摘要:
An electrode for a fuel cell of the invention comprises a cation-exchange resin, carbon particles and a catalyst metal which is amorphous. The electrode has high activity, a high catalyst utilization and high CO tolerance and is highly active in the electrochemical oxidation reaction of methanol. Furthermore these qualities of the electrode were extremely improved when the catalyst metal was loaded mainly on sites where the surface of the carbon particles contacts proton-conductive passages in the cation-exchange resin. Consequently, a fuel cell with the electrode of the invention has a high output current and a long life, and can be produced at low cost.
摘要:
The non-aqueous electrolyte secondary battery of the present invention comprises, e.g., a positive electrode 6, a negative electrode 5, a polymer membrane 1 containing carbon powder or the like, and a separating membrane layer 7 for preventing shortcircuiting. A carbon powder, silicon powder, tin powder or aluminum powder 2 contained in the polymer membrane 1 containing carbon powder or the like absorbs as a lithium-absorbing material metallic lithium powders 3 or metallic lithium dendrite 4 which has been produced from the negative electrode 5 due to charge or discharge and takes no part in charge or discharge. This lithium-absorbing material is less reactive than the metallic lithium powders 3 or metallic lithium dendrite 4 and thus enhances the safety of the battery and controls shortcircuiting between the positive electrode and the negative electrode due to metallic lithium dendrite, making it possible to drastically improve charge and discharge cycle life performance.
摘要:
A positive electrode active material for high voltage lithium battery which is represented by general formula LixMn2−yMyO4 LixMn2−yMyO4 (M: a 2-valency metal (Ni, Co, Fe, Mg, Zn), with 0.45≦y≦0.60, 0≦x≦1) having cubic spinel structure of lattice constant within 8.190 angstrom. Such an active material is manufactured by employing sol-gel process wherein one of inorganic salt, hydroxide and organic acid salt of lithium or a mixture of these for Li, one of inorganic salt and organic acid salt of manganese or a mixture of these for Mn, and one of inorganic salt and organic acid salt of the selected metal or a mixture of these for M are used as the starting materials for synthesis, ammonia water is added to the solutions of these starting materials in alcohol or water to obtain gelatinous material and the gelatinous material thus obtained is fired.
摘要:
An inexpensive positive electrode active material for lithium batteries which comprises lithium manganate having a hexagonal layered structure with space group of R3m and exhibits continuous discharge voltage characteristics between 4.5 V and 2 V for metallic lithium.
摘要:
A method for manufacturing positive a electrode active material for a lithium battery represented by general formula Li.sub.x Mn.sub.2-y M.sub.y O.sub.4 (M: a 2-valency metal, 0.45.ltoreq.y.ltoreq.0.60, 1.ltoreq.x.ltoreq.2.1) having cubic spinel structure of and a lattice constant within 8.190 angstroms by employing a solid phase reaction, comprising the steps of firing a lithium compound, a manganese compound and a metal M compound and refiring the fired material after pressurizing it at least once to remove a metal M oxide.
摘要:
A sealed alkaline secondary battery with a cadmium negative electrode employs a micro-porous separator having circular or elliptic pores, to thereby eliminate the occurrence of internal short-circuiting and to improve the oxygen gas absorption ability of the battery.
摘要:
A positive electrode active material for lithium battery which is represented by general formula Li.sub.x Mn.sub.2-y M.sub.y O.sub.4 (M: a 2-valency metal selected from Ni, Co, Fe and Zn with 0.45.ltoreq.y.ltoreq.0.60, 1.ltoreq.x.ltoreq.2.1) having cubic spinel structure of lattice constant within 8.190 angstrom. Such an active material is manufactured by employing sol-gel process wherein one of inorganic salt, hydroxide and organic acid salt of lithium or a mixture of these for Li, one of inorganic salt and organic acid salt of manganese or a mixture of these for Mn, and one of inorganic salt and organic acid salt of the selected metal or a mixture of these for M are used as the starting materials for synthesis, ammonia water is added to the solutions of these starting materials in alcohol or water to obtain gelatinous material and the gelatinous material thus obtained is fired.
摘要:
A positive electrode active material for lithium battery which is represented by general formula Li.sub.x Mn.sub.2-y M.sub.y O.sub.4 (M: a 2-valency metal, 0.45.ltoreq.y.ltoreq.0.60, 1.ltoreq.x.ltoreq.2.1) having cubic spinel structure of lattice constant within 8.190 angstroms.
摘要:
The positive active material for a secondary battery of the present invention is β-FeOOH containing at least one element selected from the group consisting of B, P, S, Li, Na, K, Mg, Al, Ca, Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Zr, Pb and Sn which shows a diffraction peak from the (110) plane having a half width Y satisfying 0.3°
摘要:
A positive active material contains lithium nickel-cobaltate, and its crystal structure is amorphous. The positive active material can further contain phosphorus. The cobalt in the positive active material can be present in a content in the range of 2 to 60 mol % (Co/(Ni+Co)). A lithium battery can contain the positive active material.