公开(公告)号：US07687593B2

公开(公告)日：2010-03-30

申请号：US11528692

申请日：2006-09-28

申请人： Mikio Yamahiro ,  Koji Ohguma ,  Hisao Oikawa ,  Hisanobu Minamizawa ,  Hiroyuki Sato ,  Kenichi Watanabe

发明人： Mikio Yamahiro ,  Koji Ohguma ,  Hisao Oikawa ,  Hisanobu Minamizawa ,  Hiroyuki Sato ,  Kenichi Watanabe

IPC分类号： C08G77/12

CPC分类号： C08F214/18

摘要： Provided are: an addition polymer of fluorosilsesquioxane (a) having one addition polymerizable functional group or an addition copolymer of the fluorosilsesquioxane (a) having one addition polymerizable functional group and an addition polymerizable monomer (b); a coating film including the polymer or the copolymer; and an addition copolymer of the fluorosilsesquioxane (a) having one addition polymerizable functional group and organopolysiloxane (c) having an addition polymerizable functional group, or an addition copolymer of the fluorosilsesquioxane (a) having one addition polymerizable functional group, the organopolysiloxane (c) having an addition polymerizable functional group, and the addition polymerizable monomer (b).

摘要翻译： 提供：具有一个可加聚官能团的氟倍半硅氧烷（a）的加成聚合物或具有一个可加聚官能团的氟代倍半硅氧烷（a）和可加聚单体（b）的加成共聚物; 包含聚合物或共聚物的涂膜; 和具有一个加成聚合官能团的氟代倍半硅氧烷（a）和具有加聚性官能团的有机聚硅氧烷（c）的加成共聚物，或具有一个可加成聚合官能团的氟代倍半硅氧烷（a）的加成共聚物，有机聚硅氧烷（c） 具有可加成聚合的官能团和可加聚单体（b）。

公开(公告)号：US07399819B2

公开(公告)日：2008-07-15

申请号：US10528001

申请日：2003-09-17

申请人： Mikio Yamahiro ,  Hisao Oikawa ,  Kazuhiro Yoshida ,  Kenya Ito ,  Yasuhiro Yamamoto ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

发明人： Mikio Yamahiro ,  Hisao Oikawa ,  Kazuhiro Yoshida ,  Kenya Ito ,  Yasuhiro Yamamoto ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

IPC分类号： C08G77/24

CPC分类号： C08G77/442 ,  C07F7/21 ,  C08G77/045 ,  C08G77/38

摘要： A large part of conventional organic-inorganic composite materials is obtained by mechanical blending silsesquioxanes with organic polymers, and therefore it has been very difficult to control the structure thereof as the molecular aggregate of the composite materials. An object of the present invention is to provide a novel silicon compound having a living radical polymerization-initiating ability for an addition-polymerizable monomer and a polymer obtained using the same to thereby solve the problem described above regarding the conventional organic-inorganic composite materials. The present inventors have found that a novel silsesquioxane derivative to which a group having an ability to initiate polymerization of a monomer is useful as means for solving the problem described above. That is, the silsesquioxane derivative of the present invention is represented by Formula (1): wherein R1 is hydrogen, alkyl, aryl or arylalkyl; R2 and R3 are alkyl, phenyl or cyclohexyl; and A is a group having an ability to initiate polymerization of a monomer.

摘要翻译： 通过将倍半硅氧烷与有机聚合物机械共混获得大部分常规有机 - 无机复合材料，因此非常难以控制其作为复合材料的分子骨料的结构。 本发明的目的是提供一种具有可加聚单体的活性自由基聚合引发能力的新型硅化合物和使用该硅化合物获得的聚合物，从而解决了有关常规有机 - 无机复合材料的上述问题。 本发明人已经发现，具有引发单体聚合能力的基团的新型倍半硅氧烷衍生物可用作解决上述问题的手段。 也就是说，本发明的倍半硅氧烷衍生物由式（1）表示：其中R 1是氢，烷基，芳基或芳基烷基; R 2和R 3是烷基，苯基或环己基; 而A是具有引发单体聚合能力的基团。

公开(公告)号：US07291747B2

公开(公告)日：2007-11-06

申请号：US10478483

申请日：2002-05-17

申请人： Hisao Oikawa ,  Kenichi Watanabe ,  Nobumasa Ootake ,  Kazuhiro Yoshida ,  Keizou Iwatani

发明人： Hisao Oikawa ,  Kenichi Watanabe ,  Nobumasa Ootake ,  Kazuhiro Yoshida ,  Keizou Iwatani

IPC分类号： C07F7/00

CPC分类号： C07F7/21

摘要： An organic silicon compound, having high reactivity, represented by the following Formula (1): wherein R and M are defined in the specification. The organic silicon compound is produced by reacting polysilsesquioxane, which is obtained by hydrolyzing a silane compound having three hydrolyzable groups and represented by the following Formula (2), with a monovalent alkaline metal hydroxide in an organic solvent, or by subjecting the silane compound having three hydrolyzable groups to hydrolysis and polycondensation in the presence of an organic solvent and an alkaline metal hydroxide: R—Si X3  (2) wherein R is the same as in Formula (1) and X represents a hydrolyzable group.

摘要翻译： 具有高反应性的有机硅化合物由下式（1）表示：其中R和M在说明书中定义。 有机硅化合物是通过使有机硅溶胶中的硅烷化合物与有机溶剂中的一价碱金属氢氧化物水解而得到的聚倍半硅氧烷，其通过将具有3个可水解基团的硅烷化合物水解，由下式（2） 三个可水解基团在有机溶剂和碱金属氢氧化物存在下进行水解和缩聚：<？in-line-formula description =“In-line formula”end =“lead”？> R-Si X 3 （2）<？in-line-formula description =“In-line formula”end =“tail”？>其中R与式（1）中相同，X表示可水解基团。

公开(公告)号：US20070135602A1

公开(公告)日：2007-06-14

申请号：US11528692

申请日：2006-09-28

申请人： Mikio Yamahiro ,  Koji Ohguma ,  Hisao Oikawa ,  Hisanobu Minamizawa ,  Hiroyuki Sato ,  Kenichi Watanabe

发明人： Mikio Yamahiro ,  Koji Ohguma ,  Hisao Oikawa ,  Hisanobu Minamizawa ,  Hiroyuki Sato ,  Kenichi Watanabe

IPC分类号： C08F214/18

CPC分类号： C08F214/18

摘要： Provided are: an addition polymer of fluorosilsesquioxane (a) having one addition polymerizable functional group or an addition copolymer of the fluorosilsesquioxane (a) having one addition polymerizable functional group and an addition polymerizable monomer (b); a coating film including the polymer or the copolymer; and an addition copolymer of the fluorosilsesquioxane (a) having one addition polymerizable functional group and organopolysiloxane (c) having an addition polymerizable functional group, or an addition copolymer of the fluorosilsesquioxane (a) having one addition polymerizable functional group, the organopolysiloxane (c) having an addition polymerizable functional group, and the addition polymerizable monomer (b).

摘要翻译： 提供：具有一个可加聚官能团的氟倍半硅氧烷（a）的加成聚合物或具有一个可加聚官能团的氟代倍半硅氧烷（a）和可加聚单体（b）的加成共聚物; 包含聚合物或共聚物的涂膜; 和具有一个加成聚合官能团的氟代倍半硅氧烷（a）和具有加聚性官能团的有机聚硅氧烷（c）的加成共聚物，或具有一个可加成聚合官能团的氟代倍半硅氧烷（a）的加成共聚物，有机聚硅氧烷（c） 具有可加成聚合的官能团和可加聚单体（b）。

公开(公告)号：US20060287454A1

公开(公告)日：2006-12-21

申请号：US10548365

申请日：2004-03-05

申请人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Yasuhiro Yamamoto ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

发明人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Yasuhiro Yamamoto ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

IPC分类号： C08F230/08 ,  C07F7/04

CPC分类号： C08G77/04 ,  C07F7/21 ,  C08F10/00 ,  C08F30/08 ,  C08F2500/03

摘要： The present invention provides a silicon compound represented by Formula (1) and a polymer obtained by using the same, and this makes it possible not only to obtain an organic-inorganic composite material having a distinct structure but also to control the structure of the above polymer as a molecular aggregate. wherein R1 is a group independently selected from hydrogen, alkyl having a carbon atom number of 1 to 40, substituted or non-substituted aryl and substituted or non-substituted arylalkyl; in this alkyl having a carbon atom number of 1 to 40, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O—, —CH═CH—, cycloalkylene or cycloalkenylene; in alkylene in this arylalkyl, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O— or —CH═CH—; and A1 is a group having an α-haloester bond.

摘要翻译： 本发明提供由式（1）表示的硅化合物和使用它的聚合物，不仅可以获得具有不同结构的有机 - 无机复合材料，而且可以控制上述结构 聚合物作为分子聚集体。 其中R 1是独立地选自氢，碳原子数为1至40的烷基，取代或未取代的芳基和取代或未取代的芳基烷基的基团; 在该碳原子数为1至40的烷基中，任选的氢可被氟取代，并且任选的-CH 2 - 可以被-O-，-CH-CH-，亚环烷基或 环亚烯基 在该芳烷基中的亚烷基中，任选的氢可以被氟取代，任选的-CH 2 - 可以被-O-或-CH-CH-取代; 且A 1是具有α-卤代酯键的基团。

公开(公告)号：US07964692B2

公开(公告)日：2011-06-21

申请号：US12318733

申请日：2009-01-07

申请人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Yasuhiro Yamamoto ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

发明人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Yasuhiro Yamamoto ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

IPC分类号： C08G77/04

CPC分类号： C08G77/04 ,  C07F7/21 ,  C08F10/00 ,  C08F30/08 ,  C08F2500/03

摘要： A polymer represented by Formula (7): wherein all variables are defined in the specification, including P1 which is a polymer chain obtained by polymerizing an addition-polymerizable monomer, which makes it possible to control the structure of the polymer as a molecular aggregate.

摘要翻译： 由式（7）表示的聚合物：其中所有变量在本说明书中定义，包括P1是通过聚合可加聚单体获得的聚合物链，其可以将聚合物的结构控制为分子聚集体。

公开(公告)号：US07868112B2

公开(公告)日：2011-01-11

申请号：US12519347

申请日：2007-12-17

申请人： Hisao Oikawa ,  Koji Ohguma ,  Kenya Ito ,  Minoru Nakayama ,  Shin Koga ,  Mikio Yamahiro ,  Hiroyuki Sato

发明人： Hisao Oikawa ,  Koji Ohguma ,  Kenya Ito ,  Minoru Nakayama ,  Shin Koga ,  Mikio Yamahiro ,  Hiroyuki Sato

IPC分类号： C08F30/08

CPC分类号： C08F290/06 ,  C08F283/12 ,  C08F290/068 ,  C08F290/14 ,  C08F290/148 ,  C08G77/04 ,  C08G77/24 ,  C08G77/385

摘要： A polymer containing: a constitutional unit A that is derived from fluorosilsesquioxane having one addition polymerizable functional group in a molecule; a constitutional unit B that is derived from organopolysiloxane having an addition polymerizable functional group; and a constitutional unit C that is derived from an addition polymerizable monomer and has a group having a polymerizable unsaturated bond on a side chain, and optionally containing a constitutional unit D that is derived from an addition polymerizable monomer other than the fluorosilsesquioxane having one addition polymerizable functional group in a molecule, the organopolysiloxane having an addition polymerizable functional group and the addition polymerizable monomer having a functional group capable of introducing a group having a polymerizable unsaturated bond.

摘要翻译： 含有：分子内具有一个加成聚合官能团的氟代倍半硅氧烷的结构单元A的聚合物; 衍生自具有可加聚官能团的有机聚硅氧烷的结构单元B; 和由可加成聚合单体衍生的具有在侧链上具有聚合性不饱和键的基团的结构单元C，并且任选地含有来自除了具有一个可加聚可聚合的氟代倍半硅氧烷之外的可加聚单体的结构单元D 分子中的官能团，具有加聚性官能团的有机聚硅氧烷和具有能够引入具有聚合性不饱和键的基团的官能团的加成聚合性单体。

公开(公告)号：US07863396B2

公开(公告)日：2011-01-04

申请号：US10548365

申请日：2004-03-05

申请人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Yasuhiro Yamamoto ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

发明人： Mikio Yamahiro ,  Hisao Oikawa ,  Kenya Ito ,  Yasuhiro Yamamoto ,  Masami Tanaka ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

IPC分类号： C08F130/08

CPC分类号： C08G77/04 ,  C07F7/21 ,  C08F10/00 ,  C08F30/08 ,  C08F2500/03

摘要： The present invention provides a silicon compound represented by Formula (1) and a polymer obtained by using the same, and this makes it possible not only to obtain an organic-inorganic composite material having a distinct structure but also to control the structure of the above polymer as a molecular aggregate. wherein R1 is a group independently selected from hydrogen, alkyl having a carbon atom number of 1 to 40, substituted or non-substituted aryl and substituted or non-substituted arylalkyl; in this alkyl having a carbon atom number of 1 to 40, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O—, —CH═CH—, cycloalkylene or cycloalkenylene; in alkylene in this arylalkyl, optional hydrogens may be substituted with fluorine, and optional —CH2— may be substituted with —O— or —CH═CH—; and A1 is a group having an α-haloester group.

摘要翻译： 本发明提供由式（1）表示的硅化合物和使用它的聚合物，不仅可以获得具有不同结构的有机 - 无机复合材料，而且可以控制上述结构 聚合物作为分子聚集体。 其中R1是独立地选自氢，碳原子数为1至40的烷基，取代或未取代的芳基和取代或未取代的芳基烷基的基团; 在该碳原子数为1至40的烷基中，任选的氢可以被氟取代，并且任选的-CH 2 - 可以被-O - ， - CH = CH-，亚环烷基或环亚烯基取代; 在该芳烷基中的亚烷基中，任选的氢可以被氟取代，并且任选的-CH 2 - 可以被-O-或-CH = CH-取代; A1为具有α-卤代基团的基团。

公开(公告)号：US20100093951A1

公开(公告)日：2010-04-15

申请号：US12519354

申请日：2007-12-17

申请人： Hisao Oikawa ,  Koji Ohguma ,  Kenya Ito ,  Mikio Yamahiro

发明人： Hisao Oikawa ,  Koji Ohguma ,  Kenya Ito ,  Mikio Yamahiro

IPC分类号： C08L83/06 ,  C08G77/04 ,  C08G77/14

CPC分类号： C08F283/12 ,  C08F290/00 ,  C08F290/06 ,  C08F290/068 ,  C08F290/14 ,  C08F290/148 ,  C08G77/385 ,  C08G77/442 ,  C08L55/00 ,  C09D155/00 ,  C08L2666/02

摘要： A polymer containing: a constitutional unit A that is derived from fluorosilsesquioxane having one addition polymerizable functional group in a molecule; a constitutional unit B that is derived from organopolysiloxane having an addition polymerizable functional group; and a constitutional unit C that is derived from an addition polymerizable functional monomer containing a group having active hydrogen, and optionally containing a constitutional unit D that is derived from an addition polymerizable monomer other than the fluorosilsesquioxane having one addition polymerizable functional group in a molecule, the organopolysiloxane having an addition polymerizable functional group and the addition polymerizable monomer containing a group having active hydrogen.

摘要翻译： 含有：分子内具有一个加成聚合官能团的氟代倍半硅氧烷的结构单元A的聚合物; 衍生自具有可加聚官能团的有机聚硅氧烷的结构单元B; 和由含有具有活性氢的基团的加成聚合性官能单体衍生的结构单元C，并且任选地含有来自除了在分子中具有一个加成聚合官能团的氟代倍半硅氧烷以外的加聚性单体的结构单元D， 具有加聚性官能团的有机聚硅氧烷和含有具有活性氢的基团的加成聚合性单体。

公开(公告)号：US08445613B2

公开(公告)日：2013-05-21

申请号：US12531606

申请日：2008-03-21

申请人： Kenya Ito ,  Hisao Oikawa ,  Koji Ohguma ,  Mikio Yamahiro

发明人： Kenya Ito ,  Hisao Oikawa ,  Koji Ohguma ,  Mikio Yamahiro

IPC分类号： C08F30/08

CPC分类号： C08F290/148 ,  C08F283/12 ,  C08F290/06 ,  C08F290/068 ,  C08G77/04 ,  C08G77/24 ,  C09D143/04 ,  Y10T428/31855

摘要： A polymer and a treating agent (such as a surface-treating agent) are provided that have excellent characteristics in such properties as water repellency, oil repellency, antifouling property and charge controlling property. The polymer contains a structural unit derived from fluorosilsesquioxane having an addition polymerizable group, or contains a structural unit derived from fluorosilsesquioxane having an addition polymerizable group and a structural unit derived from organopolysiloxane having an addition polymerizable group. The treating agent contains the polymer. An article treated with the treating agent is also provided.

摘要翻译： 提供聚合物和处理剂（例如表面处理剂），其具有防水性，拒油性，防污性和电荷控制性等性能优异的特性。 聚合物含有衍生自具有加成聚合基团的氟代倍半硅氧烷的结构单元，或含有衍生自具有加聚性基团的氟代倍半硅氧烷的结构单元和衍生自具有加成聚合基团的有机聚硅氧烷的结构单元。 处理剂含有聚合物。 还提供了用处理剂处理的制品。