公开(公告)号：US20110105638A1

公开(公告)日：2011-05-05

申请号：US12736055

申请日：2009-03-03

申请人： Masanao Kawabe ,  Hiroko Terao ,  Natsuko Okazaki

发明人： Masanao Kawabe ,  Hiroko Terao ,  Natsuko Okazaki

IPC分类号： C08L33/06 ,  C08G63/66 ,  C08L35/02 ,  B05D3/06

CPC分类号： C08F290/124 ,  C08F212/00 ,  C08F212/08 ,  C08F212/12 ,  C08F212/36 ,  C08F220/30 ,  G03F7/033 ,  C08F4/14 ,  C08F212/04 ,  C08F2220/301

摘要： An end-modified soluble polyfunctional vinyl aromatic copolymer, which is improved in heat resistance, thermal stability, solvent solubility, and compatibility with acrylate compounds, and a curable resin composition using the same are disclosed. The end-modified soluble polyfunctional vinyl aromatic copolymer is obtained by allowing a divinyl aromatic compound (a), a monovinyl aromatic compound (b), and an aromatic ether compound (c) to react with each other, and has, at an end, an end group derived from the aromatic ether compound and having an acrylate bond. The copolymer has a number average molecular weight Mn of 500 to 100,000, an introduction amount (c1) of the end group derived from the aromatic ether compound satisfies (c1)≧1.0 (group/molecule), a molar fraction a′ of a structural unit derived from the divinyl aromatic compound and a molar fraction b′ of a structural unit derived from the monovinyl aromatic compound in the copolymer satisfy 0.05≦a′/(a′+b′)≦0.95. Besides, the curable resin composition includes the copolymer and an unsaturated acrylate monomer.

摘要翻译： 公开了一种改进的耐热性，热稳定性，溶剂溶解性和与丙烯酸酯化合物的相容性的可溶性多官能乙烯基芳族共聚物，以及使用其的可固化树脂组合物。 通过使二乙烯基芳香族化合物（a），单乙烯基芳香族化合物（b）和芳香族醚化合物（c）彼此反应，得到末端改性的可溶性多官能乙烯基芳香族共聚物， 衍生自芳族醚化合物并具有丙烯酸酯键的端基。 共聚物的数均分子量Mn为500〜100,000，衍生自芳香族醚化合物的端基的导入量（c1）满足（c1）≥1.0（分组/分子），结构式 来自二乙烯基芳香族化合物的单元和来自共聚物中的单乙烯基芳香族化合物的结构单元的摩尔分数b'满足0.05＆lt; nlE; a'/（a'+ b'）＆nlE; 0.95。 此外，可固化树脂组合物包括共聚物和不饱和丙烯酸酯单体。

公开(公告)号：US08404797B2

公开(公告)日：2013-03-26

申请号：US12736055

申请日：2009-03-03

申请人： Masanao Kawabe ,  Hiroko Terao ,  Natsuko Okazaki

发明人： Masanao Kawabe ,  Hiroko Terao ,  Natsuko Okazaki

IPC分类号： C08G63/78 ,  C08F2/50 ,  C08F2/46 ,  C08J3/28 ,  B29D11/00 ,  G02B1/04

CPC分类号： C08F290/124 ,  C08F212/00 ,  C08F212/08 ,  C08F212/12 ,  C08F212/36 ,  C08F220/30 ,  G03F7/033 ,  C08F4/14 ,  C08F212/04 ,  C08F2220/301

摘要： An end-modified soluble polyfunctional vinyl aromatic copolymer, which is improved in heat resistance, thermal stability, solvent solubility, and compatibility with acrylate compounds, and a curable resin composition using the same are disclosed. The end-modified soluble polyfunctional vinyl aromatic copolymer is obtained by allowing a divinyl aromatic compound (a), a monovinyl aromatic compound (b), and an aromatic ether compound (c) to react with each other, and has, at an end, an end group derived from the aromatic ether compound and having an acrylate bond. The copolymer has a number average molecular weight Mn of 500 to 100,000, an introduction amount (c1) of the end group derived from the aromatic ether compound satisfies (c1)≧1.0 (group/molecule), a molar fraction a′ of a structural unit derived from the divinyl aromatic compound and a molar fraction b′ of a structural unit derived from the monovinyl aromatic compound in the copolymer satisfy 0.05≦a′/(a′+b′)≦0.95. Besides, the curable resin composition includes the copolymer and an unsaturated acrylate monomer.

摘要翻译： 公开了一种改进的耐热性，热稳定性，溶剂溶解性和与丙烯酸酯化合物的相容性的可溶性多官能乙烯基芳族共聚物，以及使用其的可固化树脂组合物。 通过使二乙烯基芳香族化合物（a），单乙烯基芳香族化合物（b）和芳香族醚化合物（c）彼此反应而得到末端改性的可溶性多官能乙烯基芳族共聚物， 衍生自芳族醚化合物并具有丙烯酸酯键的端基。 共聚物的数均分子量Mn为500〜100,000，衍生自芳香族醚化合物的端基的导入量（c1）满足（c1）≥1.0（分组/分子），结构式 来自二乙烯基芳香族化合物的单元和来自共聚物中的单乙烯基芳香族化合物的结构单元的摩尔分数b'满足0.05＆lt; nlE; a'/（a'+ b'）＆nlE; 0.95。 此外，可固化树脂组合物包括共聚物和不饱和丙烯酸酯单体。