-
1.发明申请Process for Producing Phosphonium Borate Compound, Novel Phosphonium Borate Compound, and Method of Using the Same 有权制备硼酸鏻化合物，新型硼酸鏻化合物的方法及其使用方法公开(公告)号：US20110237799A1
公开(公告)日：2011-09-29
申请号：US13078118
申请日：2011-04-01
Applicant: Shin MASAOKA , Hideyuki IWAZAKI
Inventor： Shin MASAOKA , Hideyuki IWAZAKI
IPC: C07D213/16 , C07C253/30 , C07C227/10 , C07C67/343 , C07F7/08 , C07C213/08 , C07C29/58
CPC classification number: B01J31/32 , B01J31/0268 , B01J31/04 , B01J31/146 , B01J31/2234 , B01J31/24 , B01J31/2404 , B01J31/26 , B01J31/28 , B01J2231/4205 , B01J2231/4283 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/84 , C07C1/325 , C07C1/326 , C07C29/32 , C07C41/16 , C07C45/68 , C07C67/343 , C07C209/10 , C07C213/08 , C07C227/08 , C07C253/30 , C07F9/54 , C07C49/782 , C07C49/796 , C07C69/612 , C07C69/618 , C07C211/54 , C07C215/68 , C07C229/44 , C07C255/41 , C07C255/49 , C07C33/483 , C07C33/30 , C07C43/263 , C07C43/275
Abstract: The invention relates to methods for carbon-carbon bond forming reactions, carbon-nitrogen bond forming reactions and/or carbon-oxygen bond forming reactions using phosphonium borate compounds represented by the Formula: (R1)(R2)(R3)PH.BAr4, wherein R1, R2, R3, and Ar4 are as defined herein in combination with a transition metal, transition metal salt, transition metal oxide or transition metal complex.
Abstract translation: 本发明涉及使用由式（R1）（R2）（R3）PH.BAr4表示的硼酸硼酸盐化合物进行碳 - 碳键形成反应，碳 - 氮键形成反应和/或碳 - 氧键形成反应的方法， 其中R 1，R 2，R 3和Ar 4如本文所定义，与过渡金属，过渡金属盐，过渡金属氧化物或过渡金属络合物组合。
-
2.发明授权Process for producing phosphonium borate compound, novel phosphonium borate compound, and method of using the same 有权硼酸鏻化合物的制造方法，新型硼酸鏻化合物及其使用方法公开(公告)号：US08604249B2
公开(公告)日：2013-12-10
申请号：US12947311
申请日：2010-11-16
Applicant: Shin Masaoka , Hideyuki Iwazaki
Inventor： Shin Masaoka , Hideyuki Iwazaki
CPC classification number: B01J31/32 , B01J31/0268 , B01J31/04 , B01J31/146 , B01J31/2234 , B01J31/24 , B01J31/2404 , B01J31/26 , B01J31/28 , B01J2231/4205 , B01J2231/4283 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/84 , C07C1/325 , C07C1/326 , C07C29/32 , C07C41/16 , C07C45/68 , C07C67/343 , C07C209/10 , C07C213/08 , C07C227/08 , C07C253/30 , C07F9/54 , C07C49/782 , C07C49/796 , C07C69/612 , C07C69/618 , C07C211/54 , C07C215/68 , C07C229/44 , C07C255/41 , C07C255/49 , C07C33/483 , C07C33/30 , C07C43/263 , C07C43/275
Abstract: The invention relates to novel phosphonium borate compounds represented by the Formula: (R1)(R2)(R3)PH.BAr4, wherein R1, R2, R3 and Ar4 are as defined herein, and compositions including such phosphonium borate compounds in combination with a transition metal, transition metal salt, transition metal oxide or transition metal complex for use in carbon-carbon bond forming reactions, carbon-nitrogen bond forming reactions and carbon-oxygen bond forming reactions.
Abstract translation: 本发明涉及由式（R1）（R2）（R3）PH.BAr4表示的新的硼酸鏻化合物，其中R1，R2，R3和Ar4如本文所定义，组合物包括这种硼酸鏻化合物与 过渡金属，过渡金属盐，用于碳 - 碳键形成反应的过渡金属氧化物或过渡金属络合物，碳 - 氮键形成反应和碳 - 氧键形成反应。
-
公开(公告)号：US07250535B2
公开(公告)日：2007-07-31
申请号：US10503577
申请日：2003-02-03
Applicant: Shinya Maehara , Hideyuki Iwazaki
Inventor： Shinya Maehara , Hideyuki Iwazaki
IPC: C07F9/02
CPC classification number: C07F9/5068
Abstract: A production process by which tertiary phosphine with an attached sterically bulky hydrocarbon group is produced in a high yield and with high purity on an industrial scale through simple and safe operations by allowing a dialkylphosphinous halide to react with a Grignard reagent in the presence of a copper compound in an amount corresponding to 0.1 to 5% by mol based on the dialkylphosphinous halide to produce tertiary phosphine represented by the following formula (3): wherein R1 and R2 are each a tertiary hydrocarbon group of 4 to 13 carbon atoms, and R3 is an alkyl group, an alkenyl group, an aryl group or the like.
Abstract translation: 通过简单且安全的操作，通过使二烷基膦卤化物与格氏试剂在铜的存在下反应，通过简单且安全的操作，以高产率和高纯度产生具有附着的空间体积烃基的叔膦的生产方法 化合物的量相对于二烷基膦卤化物为0.1〜5摩尔％，以制备由下式（3）表示的叔膦：其中R 1和R 2， 各自为4〜13个碳原子的叔烃基，R 3为烷基，烯基，芳基等。
-
4.发明授权Process for producing phosphonium borate compound, novel phosphonium borate compound, and method of using the same 有权硼酸鏻化合物的制造方法，新型硼酸鏻化合物及其使用方法公开(公告)号：US08124809B2
公开(公告)日：2012-02-28
申请号：US13078118
申请日：2011-04-01
Applicant: Shin Masaoka , Hideyuki Iwazaki
Inventor： Shin Masaoka , Hideyuki Iwazaki
CPC classification number: B01J31/32 , B01J31/0268 , B01J31/04 , B01J31/146 , B01J31/2234 , B01J31/24 , B01J31/2404 , B01J31/26 , B01J31/28 , B01J2231/4205 , B01J2231/4283 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/84 , C07C1/325 , C07C1/326 , C07C29/32 , C07C41/16 , C07C45/68 , C07C67/343 , C07C209/10 , C07C213/08 , C07C227/08 , C07C253/30 , C07F9/54 , C07C49/782 , C07C49/796 , C07C69/612 , C07C69/618 , C07C211/54 , C07C215/68 , C07C229/44 , C07C255/41 , C07C255/49 , C07C33/483 , C07C33/30 , C07C43/263 , C07C43/275
Abstract: The invention relates to methods for carbon-carbon bond forming reactions, carbon-nitrogen bond forming reactions and/or carbon-oxygen bond forming reactions using phosphonium borate compounds represented by the Formula: (R1)(R2)(R3)PH.BAr4, wherein R1, R2, R3, and Ar4 are as defined herein in combination with a transition metal, transition metal salt, transition metal oxide or transition metal complex.
Abstract translation: 本发明涉及使用由式（R1）（R2）（R3）PH.BAr4表示的硼酸硼酸盐化合物进行碳 - 碳键形成反应，碳 - 氮键形成反应和/或碳 - 氧键形成反应的方法， 其中R 1，R 2，R 3和Ar 4如本文所定义，与过渡金属，过渡金属盐，过渡金属氧化物或过渡金属络合物组合。
-
Patent Agency Ranking
5.发明申请公开(公告)号：US20060020148A1
公开(公告)日：2006-01-26
申请号：US10503577
申请日：2003-02-03
Applicant: Shinya Maehara , Hideyuki Iwazaki
Inventor： Shinya Maehara , Hideyuki Iwazaki
IPC: C07F9/02
CPC classification number: C07F9/5068
Abstract: A production process by which tertiary phosphine with an attached sterically bulky hydrocarbon group is produced in a high yield and with high purity on an industrial scale through simple and safe operations by allowing a dialkylphosphinous halide to react with a Grignard reagent in the presence of a copper compound in an amount corresponding to 0.1 to 5% by mol based on the dialkylphosphinous halide to produce tertiary phosphine represented by the following formula (3): wherein R1 and R2 are each a tertiary hydrocarbon group of 4 to 13 carbon atoms, and R3 is an alkyl group, an alkenyl group, an aryl group or the like.
Abstract translation: 通过简单且安全的操作，通过使二烷基膦卤化物与格氏试剂在铜的存在下反应，通过简单且安全的操作，以高产率和高纯度产生具有附着的空间体积烃基的叔膦的生产方法 化合物的量相对于二烷基膦卤化物为0.1〜5摩尔％，以制备由下式（3）表示的叔膦：其中R 1和R 2， 各自为4〜13个碳原子的叔烃基，R 3为烷基，烯基，芳基等。
-
6.发明申请Process for producing phosponium borate compound, novel phosphonium borate compound, and method of using the same 有权硼酸硼酸盐化合物的制造方法，新型硼酸鏻化合物及其使用方法公开(公告)号：US20070098616A1
公开(公告)日：2007-05-03
申请号：US10580699
申请日：2004-11-26
Applicant: Shin Masaoka , Hideyuki Iwazaki
Inventor： Shin Masaoka , Hideyuki Iwazaki
CPC classification number: B01J31/32 , B01J31/0268 , B01J31/04 , B01J31/146 , B01J31/2234 , B01J31/24 , B01J31/2404 , B01J31/26 , B01J31/28 , B01J2231/4205 , B01J2231/4283 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/84 , C07C1/325 , C07C1/326 , C07C29/32 , C07C41/16 , C07C45/68 , C07C67/343 , C07C209/10 , C07C213/08 , C07C227/08 , C07C253/30 , C07F9/54 , C07C49/782 , C07C49/796 , C07C69/612 , C07C69/618 , C07C211/54 , C07C215/68 , C07C229/44 , C07C255/41 , C07C255/49 , C07C33/483 , C07C33/30 , C07C43/263 , C07C43/275
Abstract: The invention relates to a phosphonium borate compound represented by Formula (I) (hereinafter, the compound (I)). The invention has objects of providing (A) a novel process whereby the compound is produced safely on an industrial scale, by simple reaction operations and in a high yield; (B) a novel compound that is easily handled; and (C) novel use as catalyst. Formula (I): (R1)(R2)(R3)PH.BAr4 (I) wherein R1, R2, R3 and Ar are as defined in the specification. The process (A) includes reacting a phosphine with a) HCl or b) H2SO4 to produce a) a hydrochloride or b) a sulfate; and reacting the salt with a tetraarylborate compound. The compound (B) has for example a secondary or tertiary alkyl group as R1 and is easily handled in air without special attention. The use (C) is characterized in that the compound (I) is used instead of an unstable phosphine compound of a transition metal complex catalyst for catalyzing C—C bond, C—N bond and C—O bond forming reactions and the compound produces an effect that is equal to that achieved by the transition metal complex catalyst.
Abstract translation: 本发明涉及由式（I）表示的硼酸鏻化合物（以下称为化合物（I））。 本发明的目的是提供（A）通过简单的反应操作和高产率使化合物在工业规模上安全生产的新方法; （二）易于处理的新型化合物; 和（C）新型用作催化剂。 公式（I）：（R＆lt; 1＆lt; 1＆gt;）（R 2）（R 2） （I）<βin-line-formula description =“In-line Formulas”end =“tail”？>其中R 1 ，R 2，R 3和Ar如说明书中所定义。 方法（A）包括使膦与a）HCl或b）H 2 SO 4 4反应以产生a）盐酸盐或b）硫酸盐; 并使该盐与四芳基硼酸盐化合物反应。 化合物（B）具有例如作为R 1的仲或叔烷基，并且容易在空气中处理而没有特别注意。 使用（C）的特征在于，使用化合物（I）代替用于催化CC键，CN键和CO键形成反应的过渡金属络合物催化剂的不稳定膦化合物，并且该化合物产生等于 这通过过渡金属络合物催化剂实现。
-
7.发明申请Process for Producing Phosphonium Borate Compound, Novel Phosphonium Borate Compound, and Method of Using the Same 有权制备硼酸鏻化合物，新型硼酸鏻化合物的方法及其使用方法公开(公告)号：US20110166389A1
公开(公告)日：2011-07-07
申请号：US12947311
申请日：2010-11-16
Applicant: Shin MASAOKA , Hideyuki IWAZAKI
Inventor： Shin MASAOKA , Hideyuki IWAZAKI
IPC: C07F5/02
CPC classification number: B01J31/32 , B01J31/0268 , B01J31/04 , B01J31/146 , B01J31/2234 , B01J31/24 , B01J31/2404 , B01J31/26 , B01J31/28 , B01J2231/4205 , B01J2231/4283 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/84 , C07C1/325 , C07C1/326 , C07C29/32 , C07C41/16 , C07C45/68 , C07C67/343 , C07C209/10 , C07C213/08 , C07C227/08 , C07C253/30 , C07F9/54 , C07C49/782 , C07C49/796 , C07C69/612 , C07C69/618 , C07C211/54 , C07C215/68 , C07C229/44 , C07C255/41 , C07C255/49 , C07C33/483 , C07C33/30 , C07C43/263 , C07C43/275
Abstract: The invention relates to novel phosphonium borate compounds represented by the Formula: (R1)(R2)(R3)PH.BAr4, wherein R1, R2, R3 and Ar4 are as defined herein, and compositions including such phosphonium borate compounds in combination with a transition metal, transition metal salt, transition metal oxide or transition metal complex for use in carbon-carbon bond forming reactions, carbon-nitrogen bond forming reactions and carbon-oxygen bond forming reactions.
Abstract translation: 本发明涉及由式（R1）（R2）（R3）PH.BAr4表示的新的硼酸鏻化合物，其中R1，R2，R3和Ar4如本文所定义，组合物包括这种硼酸鏻化合物与 过渡金属，过渡金属盐，用于碳 - 碳键形成反应的过渡金属氧化物或过渡金属络合物，碳 - 氮键形成反应和碳 - 氧键形成反应。
-
8.发明授权Process for producing phosphonium borate compound, novel phosphonium borate compound, and method of using the same 有权硼酸鏻化合物的制造方法，新型硼酸鏻化合物及其使用方法公开(公告)号：US07728176B2
公开(公告)日：2010-06-01
申请号：US10580699
申请日：2004-11-26
Applicant: Shin Masaoka , Hideyuki Iwazaki
Inventor： Shin Masaoka , Hideyuki Iwazaki
IPC: C07F9/02
CPC classification number: B01J31/32 , B01J31/0268 , B01J31/04 , B01J31/146 , B01J31/2234 , B01J31/24 , B01J31/2404 , B01J31/26 , B01J31/28 , B01J2231/4205 , B01J2231/4283 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/84 , C07C1/325 , C07C1/326 , C07C29/32 , C07C41/16 , C07C45/68 , C07C67/343 , C07C209/10 , C07C213/08 , C07C227/08 , C07C253/30 , C07F9/54 , C07C49/782 , C07C49/796 , C07C69/612 , C07C69/618 , C07C211/54 , C07C215/68 , C07C229/44 , C07C255/41 , C07C255/49 , C07C33/483 , C07C33/30 , C07C43/263 , C07C43/275
Abstract: The invention relates to a phosphonium borate compound represented by Formula (I) (hereinafter, the compound (I)). The invention has objects of providing (A) a novel process whereby the compound is produced safely on an industrial scale, by simple reaction operations and in a high yield; (B) a novel compound that is easily handled; and (C) novel use as catalyst. Formula (I): (R1)(R2)(R3)PH.BAr4 (I) wherein R1, R2, R3 and Ar are as defined in the specification. The process (A) includes reacting a phosphine with a) HCl or b) H2SO4 to produce a) a hydrochloride or b) a sulfate; and reacting the salt with a tetraarylborate compound. The compound (B) has for example a secondary or tertiary alkyl group as R1 and is easily handled in air without special attention. The use (C) is characterized in that the compound (I) is used instead of an unstable phosphine compound of a transition metal complex catalyst for catalyzing C—C bond, C—N bond and C—O bond forming reactions and the compound produces an effect that is equal to that achieved by the transition metal complex catalyst.
Abstract translation: 本发明涉及由式（I）表示的硼酸鏻化合物（以下称为化合物（I））。 本发明的目的是提供（A）通过简单的反应操作和高产率使化合物在工业规模上安全生产的新方法; （二）易于处理的新型化合物; 和（C）新型用作催化剂。 式（I）：（R1）（R2）（R3）PH.BAr4（I）其中R1，R2，R3和Ar如说明书中所定义。 方法（A）包括使膦与a）HCl或b）H 2 SO 4反应以产生a）盐酸盐或b）硫酸盐; 并使该盐与四芳基硼酸盐化合物反应。 化合物（B）具有例如作为R 1的仲或叔烷基，并且容易在空气中处理而没有特别注意。 使用（C）的特征在于，使用化合物（I）来代替用于催化C-C键，C-N键和C-O键形成反应的过渡金属络合物催化剂的不稳定膦化合物，并且化合物产生 其效果等于过渡金属络合物催化剂所达到的效果。
-
9.发明申请Process for producing phosphonium borate compound, novel phosphonium borate compound, and method of using the same 审中-公开硼酸鏻化合物的制造方法，新型硼酸鏻化合物及其使用方法公开(公告)号：US20090305877A1
公开(公告)日：2009-12-10
申请号：US12420300
申请日：2009-04-08
Applicant: Shin Masaoka , Hideyuki Iwazaki
Inventor： Shin Masaoka , Hideyuki Iwazaki
CPC classification number: B01J31/32 , B01J31/0268 , B01J31/04 , B01J31/146 , B01J31/2234 , B01J31/24 , B01J31/2404 , B01J31/26 , B01J31/28 , B01J2231/4205 , B01J2231/4283 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/84 , C07C1/325 , C07C1/326 , C07C29/32 , C07C41/16 , C07C45/68 , C07C67/343 , C07C209/10 , C07C213/08 , C07C227/08 , C07C253/30 , C07F9/54 , C07C49/782 , C07C49/796 , C07C69/612 , C07C69/618 , C07C211/54 , C07C215/68 , C07C229/44 , C07C255/41 , C07C255/49 , C07C33/483 , C07C33/30 , C07C43/263 , C07C43/275
Abstract: The invention relates to a phosphonium borate compound represented by Formula (I) (hereinafter, the compound (I)). The invention has objects of providing (A) a novel process whereby the compound is produced safely on an industrial scale, by simple reaction operations and in a high yield; (B) a novel compound that is easily handled; and (C) novel use as catalyst. Formula (I): (R1)(R2)(R3)PH.BAr4 (I) wherein R1, R2, R3 and Ar are as defined in the specification. The process (A) includes reacting a phosphine with a) HCl or b) H2SO4 to produce a) a hydrochloride or b) a sulfate; and reacting the salt with a tetraarylborate compound.The compound (B) has for example a secondary or tertiary alkyl group as R1 and is easily handled in air without special attention.The use (C) is characterized in that the compound (I) is used instead of an unstable phosphine compound of a transition metal complex catalyst for catalyzing C—C bond, C—N bond and C—O bond forming reactions and the compound produces an effect that is equal to that achieved by the transition metal complex catalyst.
Abstract translation: 本发明涉及由式（I）表示的硼酸鏻化合物（以下称为化合物（I））。 本发明的目的是提供（A）通过简单的反应操作和高产率使化合物在工业规模上安全生产的新方法; （二）易于处理的新型化合物; 和（C）新型用作催化剂。 式（I）：（R1）（R2）（R3）PH.BAr4（I）其中R1，R2，R3和Ar如说明书中所定义。 方法（A）包括使膦与a）HCl或b）H 2 SO 4反应以产生a）盐酸盐或b）硫酸盐; 并使该盐与四芳基硼酸盐化合物反应。 化合物（B）具有例如作为R 1的仲或叔烷基，并且容易在空气中处理而没有特别注意。 使用（C）的特征在于，使用化合物（I）代替用于催化CC键，CN键和CO键形成反应的过渡金属络合物催化剂的不稳定膦化合物，并且该化合物产生等于 这通过过渡金属络合物催化剂实现。
-
-
-
-
-
-
-
-
Search Results
9
records
(took 0.02 seconds)
