公开(公告)号：US4312642A

公开(公告)日：1982-01-26

申请号：US126267

申请日：1980-03-03

Applicant: Gunter Lehr ,  Karl-Dieter Lohr ,  Uwe Hucks ,  Hugo Vernaleken

Inventor： Gunter Lehr ,  Karl-Dieter Lohr ,  Uwe Hucks ,  Hugo Vernaleken

IPC: B29C48/76 ,  B01D19/00

CPC classification number: B29C47/76 ,  B29C47/0009 ,  B29C47/766

Abstract: A method for the separate discharge of the individual phase streams of a multiple component flow comprising a high viscosity slow flowing liquid or suspension and a gas flowing at at least 100 times faster with the volumetric ratio of the gas to the liquid being greater than 1:1. The multicomponent flow is transversely fed through an inlet and directly into a rotating helical channel for conveying liquid in one direction. The channel has a liquid outlet spaced from the inlet in the one direction and a gas outlet spaced from the inlet in the opposite direction. A gas shut-off is formed between the inlet and the liquid outlet so as to effect the discharge of gas through the gas outlet in the opposite direction during the conveying of the liquid by the helical channel to the liquid outlet in the one direction.

Abstract translation: 一种用于单独排放多组分流的单个相流的方法，其包括高粘度慢流动的液体或悬浮液和以至少100倍的速度流动的气体，其中气体与液体的体积比大于1： 1。 多组分流被横向地通过入口进料并直接进入用于在一个方向上输送液体的旋转螺旋通道。 通道具有在一个方向上与入口间隔开的液体出口和在相反方向上与入口间隔开的气体出口。 在入口和液体出口之间形成气体切断，以便在将液体通过螺旋通道沿一个方向输送到液体出口时，在相反方向上实现气体通过气体出口的排出。

公开(公告)号：US4472558A

公开(公告)日：1984-09-18

申请号：US45028

申请日：1979-06-04

Applicant: Clemens Casper ,  Henning Klussmann ,  Gunter Lehr ,  Johannes O. Sajben ,  Artur Reischl ,  Rudolf Binsack ,  Frank Wingler

Inventor： Clemens Casper ,  Henning Klussmann ,  Gunter Lehr ,  Johannes O. Sajben ,  Artur Reischl ,  Rudolf Binsack ,  Frank Wingler

IPC: B01D3/28 ,  B01J3/04 ,  B01J10/02 ,  B01J19/24 ,  C08F2/00 ,  C08F2/06 ,  C08G18/00 ,  C08G18/08

CPC classification number: C08G18/0838 ,  B01J10/02 ,  B01J19/243 ,  B01J3/042 ,  B01J2219/00085 ,  B01J2219/00162 ,  B01J2219/00164

Abstract: This invention relates to a process for carrying out reactions which primarily occur during the transport of compounds in the liquid phase or at the liquid-gas interface. Starting components are reacted with one another and/or with gases of the inner space in a multi-phase flow tube having a liquid ring flow which may contain dissolved and/or dispersed constituents. Any necessary heat exchange takes place between the liquid and the wall of the tube or the gases.

Abstract translation: 本发明涉及一种进行反应的方法，主要发生在化合物在液相或液 - 液界面输送过程中。 起始组分在具有可能含有溶解和/或分散成分的液体环流的多相流动管中彼此反应和/或与内部空间的气体反应。 在液体和管壁或气体之间进行任何必要的热交换。

公开(公告)号：US4327208A

公开(公告)日：1982-04-27

申请号：US167055

申请日：1980-07-09

Applicant: Gunter Lehr ,  Uwe Hucks ,  Hugo Vernaleken ,  Werner Nielinger ,  Erhard Tresper

Inventor： Gunter Lehr ,  Uwe Hucks ,  Hugo Vernaleken ,  Werner Nielinger ,  Erhard Tresper

IPC: C08G69/00 ,  C08G69/16 ,  C08G69/46 ,  C08L101/16

CPC classification number: C08G69/46

Abstract: A process for the production of polyamide-6 or corresponding copolyamides by hydrolytic polymerization wherein the low molecular weight secondary reaction products and the unreacted .epsilon.-caprolactam are separated off from the polyamide melt and directly condensed on the .epsilon.-caprolactam melt to be polymerized.

Abstract translation: 通过水解聚合制备聚酰胺-6或相应的共聚酰胺的方法，其中将低分子量二级反应产物和未反应的ε-己内酰胺与聚酰胺熔体分离并直接在ε-己内酰胺熔体上缩合以进行聚合。

公开(公告)号：US4212963A

公开(公告)日：1980-07-15

申请号：US968892

申请日：1978-12-13

Applicant: Gunter Lehr ,  Rudolf Binsack

Inventor： Gunter Lehr ,  Rudolf Binsack

IPC: C08G63/00 ,  C08G63/78 ,  C08G63/18

CPC classification number: C08G63/785 ,  C08G63/78

Abstract: Polybutylene terephthalates having a narrow molecular weight distribution, a low carboxyl group content and an intrinsic viscosity of from 0.2 to 1.4 dl/g can be continuously produced by transporting a molten reaction mixture of terephthalic acid mono- and/or bis-(hydroxybutyl) ester or low viscosity polybutylene terephthalate at 160.degree. to 300.degree. C., together with a heated inert gas, in a diphasic annular stream through an externally heated spiral reaction tube (of substantially constant pitch) having a diameter of from 3 to 100 mm and a diameter/length ratio of from 1:400 to 1:2000 by the maintenance of a pressure difference between the beginning and the end of the reaction tube, under conditions such that the absolute pressure, determined at the point of entry of the reaction mixture into the tube, is from 1 to 100 bar and the viscosity of the annular stream is from 1 to 10,000 poises (determined at the reaction temperature), and a circular stream between the surface of the melt and the wall of the tube is produced by the curvature of the tube and a stream of gas flowing at a velocity of from 20 to 300 m/sec to accelerate the transport of material between the melt and the inert gas, whereby the reaction takes place in the liquid phase and/or at the melt/gas interface.

Abstract translation: 通过将对苯二甲酸单 - 和/或双 - （羟基丁基）酯的熔融反应混合物输送，可以连续制备具有窄分子量分布，低羧基含量和特性粘度为0.2-1.4dl / g的聚对苯二甲酸丁二醇酯 或低粘度聚对苯二甲酸丁二醇酯在160℃至300℃下与加热的惰性气体一起通过直径为3至100mm的外部加热的螺旋反应管（基本上恒定的间距）和二价环状流 通过维持反应管的开始和结束之间的压力差，在使反应混合物进入点确定的绝对压力为 管子为1至100巴，环形流的粘度为1至10,000泊（在反应温度下确定），并且在熔体表面之间的圆形流 d管的壁由管的曲率和以20-300m / sec的速度流动的气流产生，以加速在熔体和惰性气体之间的材料的输送，从而发生反应 在液相和/或在熔体/气体界面处。