公开(公告)号：US5457251A

公开(公告)日：1995-10-10

申请号：US006873

申请日：1993-01-21

申请人： Kunihiko Yamashita ,  Hideaki Obana ,  Issei Katsuta

发明人： Kunihiko Yamashita ,  Hideaki Obana ,  Issei Katsuta

IPC分类号： B01J8/22 ,  C07C5/11

CPC分类号： B01J8/228 ,  B01J8/222 ,  C07C5/11 ,  B01J2208/0084 ,  C07C2101/16 ,  C07C2523/46

摘要： Disclosed is a method for partially hydrogenating a monocyclic aromatic hydrocarbon to produce a cycloolefin, comprising reacting a monocyclic aromatic hydrocarbon with hydrogen in the presence of a particulate hydrogenation catalyst comprised mainly of metallic ruthenium, in a reaction system comprising a continuous aqueous phase having the particulate hydrogenation catalyst suspended therein, an oil phase containing the monocyclic aromatic hydrocarbon, and a gaseous phase comprising hydrogen gas, while applying a shearing force to the reaction system at a specific maximum shear rate. By the method of the present invention, not only can a cycloolefin be produced at high selectivity and in high yield, but also the catalytic activity can be stably maintained at a high level for a prolonged period of time.

摘要翻译： 公开了一种用于部分氢化单环芳烃以产生环烯烃的方法，包括在包含主要由金属钌组成的颗粒氢化催化剂存在下使单环芳族烃与氢反应，所述反应体系包含具有颗粒的连续水相 悬浮在其中的氢化催化剂，含有单环芳烃的油相和包含氢气的气相，同时以特定的最大剪切速率向反应体系施加剪切力。 通过本发明的方法，不仅可以高选择性和高收率地制备环烯烃，而且可以将催化活性稳定地维持在较高的水平长时间。

公开(公告)号：US5302762A

公开(公告)日：1994-04-12

申请号：US32220

申请日：1993-03-17

申请人： Kunihiko Yamashita ,  Hideaki Obana ,  Tadashi Kai

发明人： Kunihiko Yamashita ,  Hideaki Obana ,  Tadashi Kai

IPC分类号： C07B61/00 ,  B01J8/22 ,  B01J29/06 ,  B01J29/70 ,  C07C29/04 ,  C07C35/06 ,  C07C35/08

CPC分类号： B01J8/222 ,  B01J8/226 ,  B01J8/228 ,  C07C29/04 ,  B01J2208/0084 ,  B01J2219/185 ,  C07C2101/08 ,  C07C2101/14

摘要： Disclosed is a method for hydrating a cycloolefin, in which the hydration is conducted in a reaction system comprising a continuous aqueous phase including water and a crystalline aluminosilicate catalyst suspended therein and an oil phase including a cycloolefin, while dispersing the oil phase as globules having a specific diameter. By the method of the present invention, not only can a cyclic alcohol be produced at high selectivity and in high yield, but the activity of the catalyst can also be stably maintained at a high level for a prolonged period of time, and the produced cyclic alcohol can be readily separated.

摘要翻译： 公开了一种水合环烯烃的方法，其中水合在包括连续水相的反应体系中进行，该反应体系包含水和悬浮在其中的结晶硅铝酸盐催化剂和包含环烯烃的油相，同时将油相分散为具有 比直径。 通过本发明的方法，不仅可以高选择性和高收率地制备环状醇，而且催化剂的活性也可以在较长的时间内稳定地保持在高水平，并且所产生的环状 酒精可以容易地分离。

公开(公告)号：US4080425A

公开(公告)日：1978-03-21

申请号：US690134

申请日：1976-05-26

申请人： Tetsuo Tanaka ,  Tadatsugu Yamamoto ,  Yasuo Takahashi ,  Hideaki Obana ,  Kunio Watanabe ,  Kunihiko Wada ,  Kunihiko Yamashita ,  Kusuo Ohki

发明人： Tetsuo Tanaka ,  Tadatsugu Yamamoto ,  Yasuo Takahashi ,  Hideaki Obana ,  Kunio Watanabe ,  Kunihiko Wada ,  Kunihiko Yamashita ,  Kusuo Ohki

IPC分类号： B01D53/56 ,  F23C99/00 ,  F23G7/06 ,  C01B21/00

CPC分类号： B01D53/56

摘要： An exhaust gas containing nitrogen oxides is efficiently purified without the necessary use of catalysts by contacting the exhaust gas with a nitrile compound at high temperature in the presence of oxygen, whereby the nitrogen oxides and the nitrile compound are selectively decomposed into harmless materials.

摘要翻译： 含有氮氧化物的废气在不需要使用催化剂的情况下通过在氧气存在下在高温下与腈化合物接触而有效地纯化，由此氮氧化物和腈化合物被选择性分解成无害物质。