a promoter. The process produces an enhanced proportion of olefins, in the hydrocarbons produced.

摘要翻译： 提供了一种用于从合成气生产烃的方法，其中合成气进料到反应器中，其中催化剂在160℃和400℃之间的温度下进料到进料上，压力在1巴之间 和5巴。 进料包括含有合成气加入反应器中的一种或两种氮和磷的化合物。 含有氮的化合物通常构成进料的至少1体积％，优选为4〜20体积％以上。 含碳气体可以是合成气中氢与一氧化碳的比例为0.5:1至5:1的一氧化碳。 催化剂优选为负载型钴催化剂，并可用助催化剂进行改性。 该方法在所生产的烃中产生增加比例的烯烃。