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    Polymers comprising triaylamine units as electroluminescence materials
    3.
    发明授权
    Polymers comprising triaylamine units as electroluminescence materials 失效
    包含三烯丙基胺单元作为电致发光材料的聚合物

    公开(公告)号：US5814244A

    公开(公告)日：1998-09-29

    申请号：US711367

    申请日：1996-09-03

    Applicant: Willi Kreuder ,  Hans-Heinrich Horhold ,  Henning Rost

    Inventor： Willi Kreuder ,  Hans-Heinrich Horhold ,  Henning Rost

    IPC: C09K11/06 ,  H05B33/14 ,  C08G12/04

    CPC classification number: H01L51/0036 ,  C09K11/06 ,  H01L51/005 ,  H05B33/14

    Abstract: An electroluminescence material comprising one or more polymers which comprise structural units of the formula (I), ##STR1## where the symbols and indices have the following meanings: Ar.sup.1, Ar.sup.2, Ar.sup.3, Ar.sup.4, Ar.sup.5, Ar.sup.6 are identical or different, monocyclic and/or polycyclic aryl and/or heteroaryl groups which may be linked via one or more bridges and/or be condensed and may be unsubstituted or substituted, where Ar.sup.1, Ar.sup.3, Ar.sup.5 and Ar.sup.6 are each divalent and Ar.sup.2 and Ar.sup.4 are each monovalent; R.sup.1 is H, a hydrocarbon radical having from 1 to 22 carbon atoms, which may be unsubstituted or substituted, preferably by F, and can also contain heteroatoms, preferably 0, or Ar.sup.7, where Ar.sup.7 is, independently of Ar.sup.1-6, as defined for Ar.sup.1-6 ; n is 0, 1 or 2. The electroluminescence material of the invention has, inter alia, a low threshold voltage of the electroluminescence and a high efficiency, although the polymers are not conjugated.

    Abstract translation: 包含一种或多种包含式（I），其中符号和指数具有以下含义的结构单元的聚合物的电致发光材料：Ar1，Ar2，Ar3，Ar4，Ar5，Ar6相同或不同 单环和/或多环芳基和/或杂芳基，其可以通过一个或多个桥连接和/或被缩合并且可以是未取代的或取代的，其中Ar 1，Ar 3，Ar 5和Ar 6各自为二价，Ar 2和Ar 4各自为 一价; R 1是H，具有1至22个碳原子的烃基，其可以是未取代的或被F取代的，并且还可以含有杂原子，优选为0或Ar 7，其中Ar 7独立地为Ar1-6，如所定义 对于Ar1-6; n是0,1或2.本发明的电致发光材料尤其具有电致发光的低阈值电压和高效率，尽管聚合物不共轭。

    Process for the preparation of high molecular thermoplastic epoxide-amine-polyadducts
    4.
    发明授权
    Process for the preparation of high molecular thermoplastic epoxide-amine-polyadducts 失效
    制备高分子量热塑性环氧化物 - 胺 - 加合物的方法

    公开(公告)号：US4308085A

    公开(公告)日：1981-12-29

    申请号：US172598

    申请日：1980-07-28

    Applicant: Hans-Heinrich Horhold ,  Dieter Klemm ,  Klaus Bellstedt ,  Ludwig Haase ,  Joachim Klee ,  Klaus Schubert ,  Helmut Wachs ,  Rolf Martin

    Inventor： Hans-Heinrich Horhold ,  Dieter Klemm ,  Klaus Bellstedt ,  Ludwig Haase ,  Joachim Klee ,  Klaus Schubert ,  Helmut Wachs ,  Rolf Martin

    IPC: C08G59/50 ,  C08G65/26

    CPC classification number: C08G59/50

    Abstract: High molecular linear, thermoplastic, epoxide-amine-adducts containing the structural segment ##STR1## are prepared by a solvent-free reaction of equivalent amounts at 20 to 200.degree. C. of N,N'-bis(aralkyl) diamines (for example, N,N'-dibenzyl-ethylenediamine, N,N'-dibenzyl-p-xylylenediamine, N,N'-dibenzyl-4,4'-diamino-diphenylmethane, N,N'-dibenzyl-3,6-dioxa-octanediamine-1,8) with diepoxides (for example, 2,2-bis(4-glycidyloxyphenyl)propane). The polyadducts are soluble and may be processed by thermoplastic methods. The polyaddition process may be conducted for the forming of shaped objects in a form-shaping vessel, for the production of coatings directly upon the surface to be coated and also in the presence of inserted materials and has, due to these characteristics, the nature of a casting system.

    Abstract translation: 含有结构片段“IMAGE”的高分子线性，热塑性，环氧化物 - 胺加合物通过在20-200℃下等量的N，N'-双（芳烷基）二胺的无溶剂反应（例如 ，N，N'-二苄基 - 乙二胺，N，N'-二苄基对苯二甲胺，N，N'-二苄基-4,4'-二氨基 - 二苯基甲烷，N，N'-二苄基-3,6-二氧杂 - 辛二胺-1,8）与二环氧化物（例如，2,2-双（4-缩水甘油氧基苯基）丙烷））。 聚加成物是可溶的并且可以通过热塑性方法加工。 可以进行加聚方法以在成形容器中形成成形物体，用于直接在待涂覆的表面上以及在插入材料的存在下生产涂层，并且由于这些特性，由于这些特性， 铸造系统。

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