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公开(公告)号：US20120164385A1
公开(公告)日：2012-06-28
申请号：US13333320
申请日：2011-12-21
CPC分类号： E04D1/20 , C08J3/2053 , C08J7/042 , C08J2300/22 , C08J2317/00 , C08K3/22 , C08K5/092 , C08K2201/019 , C08L17/00 , C08L19/003 , C08L25/00 , C08L33/08 , Y02A30/255 , Y02B80/34 , Y10T428/2438
摘要： The present invention provides shaped articles comprising one or more composite layer of (i) a vulcanizate encapsulated in a colored or uncolored thermoplastic polymer matrix containing one or more passivating agent, and (ii) a reflective material chosen from colored fluidizable particles of a thermoplastic reflective colorant encapsulated vulcanizate, roofing granules, thermoplastic encapsulated roofing granules, the colored thermoplastic polymer matrix, and combinations thereof. The articles can be laminates of colored or reflective layers on uncolored or other layers, or one or more colored layer having colored fluidizable particles are dispersed within the surface of the uppermost composite layer or having either the colored fluidizable particles or the granules are dispersed on the surface of the composite layer or are adhered thereto with a thermoplastic resin. Roofing shingles are provided.
摘要翻译： 本发明提供了一种成形制品，其包含一种或多种复合层，所述复合层包含（i）包封在含有一种或多种钝化剂的有色或未着色的热塑性聚合物基质中的硫化胶，和（ii）选自热塑性反射的有色可流化颗粒的反射材料 着色剂包封的硫化橡胶，屋顶颗粒，热塑性包封屋顶颗粒，着色热塑性聚合物基质及其组合。 制品可以是未着色或其它层上的有色或反射层的层压体，或者具有可着色的可流化颗粒的一个或多个着色层分散在最上层复合层的表面内，或者将着色的可流化颗粒或颗粒分散在 复合层的表面或者用热塑性树脂粘附在其上。 提供屋顶木瓦。
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2.发明授权Methods for making composites having thermoplastic properties from recycled crosslinked polymer 有权从循环交联聚合物制备具有热塑性的复合材料的方法公开(公告)号：US08304460B2
公开(公告)日：2012-11-06
申请号：US12456473
申请日：2009-06-17
IPC分类号： C08J11/04
CPC分类号： C08J3/16 , C08C1/14 , C08F6/22 , C08J11/06 , C08J2300/30 , C08J2319/00 , C08J2321/00 , C08L19/003 , C08L33/12 , C08L101/02 , Y02W30/701 , Y10T428/24355 , Y10T428/24405 , Y10T428/269 , C08L2666/04
摘要： The present invention provides methods of making shapeable composites in the form of finely divided materials or articles and the materials and articles produced by the methods, the methods comprising forming mixtures by (i) treating an aqueous thermoplastic acrylic or vinyl polymer to increase the particle size thereof to a weight average particle size of 1 μm or more, and, optionally, dewatering to form a crumb mixture; and (ii) combining a thermoplastic acrylic or vinyl polymer with one or more waste rubber vulcanizate having a sieve particle size ranging from 10 to 600 μm in the amount of from 15 to 95 wt. %, based on the total weight of polymer and rubber to form a crumb slurry, such that (ii) can take place before, during, after (i) but before any dewatering, or after any dewatering; and (iii) thermoplastic processing the mixture. Thermoplastic processing can directly form articles, like sheets or films. The shapeable composites have excellent adhesion to other materials. In one embodiment, the sheets and films can be formed into laminates.
摘要翻译： 本发明提供了以细碎材料或制品形式制造可成形复合材料的方法，以及通过该方法生产的材料和制品，所述方法包括通过（i）处理水性热塑性丙烯酸或乙烯基聚合物以增加粒径来形成混合物 的重均粒径为1μm以上，任选地脱水以形成碎屑混合物; 和（ii）将热塑性丙烯酸或乙烯基聚合物与一种或多种具有10至600μm的筛粒度为15至95重量％的废橡胶硫化橡胶组合。 ％，基于聚合物和橡胶的总重量以形成碎屑浆料，使得（ii）可以在（i）之前，之后，但在任何脱水之前，或在任何脱水之后进行; 和（iii）热塑性加工混合物。 热塑性加工可以直接形成制品，如片材或薄膜。 可塑性复合材料对其他材料具有优异的附着力。 在一个实施例中，片和膜可以形成为层压体。
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公开(公告)号：US09404259B2
公开(公告)日：2016-08-02
申请号：US13333320
申请日：2011-12-21
CPC分类号： E04D1/20 , C08J3/2053 , C08J7/042 , C08J2300/22 , C08J2317/00 , C08K3/22 , C08K5/092 , C08K2201/019 , C08L17/00 , C08L19/003 , C08L25/00 , C08L33/08 , Y02A30/255 , Y02B80/34 , Y10T428/2438
摘要： The present invention provides shaped articles comprising one or more composite layer of (i) a vulcanizate encapsulated in a colored or uncolored thermoplastic polymer matrix containing one or more passivating agent, and (ii) a reflective material chosen from colored fluidizable particles of a thermoplastic reflective colorant encapsulated vulcanizate, roofing granules, thermoplastic encapsulated roofing granules, the colored thermoplastic polymer matrix, and combinations thereof. The articles can be laminates of colored or reflective layers on uncolored or other layers, or one or more colored layer having colored fluidizable particles are dispersed within the surface of the uppermost composite layer or having either the colored fluidizable particles or the granules are dispersed on the surface of the composite layer or are adhered thereto with a thermoplastic resin. Roofing shingles are provided.
摘要翻译： 本发明提供了一种成形制品，其包含一种或多种复合层，所述复合层包含（i）包封在含有一种或多种钝化剂的有色或未着色的热塑性聚合物基质中的硫化胶，和（ii）选自热塑性反射的有色可流化颗粒的反射材料 着色剂包封的硫化橡胶，屋顶颗粒，热塑性包封屋顶颗粒，着色热塑性聚合物基质及其组合。 制品可以是未着色或其它层上的有色或反射层的层压体，或者具有可着色的可流化颗粒的一个或多个着色层分散在最上层复合层的表面内，或者将着色的可流化颗粒或颗粒分散在 复合层的表面或者用热塑性树脂粘附在其上。 提供屋顶木瓦。
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公开(公告)号：US20120165459A1
公开(公告)日：2012-06-28
申请号：US13331687
申请日：2011-12-20
申请人： Harry R. HEULINGS , Willie LAU
发明人： Harry R. HEULINGS , Willie LAU
IPC分类号： C08L17/00
CPC分类号： C08J3/005 , C08J3/124 , C08J3/126 , C08J3/215 , C08J2300/22 , C08J2317/00 , C08J2319/00 , C08J2321/00 , C08J2400/22 , C08L19/003 , C08L25/14 , C08L33/06
摘要： The present invention provides methods for making shelf-stable fluidizable particles that comprise mixing from 35 wt. % to 89.95 wt. %, based on total solids, of particles of one or more vulcanizate having a sieve particle size of from 10 to 800 μm, 10 to 65 wt. %, based on total solids, of one or more thermoplastic polymer in the form of an emulsion of a thermoplastic polymer in the presence of from 0.05 to 3 wt. %, based on total solids, of a passivating agent, to form a moist mixture followed by drying the moist mixture to form fluidizable particles such that the total solids content of the mixture remains 65 wt. % or more throughout processing. In addition, the invention provides plasticizer free storage stable fluidizable particles and 0colored fluidizable particles.
摘要翻译： 本发明提供制备储存稳定的可流化颗粒的方法，其包括从35wt。 ％至89.95重量％ 基于总固体的一种或多种具有10至800μm筛粒径的硫化橡胶颗粒，10至65wt。 ％，基于总固体，一种或多种热塑性聚合物形式的热塑性聚合物在0.05至3wt。 ％，基于总固体，钝化剂，以形成湿混合物，然后干燥湿混合物以形成可流化颗粒，使得混合物的总固体含量保持65wt。 ％或更多的整个加工。 此外，本发明提供了不含增塑剂的储存稳定的可流化颗粒和0色可流化颗粒。
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5.发明申请Methods for making composites having thermoplastic properties from recycled crosslinked polymer 有权从循环交联聚合物制备具有热塑性的复合材料的方法公开(公告)号：US20100009152A1
公开(公告)日：2010-01-14
申请号：US12456473
申请日：2009-06-17
CPC分类号： C08J3/16 , C08C1/14 , C08F6/22 , C08J11/06 , C08J2300/30 , C08J2319/00 , C08J2321/00 , C08L19/003 , C08L33/12 , C08L101/02 , Y02W30/701 , Y10T428/24355 , Y10T428/24405 , Y10T428/269 , C08L2666/04
摘要： The present invention provides methods of making shapeable composites in the form of finely divided materials or articles and the materials and articles produced by the methods, the methods comprising forming mixtures by (i) treating an aqueous thermoplastic acrylic or vinyl polymer to increase the particle size thereof to a weight average particle size of 1 μm or more, and, optionally, dewatering to form a crumb mixture; and (ii) combining a thermoplastic acrylic or vinyl polymer with one or more waste rubber vulcanizate having a sieve particle size ranging from 10 to 600 μm in the amount of from 15 to 95 wt. %, based on the total weight of polymer and rubber to form a crumb slurry, such that (ii) can take place before, during, after (i) but before any dewatering, or after any dewatering; and (iii) thermoplastic processing the mixture. Thermoplastic processing can directly form articles, like sheets or films. The shapeable composites have excellent adhesion to other materials. In one embodiment, the sheets and films can be formed into laminates.
摘要翻译： 本发明提供了以细碎材料或制品形式制造可成形复合材料的方法，以及通过该方法生产的材料和制品，所述方法包括通过（i）处理水性热塑性丙烯酸或乙烯基聚合物以增加粒径来形成混合物 的重量平均粒径为1μm以上，任选地脱水以形成碎屑混合物; 和（ii）将热塑性丙烯酸或乙烯基聚合物与一种或多种具有10至600μm的筛粒度的废橡胶硫化橡胶组合，其量为15至95重量％。 ％，基于聚合物和橡胶的总重量以形成碎屑浆料，使得（ii）可以在（i）之前，之后，但在任何脱水之前，或在任何脱水之后进行; 和（iii）热塑性加工混合物。 热塑性加工可以直接形成制品，如片材或薄膜。 可塑性复合材料对其他材料具有优异的附着力。 在一个实施例中，片和膜可以形成为层压体。
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