公开(公告)号：US5136028A

公开(公告)日：1992-08-04

申请号：US612733

申请日：1990-11-09

申请人： Herbert Seiler

发明人： Herbert Seiler

IPC分类号： C09B62/085 ,  D06P3/66

CPC分类号： C09B62/085

摘要： Novel reactive dyes of formula ##STR1## wherein Z is a radical of formula ##STR2## and R.sub.1, R.sub.2, R.sub.3, (R.sub.4).sub.2-3, (R.sub.5).sub.1-3, R.sub.7 and (R.sub.8).sub.1-3 are as defined in claim 1, give intense red dyeings and prints of good fastness properties on cellulosic fibres.

摘要翻译： （1）式（1）其中Z是式NHR1，（1a）N（R2）R3，（1b）的基团的新型活性染料（1）其中Z是式NHR1，（1a） （1f）和R1，R2，R3，（R4）2-3，（R5）1-3，R7和（R8）1-3如权利要求1中所定义，给出强烈的红色染色和印刷品 纤维素纤维的坚牢度性质。

公开(公告)号：US4866162A

公开(公告)日：1989-09-12

申请号：US914556

申请日：1986-10-02

申请人： Herbert Seiler ,  Gert Hegar

发明人： Herbert Seiler ,  Gert Hegar

IPC分类号： C09B45/00 ,  C09B62/08 ,  C09B62/085 ,  C09B62/095

CPC分类号： C09B62/08

摘要： Azo dyes of the formula ##STR1## wherein D is a disulfonaphthyl-(2) residue, K is a naphtalene or benzene residue, R is hydrogen, and X is hydrogen, are especially suitable for dyeing of cellulosic materials of fibrous structure, they have a good exhaustion capacity and excellent dye fixation.

摘要翻译： 式（1）的偶氮染料其中D是二磺基 - （2）残基，K是萘或苯残基，R是氢，X是氢，特别适用于纤维结构纤维素材料的染色 ，它们具有良好的排汗能力和优异的染色固定性。

公开(公告)号：US4049661A

公开(公告)日：1977-09-20

申请号：US660403

申请日：1976-02-23

申请人： Herbert Seiler ,  Paul Dussy

发明人： Herbert Seiler ,  Paul Dussy

IPC分类号： C09B62/00 ,  C09B62/02 ,  D06P1/38 ,  D06P1/90 ,  D06P1/92 ,  D06P3/10 ,  C07D239/00 ,  C09B5/16 ,  C09B5/44

CPC分类号： D06P1/924 ,  C09B62/00 ,  C09B62/02 ,  D06P1/38 ,  D06P1/908 ,  D06P1/928 ,  D06P3/10

摘要： New reactive dyestuffs free from acid, salt-forming, water-solubilizing groups, and having the formula ##STR1## wherein D represents the radical of an anthraquinone dyestuff,Q represents NX.sub.3, O, S or NX.sub.3 CO wherein X.sub.3 represents hydrogen or lower alkyl,R represents diazinyl containing only chlorine, bromine or fluorine substituents, each of which can be split off as anion and which is bound to a ring carbon atom adjacent to a tertiary nitrogen atom,X.sub.1 represents hydrogen andX.sub.2 represents alkyl having from 8 to 18 carbon atoms, orX.sub.1 and X.sub.2 represents the same or different alkyl or alkoxyalkyl wherein X.sub.1 and X.sub.2 must together contain from 8 to 36 carbon atoms, orX.sub.1 represents cyclohexyl or cyclohexyl substituted by lower alkyl, andX.sub.2 represents alkyl of 1 to 18 carbon atoms, alkyl of 1 to 18 carbon atoms substituted by a member selected from the group consisting of hydroxyl, lower alkoxy, lower alkenyloxy and cyano, lower alkenyl, cyclohexyl or cyclohexyl substituted by lower alkyl, said dyestuffs being suitable for the dyeing and printing of hydrophobic organic fibre material, especially fibre material from synthetic polyamide, and being characterized by their good to excellent solubility in aprotic solvents or mixture of solvents.

摘要翻译： 新的活性染料不含酸，盐形成，水溶性基团，并具有下式：其中D表示蒽醌染料的基团，Q表示NX3，O，S或NX3CO，其中X3表示氢或低级烷基， R表示仅含有氯，溴或氟取代基的二嗪基，其各自可以作为阴离子分离，并且与邻近叔氮原子的环碳原子结合，X1表示氢，X2表示具有8至18个碳原子的烷基 或X 1和X 2表示相同或不同的烷基或烷氧基烷基，其中X 1和X 2必须一起含有8至36个碳原子，或X 1表示被低级烷基取代的环己基或环己基，X 2表示1至18个碳原子的烷基， 被选自羟基，低级烷氧基，低级烯氧基和氰基的低级烯基，环己基或被低级烷基取代的环己基取代的1至18个碳原子的烷基， 所述染料适用于疏水性有机纤维材料的染色和印花，特别是合成聚酰胺的纤维材料，其特征在于其在非质子溶剂或溶剂混合物中的良好至优异的溶解性。

公开(公告)号：US4845203A

公开(公告)日：1989-07-04

申请号：US92794

申请日：1987-09-03

申请人： Rolf Dietz ,  Herbert Seiler

发明人： Rolf Dietz ,  Herbert Seiler

IPC分类号： C09B62/09 ,  C09B62/01 ,  C09B62/44 ,  C09B62/513

CPC分类号： C09B62/4401 ,  C09B62/01

摘要： A fibre-reactive dye of the formula ##STR1## in which R.sub.1 is hydrogen, halogen, C.sub.1-14 -alkyl, C.sub.1-4 -alkoxy, nitro or carboxyl;X.sub.2 is hydrogen, vinylsulfonyl, .beta.-chloroethylsulfonyl, .beta.-sulfatoethylsulfonyl, .beta.-acetoxyethylsulfonyl or a radical of the formulaCl--CH.sub.2 --CH.sub.2 --SO.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --CO--NH-- orCl--CH.sub.2 --CH.sub.2 --SO.sub.2 --CH.sub.2 --CH.sub.2 --NH--CO--;n is 1 to 3;R.sub.2 is C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy; R.sub.3 is hydrogen C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, acetylamino, sulfoacetylamino, ureido or sulfo; andX.sub.1 is a radical of the formula ##STR2## in which Z is the radical of an amine comprising a vinylsulfonyl moiety, subject to the proviso that Z must not be a vinylsulfonylphenylamino or vinylsulfonylnaphtylamino moiety. These dyes are useful for dyeing and printing a wide variety of materials, and in particular cellulose-containing fibre materials.

摘要翻译： 其中R 1是氢，卤素，C 1-14 - 烷基，C 1-4 - 烷氧基，硝基或羧基的式（Ⅰ）＆lt; IMAGE＆gt;的纤维反应性染料; X2是氢，乙烯基磺酰基，β-氯乙基磺酰基，β-磺基乙基磺酰基，β-乙酰氧基乙基磺酰基或式Cl-CH 2 -CH 2 -SO 2 -CH 2 -CH 2 -CH 2 -CO-NH-或Cl-CH 2 -CH 2 -SO 2 - CH2-CH2-NH-CO-; n为1〜3; R2是C1-C4烷基或C1-C4烷氧基; R3是氢C1-C4烷基，C1-C4烷氧基，乙酰氨基，磺乙酰氨基，脲基或磺基; 并且X 1是式（Ⅶ）的基团，其中Z是包含乙烯基磺酰基部分的胺基团，条件是Z不能是乙烯基磺酰基苯基氨基或乙烯基磺酰基萘基氨基部分。 这些染料可用于染色和印刷各种材料，特别是含纤维素的纤维材料。

公开(公告)号：US4189570A

公开(公告)日：1980-02-19

申请号：US841762

申请日：1977-10-13

申请人： Emil Bonometti ,  Herbert Seiler

发明人： Emil Bonometti ,  Herbert Seiler

IPC分类号： C07D251/44 ,  C09B62/08 ,  C09B62/085

CPC分类号： C09B62/08 ,  C07D251/44

摘要： Process for producing compounds of the formula ##STR1## wherein R is hydrogen, methyl or ethyl, and n is 1 or 2, which process comprises condensing aminohydroxynaphthalenesulphonic acids of the formula ##STR2## with 2,4,6-trifluoro-s-triazine, in an aqueous solution or suspension, within a pH range which is defined bypK.sub.N(R)H .ltoreq.pH.ltoreq.(pK.sub.OH -2)wherein pK.sub.N(R)H and pK.sub.OH are the pK values respectively of the amino group and hydroxyl group of the aminohydroxynaphthalenesulphonic acid and pH is the hydrogen exponent, to give compounds of the formula (1).

摘要翻译： 制备下式化合物的方法（1）其中R是氢，甲基或乙基，n是1或2，该方法包括将下式（IMAGE）（2）的氨基羟基萘磺酸与2,4,6 在三氯三嗪三嗪中，在由pKN（H）pH（pKOH-2）定义的pH范围内的水溶液或悬浮液中，其中pKN（R）H和pKOH是pK 分别为氨基羟基萘磺酸的氨基和羟基，pH为氢指数，得到式（1）化合物。

公开(公告)号：US5023326A

公开(公告)日：1991-06-11

申请号：US435222

申请日：1989-11-09

申请人： Athanassios Tzikas ,  Herbert Seiler

发明人： Athanassios Tzikas ,  Herbert Seiler

IPC分类号： C09B62/008 ,  C09B62/085 ,  C09B62/245 ,  C09B62/44 ,  C09B62/47 ,  C09B62/473 ,  C09B62/51 ,  D06P3/66

CPC分类号： C09B62/47 ,  C09B62/0085 ,  C09B62/085 ,  C09B62/245 ,  C09B62/4413 ,  C09B62/51

摘要： Reactive dyes of the formula ##STR1## in which Y is hydrogen or sulfo, U is --CN, --CONH.sub.2, --SO.sub.3 H, --OH or --OSO.sub.3 H, D is a phenyl or naphthyl radical, which can be substituted by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, carboxyl and sulfo, and which contains at least one reactive radical bound direclty or via a bridge member to a ring carbon atom, or to which a further radical is bound which contains a reactive radical, and u is the number 2, 3, 4 or 5, are suitable in particular for the dyeing or printing of cellulose-containing fiber materials by the exhaust method or by the continuous method and product in combination with a high colorisitc yield dyeings and prints which have good fastness properties.

摘要翻译： 其中Y是氢或磺基的式（1）的反应性染料，U是-CN，-CONH 2，-SO 3 H，-OH或-OSO 3 H，D是苯基或萘基，其可被C1 C 4烷基，C 1 -C 4烷氧基，卤素，羧基和磺基，并且其含有至少一个反应性基团结合的直链或通过桥连构件连接至环碳原子，或另外的基团与其结合，其含有反应性基团，u 是2,3,4或5号，特别适用于通过排气法或连续法和产品与含有良好色泽的高色度染色和印花相结合的含纤维素纤维材料的染色或印花 坚牢性。

公开(公告)号：US4801694A

公开(公告)日：1989-01-31

申请号：US73323

申请日：1987-07-13

申请人： Peter Scheibli ,  Karl Seitz ,  Herbert Seiler ,  Athanassios Tzikas

发明人： Peter Scheibli ,  Karl Seitz ,  Herbert Seiler ,  Athanassios Tzikas

IPC分类号： C09B62/002 ,  C09B62/02 ,  C09B62/04 ,  C09B62/44 ,  C09B62/503 ,  D06P3/66 ,  C09B62/024 ,  C09B62/026 ,  C09B62/036

CPC分类号： C09B62/02 ,  C09B62/4403

摘要： Reactive dyes of the formula ##STR1## in which D is the radical of an organic dye of the monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthrone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide series, R is hydrogen or substituted or unsubstituted C.sub.1-4 -alkyl, X is a substituent which is detachable as an anion, B is a radical of the formula ##STR2## R.sub.1 and R.sub.2, independently of each other, are hydrogen or substituted or unsubstituted C.sub.1-4 -alkyl or phenyl, A is a substituted or unsubstituted aliphatic or aromatic bridge member, Y is a --CO--Z or --SO.sub.2 --Z radical, Z is an aliphatic, aromatic or heterocyclic reactive radical, and n is 1 or 2, are suitable for dyeing or printing cellulose-containing and nitrogen-containing materials and in high dyeing yield produce dyeings and prints having good fastness properties.

摘要翻译： 式（1）的活性染料其中D是单偶氮，多偶氮，金属络合物偶氮，蒽醌，酞菁，甲an，偶氮甲碱，二恶嗪，吩嗪，二苯乙烯，三苯基甲烷，呫吨，噻吨酮的有机染料的基团 硝基芳基，萘醌，芘醌或苝四碳酰亚胺系列，R为氢或取代或未取代的C1-4 - 烷基，X为可作为阴离子取代的取代基，B为下式的基团：R1和R2，独立地为 彼此是氢或取代或未取代的C1-4 - 烷基或苯基，A是取代或未取代的脂族或芳族桥连构件，Y是-CO-Z或-SO2-Z基团，Z是脂族，芳族或 杂环反应性基团，n为1或2，适用于染色或印刷含纤维素和含氮材料，并且在高染色率下产生具有良好牢度性能的染色和印花。

公开(公告)号：US4754023A

公开(公告)日：1988-06-28

申请号：US821213

申请日：1986-01-23

申请人： Athanassios Tzikas ,  Herbert Seiler ,  Peter Scheibli

发明人： Athanassios Tzikas ,  Herbert Seiler ,  Peter Scheibli

IPC分类号： C09B62/04 ,  C09B62/44 ,  C09B62/503 ,  C09B62/505 ,  C09B62/51 ,  C09B62/513 ,  C09B62/517 ,  C09B62/06 ,  C09B62/08 ,  C09B62/10

CPC分类号： C09B62/4403

摘要： A reactive dye of the formula ##STR1## in which: F is a radical selected from the group consisting of metal-free or metal-containing monoazo or disazo dyes containing at least one --SO.sub.3 H group, anthraquinone dyes, sulfophthalocyanine dyes, formazan dyes, phenazine dyes, oxazine dyes and nitroaryl dyes,R is hydrogen, C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted with --COOH or --SO.sub.3 H, cyanoethyl, or hydroxyethyl,X is fluorine, chlorine, bromine, --SO.sub.3 H, phenylsulfonyl or C.sub.1 -C.sub.4 -alkylsulfonyl,p is 1 or 2 andA is a radical of the formula ##STR2## in which: Y is chlorine, bromine, fluorine, --OH, --OSO.sub.3 H, --O-acyl, --CN, --COOH, --COO--C.sub.1 -C.sub.4 -alkyl, --CONH.sub.2 or --SO.sub.2 --Z,the group designated "alk" is a straight or branched polymethylene radical having 2 to 6 carbon atoms,V is ##STR3## hydrogen or C.sub.1 -C.sub.4 -alkyl which is unsubstituted or substituted by C.sub.1 -C.sub.2 -alkoxy, carboxyl, sulfo, halogen or hydroxy,Z is .beta.-halogenoethyl, vinyl or .beta.-acetoxyethyl, or A is a radical of the formulae ##STR4## in all of which R' is C.sub.1-6 -alkyl or hydrogen, Z is as defined above, o is 0 to 6, and m is 2 to 6.

摘要翻译： 式“IMAGE”的活性染料，其中：F是选自含有至少一个-SO 3 H基团的无金属或含金属单偶氮或双偶氮染料的基团，蒽醌染料，磺酞菁染料，甲an染料， 吩嗪染料，恶嗪染料和硝基芳基染料，R为氢，未被取代或被-COOH或-SO 3 H取代的C 1 -C 4烷基，氰乙基或羟乙基，X为氟，氯，溴，-SO 3 H，苯磺酰基或C 1 -C 4 - 烷基磺酰基，p是1或2，A是下式的基团，其中：Y是氯，溴，氟，-OH，-OSO 3 H，-O-酰基，-CN，-COOH，-COO- C 1 -C 4 - 烷基，-CONH 2或-SO 2 - Z，被称为“alk”的基团是具有2至6个碳原子的直链或支链多亚甲基，V是氢或未被取代的C 1 -C 4烷基， 被C 1 -C 2烷氧基，羧基，磺基，卤素或羟基取代，Z是β-卤代乙基，乙烯基或β-乙酰氧基乙基，或A是下式的基团： 其中R'为C 1-6 - 烷基或氢，Z如上所定义，o为0至6，m为2至6，> 。

公开(公告)号：US4631065A

公开(公告)日：1986-12-23

申请号：US767246

申请日：1985-08-20

申请人： Karl Seitz ,  Peter Scheibli ,  Herbert Seiler

发明人： Karl Seitz ,  Peter Scheibli ,  Herbert Seiler

IPC分类号： C09B62/085 ,  C09B62/02 ,  C09B62/165 ,  C09B62/17 ,  C09B62/245 ,  C09B62/25 ,  D06P3/00 ,  D06P3/66

CPC分类号： C09B62/02 ,  Y10S8/918

摘要： The invention relates to reactive dyes of the formula ##STR1## wherein D is the radical of a dye of the monoazo or polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide series, each of R.sub.1 and R.sub.2 independently is hydrogen or an unsubstituted or substituted C.sub.1 -C.sub.4 alkyl radical, X.sub.1 is an unsubstituted or substituted aminofluoro-s-triazine radical, and X.sub.2 is a heterocyclic reactive radical which is attached direct to the radical D through the --N(R.sub.2) bridge member, excepting an unsubstituted or substituted aminofluoro-s-triazine.These dyes are particularly suitable for dyeing and printing cellulosic fibre material by the cold pad-batch method and give dyeings and prints of good fastness properties and high tinctorial strength.

摘要翻译： 本发明涉及式（1）的活性染料，其中D是单偶氮或多偶氮，金属络合物偶氮，蒽醌，酞菁，甲an，偶氮甲碱，二恶嗪，吩嗪，二苯乙烯，三苯甲烷，呫吨的染料的基团 ，噻吨酮，硝基芳基，萘醌，芘醌或苝四碳酰亚胺系列，R 1和R 2各自独立地为氢或未取代或取代的C 1 -C 4烷基，X 1为未取代或取代的氨基氟三嗪基，X 2为杂环反应性基团 除了未取代或取代的氨基氟三嗪以外，它直接通过-N（R2）桥连接在基团D上。 这些染料特别适用于通过冷垫分批法对纤维素纤维材料进行染色和印花，并提供良好的牢度性能和高着色强度的染色和印花。

公开(公告)号：US4578457A

公开(公告)日：1986-03-25

申请号：US645878

申请日：1984-08-29

申请人： Herbert Seiler

发明人： Herbert Seiler

IPC分类号： C09B62/085 ,  D06P1/382 ,  C09B62/08

CPC分类号： C09B62/085 ,  Y10S8/918

摘要： The invention relates to novel reactive dyes of the formula ##STR1## wherein Z is --NH.sub.2, C.sub.1 -C.sub.6 alkylamino, N,N--di(C.sub.1 -C.sub.6)alkylamino, cyclohexylamino, N--(C.sub.1 -C.sub.6)alkyl-N-cyclohexylamino, N,N-dicyclohexylamino, phenyl(C.sub.1 -C.sub.2)alkylamino, N--(C.sub.2 -C.sub.4)alkyl-N-phenylamino, naphthylamino, a heterocyclic radical which is bound through an amino group and which may contain further fused carbocyclic rings, or a radical which is bound through the nitrogen atom of an N-heterocyclic ring and which may contain further hetero-atoms, and wherein the alkyl and cyclohexyl moieties, phenyl and naphthyl rings and heterocyclic radicals may be further substituted, and one Y is hydrogen and the other is sulfo. Strong red dyeings and prints are obtained with these dyes on cellulose fibres.

摘要翻译： 本发明涉及式（1）的新型活性染料，其中Z是-NH 2，C 1 -C 6烷基氨基，N，N-二（C 1 -C 6）烷基氨基，环己基氨基，N-（C 1 -C 6）烷基-N - 环己基氨基，N，N-二环己基氨基，苯基（C 1 -C 2）烷基氨基，N-（C 2 -C 4）烷基-N-苯基氨基，萘基氨基，通过氨基结合并可以含有其它稠合碳环的杂环基 或通过N-杂环的氮原子结合并且可以含有其它杂原子的基团，并且其中烷基和环己基部分，苯基和萘基环和杂环基可以被进一步取代，一个Y是 氢和另一个是磺基。 用这些染料在纤维素纤维上获得强烈的红色染色和印花。