公开(公告)号：US20140018564A1

公开(公告)日：2014-01-16

申请号：US14007218

申请日：2012-03-29

申请人： Taichi Senda ,  Masaya Tanimoto ,  Hidenori Hanaoka

发明人： Taichi Senda ,  Masaya Tanimoto ,  Hidenori Hanaoka

IPC分类号： B01J31/22

CPC分类号： B01J31/2295 ,  B01J31/143 ,  B01J31/146 ,  B01J31/1608 ,  B01J2231/20 ,  B01J2531/40 ,  B01J2531/46 ,  C07C2/34 ,  C07C2531/14 ,  C07C2531/22 ,  C07F17/00 ,  C07C11/107

摘要： A silicon-bridged Cp-Ar transition metal complex is provided that serves as a catalytic component capable of efficiently and highly selectively producing 1-hexene through the trimerization reaction of ethylene. The transition metal complex is represented by formula (1): wherein M1 represents a transition metal atom of Group 4 of the Periodic Table of the Elements; Ar1 is an aryl group represented by formula (2), Ar2 is an aryl group represented by formula (3) and Ar3 is an aryl group represented by formula (4) (not all of the three aryl groups Ar1, Ar2 and Ar3 are the same at the same time), Wherein each of the X and R groups represents hydrogen or the like.

摘要翻译： 提供硅桥连Cp-Ar过渡金属络合物，其作为能够通过乙烯的三聚反应有效和高选择性地生产1-己烯的催化组分。 过渡金属络合物由式（1）表示：其中M1表示元素周期表第4族的过渡金属原子; Ar 1为式（2）所示的芳基，Ar 2为式（3）所示的芳基，Ar 3为式（4）所示的芳基（不是全部3个芳基Ar 1，Ar 2和Ar 3均为 同时），其中X和R基中的每一个表示氢等。

公开(公告)号：US20120326095A1

公开(公告)日：2012-12-27

申请号：US13575538

申请日：2011-01-27

申请人： Tomoyasu Yoshida ,  Hidenori Hanaoka ,  Shota Moriwaki

发明人： Tomoyasu Yoshida ,  Hidenori Hanaoka ,  Shota Moriwaki

IPC分类号： C08G61/02 ,  C09K11/02 ,  C08G73/02 ,  H01B1/12

CPC分类号： C09K11/06 ,  C08G61/10 ,  C08G61/12 ,  C08G2261/148 ,  C08G2261/3142 ,  C08G2261/3162 ,  C08G2261/411 ,  C08G2261/95 ,  C09K2211/1416 ,  H01L51/0035 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/5012 ,  H05B33/14

摘要： A polymer compound comprising a constitutional unit represented by the following formula (1-1) and/or formula (2-1); wherein R1, R2, R3, R4, R5, R6, R7, R8, R9 and R10 each independently represent a hydrogen atom, an optionally substituted alkyl group, an optionally substituted aryl group, an optionally substituted monovalent aromatic heterocyclic group, or the group —O—RA; where RA represents an optionally substituted alkyl group, an optionally substituted aryl group or an optionally substituted monovalent aromatic heterocyclic group, and when multiple RA groups are present, the RA groups may be the same or different.

摘要翻译： 包含由下式（1-1）和/或式（2-1）表示的结构单元的高分子化合物; 其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9和R 10各自独立地表示氢原子，任选取代的烷基，任选取代的芳基，任选取代的一价芳族杂环基或基团 -O-RA; 其中RA表示任选取代的烷基，任选取代的芳基或任选取代的一价芳族杂环基，当存在多个RA基时，RA基可以相同或不同。

公开(公告)号：US08084559B2

公开(公告)日：2011-12-27

申请号：US11795967

申请日：2006-01-24

申请人： Taichi Senda ,  Hidenori Hanaoka ,  Shinya Nakahara ,  Kenji Sogoh

发明人： Taichi Senda ,  Hidenori Hanaoka ,  Shinya Nakahara ,  Kenji Sogoh

IPC分类号： C08F4/64 ,  C08F4/76 ,  C08F4/52 ,  C07F17/00

CPC分类号： C08F10/00 ,  B01J31/2295 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/02 ,  C08F210/02 ,  C08F210/16 ,  C08F2420/02 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/659 ,  C08F4/6592 ,  C08F232/00 ,  C08F2500/17 ,  C08F2500/25 ,  C08F210/14

摘要： A transition metal complex represented by formula [1], and its production process; a substituent-carrying fluorene compound represented by formula [2], and its production process; an olefin polymerization catalyst component comprising the complex; an olefin polymerization catalyst obtained by contacting the catalyst component with a defined aluminum compound and/or a defined boron compound; and a production process of an olefin polymer using the catalyst:

摘要翻译： 由式[1]表示的过渡金属络合物及其制备方法; 由式[2]表示的带取代基的芴化合物及其制备方法; 包含所述络合物的烯烃聚合催化剂组分; 通过使催化剂组分与限定的铝化合物和/或定义的硼化合物接触获得的烯烃聚合催化剂; 和使用该催化剂的烯烃聚合物的生产方法：

公开(公告)号：US08026324B2

公开(公告)日：2011-09-27

申请号：US12531852

申请日：2008-03-18

申请人： Hidenori Hanaoka ,  Masaaki Nabika

发明人： Hidenori Hanaoka ,  Masaaki Nabika

IPC分类号： C08F4/642 ,  C08F4/6592 ,  C07F17/00 ,  B01J31/22

CPC分类号： C07F17/00 ,  C08F10/00 ,  C08F210/16 ,  C08F2420/02 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/10

摘要： A transition metal complex of the following formula (1): in which A represents an atom of Group 16 of the periodic table; B1 represents an atom of Group 14 of the periodic table; M1 represents a transition metal atom of Group 4 of the periodic table; Cp1 represents a group having a cyclopentadiene anion backbone; R1, R2, R3, R4, R5 and R6 represent independently of one another a hydrogen atom, a halogen atom, a C1-20 alkyl group optionally substituted with a halogen atom; R7, R8, R9, R10, R11 and R12 represent independently of one another a hydrogen atom, a C1-20 alkyl group optionally substituted with a halogen atom; and a 1,3-diene comprising R7, R8, R9, R10, R11, R12 and 4 carbon atoms coordinates on M1, and the 1,3-diene may be of either a cis or trans form, or a mixed form thereof, although the coordination form is not limited, and the double bonds may be delocalized. When this transition metal complex is used as a catalytic component, high molecular weight polyolefin is produced with high catalytic activity.

摘要翻译： 下式（1）的过渡金属络合物：其中A表示周期表第16族的原子; B1表示周期表第14族的原子; M1表示周期表第4族的过渡金属原子; Cp1表示具有环戊二烯阴离子主链的基团; R 1，R 2，R 3，R 4，R 5和R 6彼此独立地表示氢原子，卤素原子，任选被卤素原子取代的C 1-20烷基; R 7，R 8，R 9，R 10，R 11和R 12彼此独立地表示氢原子，任选被卤素原子取代的C 1-20烷基; 和在M 1上配位的包含R7，R8，R9，R10，R11，R12和4个碳原子的1,3-二烯，1,3-二烯可以是顺式或反式，或其混合形式， 虽然协调形式没有限制，双重债券可能会离域。 当该过渡金属络合物用作催化组分时，产生具有高催化活性的高分子量聚烯烃。

公开(公告)号：US07851569B2

公开(公告)日：2010-12-14

申请号：US12309082

申请日：2007-07-05

申请人： Taichi Senda ,  Hidenori Hanaoka

发明人： Taichi Senda ,  Hidenori Hanaoka

IPC分类号： C08F4/52 ,  C07F17/00 ,  C07F5/00 ,  B01J31/22

CPC分类号： C07F17/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/52 ,  C08F2500/03 ,  C08F2500/10 ,  C08F210/14 ,  C08F4/545

摘要： A rare earth metal complex represented by the formula (1): in which A represents a Group 14 element of the periodic table, Cp represents a group having a substituted or unsubstituted cyclopentadienyl anion moiety, Ln represents a Group 3 metal atom or a lanthanoid metal atom, R1 to R6 are the same or different, and represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, a silyl group substituted with a hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, R7 represents an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, or an aralkyl group having 7 to 20 carbon atoms, Xs represent a monoanionic ligand, Ys represent a neutral ligand, m represents an integer of 1 to 3, and n represents an integer of 0 to 3. The rare earth metal complex is useful as, for example, a catalyst for polymerization reaction of olefins. A polar monomer such as a lactone can be polymerized using the rare earth metal complex as a catalyst.

摘要翻译： 由式（1）表示的稀土金属络合物：其中A表示周期表的第14族元素，Cp表示具有取代或未取代的环戊二烯基阴离子部分的基团，Ln表示第3族金属原子或镧系金属 原子，R 1〜R 6相同或不同，表示氢原子，卤素原子，碳原子数1〜20的烷基，碳原子数6〜20的芳基，碳原子数7〜20的芳烷基 ，被碳原子数1〜20的烃基取代的甲硅烷基，碳原子数1〜20的烷氧基，碳原子数1〜20的烷基，碳原子数6〜20的芳基，碳原子数6〜20的芳基， 具有7〜20个碳原子的芳烷基，Xs表示单阴离子配体，Y表示中性配体，m表示1〜3的整数，n表示0〜3的整数。稀土金属络合物用于 例如，聚合催化剂反应 的烯烃。 可以使用稀土金属络合物作为催化剂使极性单体如内酯聚合。

公开(公告)号：US20100261857A1

公开(公告)日：2010-10-14

申请号：US12677750

申请日：2008-09-12

申请人： Taichi Senda ,  Hidenori Hanaoka

发明人： Taichi Senda ,  Hidenori Hanaoka

IPC分类号： C08F220/14 ,  C08F4/74 ,  C08F2/00

CPC分类号： C08F297/08 ,  C08F293/005

摘要： An olefin/(meth)acrylate block copolymer in which a polyolefin segment obtained by polymerization of an olefin is covalently-bonded to a poly(meth)acrylate segment obtained by polymerization of a (meth)acrylate compound, anda morphology has a micro phase-separation structure.

摘要翻译： 一种烯烃/（甲基）丙烯酸酯嵌段共聚物，其中通过烯烃聚合获得的聚烯烃链段与由（甲基）丙烯酸酯化合物聚合获得的聚（甲基）丙烯酸酯链段共价结合，并且形态具有微相 分离结构。

公开(公告)号：US07615660B2

公开(公告)日：2009-11-10

申请号：US11883242

申请日：2006-01-24

申请人： Taichi Senda ,  Hidenori Hanaoka

发明人： Taichi Senda ,  Hidenori Hanaoka

IPC分类号： C07F17/00 ,  C07F7/28

CPC分类号： C08F10/00 ,  B01J31/2295 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/02 ,  C08F210/02 ,  C08F210/16 ,  C08F2420/02 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/659 ,  C08F4/6592 ,  C08F232/00 ,  C08F2500/17 ,  C08F2500/25 ,  C08F210/14

摘要： The present invention provides a process for producing an alkoxy-titanium complex of formula (2) by reacting a titanium halide complex of formula (1) with an alkaline earth metal alkoxide: wherein A denotes a Group 14 element in a periodic table; R1, R2, R3, and R4 are the same or different and denote a hydrogen atom, halogen, a C1-20 alkyl group which may be substituted by halogen, a C6-20 aryl group which may be substituted by halogen, or the like; R5, R6, R7, R8, R9, and R10 are the same or different and independently denote a hydrogen atom, halogen, a C1-20 alkyl group which may be substituted by halogen, or the like; and X1 and X2 independently denote any halogen atom: wherein R11 and R12 are the same or different and independently denote a C1-20 alkyl group which may be substituted by halogen, or the like.

摘要翻译： 本发明提供通过使式（1）的卤化钛配合物与碱土金属醇盐反应来制备式（2）的烷氧基​​钛络合物的方法：其中A表示周期表中的第14族元素; R1，R2，R3和R4相同或不同，表示氢原子，卤素，可被卤素取代的C1-20烷基，可被卤素取代的C6-20芳基等 ; R 5，R 6，R 7，R 8，R 9和R 10相同或不同，独立地表示氢原子，卤素，可被卤素取代的C 1-20烷基等; X 1和X 2独立地表示任何卤素原子：其中R 11和R 12相同或不同，并且独立地表示可被卤素取代的C 1-20烷基等。

公开(公告)号：US20080319213A1

公开(公告)日：2008-12-25

申请号：US11660933

申请日：2005-07-11

申请人： Taichi Senda ,  Noriyuki Hida ,  Hidenori Hanaoka

发明人： Taichi Senda ,  Noriyuki Hida ,  Hidenori Hanaoka

IPC分类号： C07F7/00 ,  C07F7/28

CPC分类号： C07F17/00 ,  C08F10/00 ,  C08F2420/02 ,  C08F4/6592

摘要： The invention provides a process for producing a metallocene compound of formula (3) wherein R1 to R9 independently denote a hydrogen atom, a halogen atom, an alkyl, or the like; R10 denotes a halogen atom, an alkyl, an alkoxy, or the like; X5 and X6 independently denote a hydrogen atom, a halogen atom, or the like; and M denotes a transition metal atom of Group 4 of the Periodic Table, which process is characterized by reacting a silicon-substituted cyclopentadiene compound of formula (1) wherein R1 to R10 independently denote the same as described above; R11 denotes a hydrocarbon group or a tri-substituted silyl; and R12 to R14 independently denote a halogen atom or a hydrocarbon group, with a transition metal compound of the following formula (2) wherein M denotes the same as described above; X1, X2, X3, and X4 independently denotes a hydrogen atom, a halogen atom, an alkyl, or the like, in a solvent containing an aromatic hydrocarbon.

摘要翻译： 本发明提供了制备式（3）的茂金属化合物的方法，其中R 1至R 9独立地表示氢原子，卤素原子，烷基等; R 10表示卤素原子，烷基，烷氧基等; X 5和X 6独立地表示氢原子，卤素原子等; 并且M表示周期表第4族的过渡金属原子，该方法的特征在于使式（1）的硅取代的环戊二烯化合物（其中R 1至R 10独立地表示与上述相同的基团） R 11表示烃基或三取代甲硅烷基; 和R 12至R 14独立地表示卤素原子或烃基，与下式（2）的过渡金属化合物，其中M表示与上述相同的基团; X 1，X 2，X 3和X 4独立地表示在含有芳香族烃的溶剂中的氢原子，卤素原子，烷基等。

公开(公告)号：US20070135600A1

公开(公告)日：2007-06-14

申请号：US10577437

申请日：2004-10-27

申请人： Yuka Otomaru ,  Hidenori Hanaoka

发明人： Yuka Otomaru ,  Hidenori Hanaoka

IPC分类号： C08F4/46 ,  C07F9/02 ,  C07F11/00

CPC分类号： C07F9/5022 ,  B01J31/2404 ,  B01J2231/12 ,  B01J2531/46 ,  B01J2531/48 ,  C07F9/59 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F4/64186 ,  C08F4/64162 ,  C08F2500/03 ,  C08F2500/04 ,  C08F210/14 ,  C08F4/64027 ,  C08F4/64041

摘要： The invention provides a transition metal complex of formula (3) below: wherein R1, R2, R3, R4, R5, R6, R7 and R8 are the same or different and each independently represents a hydrogen atom, a halogen atom or a substituted or unsubstituted alkyl group having 1 to 10 carbon atom(s); R5 represents a hydrogen atom, a fluorine atom or a substituted or unsubstituted alkyl group having 1 to 10 carbon atom(s); X1 represents a hydrogen atom, a halogen atom or a substituted or unsubstituted alkyl group having 1 to 10 carbon atom(s); L represents a balancing counter ion or neutral ligand similar to X1 that is bonding or coordinating to metal M; and q represents an integer of 0 or 1, and G20 represents any one of G21 to G26 below: where A1 represents an element of Group 15 of the periodic table, wherein A1 in G23 represents an anion of an element of Group 15 of the periodic table, and A1 in G21 represents a nitrogen atom; R9, R14, R12, R13, R19, R20, R10, R11, R15, R16, R17, R18, R19, R20, R21 and R22 each independently represents, a hydrogen atom; or a substituted or unsubstituted alkyl groups having 1 to 10 carbon atom(s), and the line linking M and R20 represents that M is coordinated or linked to an element of Group 15 or 16 of the periodic table or to a fluorine atom constituting R20.

公开(公告)号：US20050154158A1

公开(公告)日：2005-07-14

申请号：US10503252

申请日：2003-02-06

申请人： Hidenori Hanaoka ,  Taichi Senda ,  Eiji Yoshikawa ,  Satoshi Kobayashi

发明人： Hidenori Hanaoka ,  Taichi Senda ,  Eiji Yoshikawa ,  Satoshi Kobayashi

IPC分类号： C07F7/10 ,  C07F7/28 ,  C07F17/00 ,  C08F4/64 ,  C08F4/645 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/02 ,  C08F210/16 ,  C08F4/44 ,  B01J31/00

CPC分类号： C08F10/00 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/02 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/10

摘要： A transition metal complex represented by the formula (1): wherein M is a Group 4 transition metal, A is a Group 16 element, B is a Group 14 element, n is an integer of 0 or 1, R1, R2, R3 and R4 may be the same or different and each independently denotes a substituent selected from the group consisting of the groups (I) and (II): group (I): hydrogen, alkyl and so on, group (II): alkoxy, alkylthio and so on, provided that at least one of R1, R2, R3 and R4 is a substituent selected from group (II); R5, R6, R7, R8, R9, R10, X1 and X2 may be the same or different and are each hydrogen, halogen, alkyd or the like; and a catalyst for olefin polymerization comprising said complex, an organoaluminum compound and a boron compound are provided.

摘要翻译： 由式（1）表示的过渡金属络合物：其中M是第4族过渡金属，A是第16族元素，B是第14族元素，n是0或1的整数，R 1， R 2，R 3，R 4和R 4可以相同或不同，并且各自独立地表示选自以下的取代基： 的基团（I）和（II）：基团（I）：氢，烷基等，基团（II）：烷氧基，烷硫基等，条件是R 1， R 2，R 3和R 4是选自（II）组的取代基。 R 5，R 6，R 7，R 8，R 9， R 10，X 1和X 2可以相同或不同，各自为氢，卤素，醇酸等; 并提供包含所述络合物，有机铝化合物和硼化合物的烯烃聚合催化剂。