公开(公告)号：US09751286B2

公开(公告)日：2017-09-05

申请号：US14129990

申请日：2012-07-02

申请人： Akiko Yoda ,  Kenya Ito ,  Koji Ohguma ,  Mikio Yamahiro

发明人： Akiko Yoda ,  Kenya Ito ,  Koji Ohguma ,  Mikio Yamahiro

IPC分类号： B32B27/18 ,  B32B27/30 ,  B32B27/08 ,  B32B27/36

CPC分类号： B32B27/18 ,  B32B27/08 ,  B32B27/308 ,  B32B27/36 ,  B32B2307/40 ,  B32B2307/71 ,  B32B2307/712 ,  B32B2457/20 ,  Y10T428/24975 ,  Y10T428/31797 ,  Y10T428/31928

摘要： Provided is a multi-layered weather-resistant multilayer film that exhibits good substrate adhesion, wherein curing problems are avoided, bleed-out is minimized, yellowing is reduced, and weather-resistance is improved. The weather-resistant multilayer film 10 is provided with the following: a transparent film-like substrate C; a UV-absorbing resin layer B laminated on the substrate C and containing a UV absorber; and a first cured resin layer A laminated on the UV-absorbing resin layer B. The first cured resin layer A has a thickness of 1.0 to 10 μm. The UV-absorbing resin layer B has a thickness of 0.5 to 5 μm. The UV-absorbing resin layer B has an absorption wavelength of 200 to 500 nm.

公开(公告)号：US09375867B2

公开(公告)日：2016-06-28

申请号：US14127964

申请日：2012-06-18

申请人： Kenya Ito ,  Koji Ohguma ,  Takuro Tanaka ,  Yuka Takahashi ,  Aki Kuromatsu ,  Mikio Yamahiro

发明人： Kenya Ito ,  Koji Ohguma ,  Takuro Tanaka ,  Yuka Takahashi ,  Aki Kuromatsu ,  Mikio Yamahiro

IPC分类号： B29C45/14 ,  B32B27/16 ,  B44C1/17 ,  B32B7/06 ,  B32B38/00

CPC分类号： B29C45/14688 ,  B29C45/14 ,  B29C45/14811 ,  B29C45/14827 ,  B32B7/06 ,  B32B27/16 ,  B32B38/0036 ,  B32B2270/00 ,  B32B2451/00 ,  B44C1/1729 ,  Y10T428/24851 ,  Y10T428/31511 ,  Y10T428/31515 ,  Y10T428/31551 ,  Y10T428/31554 ,  Y10T428/31598 ,  Y10T428/31663 ,  Y10T428/31946

摘要： Provided is a transfer film for in-mold molding which is superior in solvent resistance, heat resistance, durability, blocking resistance, and moldability, and is capable of suppressing the generation of gate flow, and also provided is a method for producing such a film. The film is provided with: a transfer layer (11) which is to be transferred to an in-mold molded body and which is to be cured when irradiated with active energy rays after the transfer; and a film shaped substrate (L0). The transfer layer (11) comprises an IMD layer (L2) laminated on the substrate (L0) and to be arranged on the outermost surface of the molded body after the in-mold molding. The IMD layer (L2) is constituted by a mixture composition containing at least one active-energy curable resin and at least one thermosetting resin.

摘要翻译： 提供了一种模内成型用转印膜，其耐溶剂性，耐热性，耐久性，耐粘连性和成型性优异，并且能够抑制栅极流动的产生，并且还提供了制造这种膜的方法 。 膜设置有：转印层（11），其被转印到模内成型体中，并且在转印后用活性能量射线照射时被固化; 和薄膜状基板（L0）。 转印层（11）包括层叠在基板（L0）上的IMD层（L2），并且在模内成型之后布置在成形体的最外表面上。 IMD层（L2）由含有至少一种活性能量固化树脂和至少一种热固性树脂的混合物组合物构成。

公开(公告)号：US20100137540A1

公开(公告)日：2010-06-03

申请号：US12531606

申请日：2008-03-21

申请人： Kenya Ito ,  Hisao Oikawa ,  Koji Ohguma ,  Mikio Yamahiro

发明人： Kenya Ito ,  Hisao Oikawa ,  Koji Ohguma ,  Mikio Yamahiro

IPC分类号： C08F230/08

CPC分类号： C08F290/148 ,  C08F283/12 ,  C08F290/06 ,  C08F290/068 ,  C08G77/04 ,  C08G77/24 ,  C09D143/04 ,  Y10T428/31855

摘要： A polymer and a treating agent (such as a surface-treating agent) are provided that have excellent characteristics in such properties as water repellency, oil repellency, antifouling property and charge controlling property. The polymer contains a structural unit derived from fluorosilsesquioxane having an addition polymerizable group, or contains a structural unit derived from fluorosilsesquioxane having an addition polymerizable group and a structural unit derived from organopolysiloxane having an addition polymerizable group. The treating agent contains the polymer. An article treated with the treating agent is also provided.

摘要翻译： 提供聚合物和处理剂（例如表面处理剂），其具有防水性，拒油性，防污性和电荷控制性等性能优异的特性。 聚合物含有衍生自具有加成聚合基团的氟代倍半硅氧烷的结构单元，或含有衍生自具有加聚性基团的氟代倍半硅氧烷的结构单元和衍生自具有加成聚合基团的有机聚硅氧烷的结构单元。 处理剂含有聚合物。 还提供了用处理剂处理的制品。

公开(公告)号：US20070032454A1

公开(公告)日：2007-02-08

申请号：US11545594

申请日：2006-10-11

申请人： Yoshitaka Morimoto ,  Kenichi Watanabe ,  Nobumasa Ootake ,  Jyun-ichi Inagaki ,  Kazuhiro Yoshida ,  Koji Ohguma

发明人： Yoshitaka Morimoto ,  Kenichi Watanabe ,  Nobumasa Ootake ,  Jyun-ichi Inagaki ,  Kazuhiro Yoshida ,  Koji Ohguma

IPC分类号： A61K31/695 ,  C07F7/00

CPC分类号： C08G77/20 ,  C07F7/21 ,  C08G77/04 ,  C08G77/045 ,  C08G77/14

摘要： The present inventors have obtained a PSQ derivative of a completely condensed type into which a functional group is readily introduced by using a novel PSQ derivative of an incompletely condensed type in which four alkaline metal atoms are bonded to silsesquioxane of a cage type having eight Si's. The above silsesquioxane derivative is represented by Formula (1). A silsesquioxane derivative to which alkaline metal atoms are bonded is represented by Formula (2). In Formula (1) and Formula (2), R is a group selected from alkyl, aryl and arylalkyl; Y is a group represented by Formula (a) or Formula (b); and M is a monovalent alkaline metal atom. X in Formula (a) and Formula (b) is hydrogen, halogen, a hydroxyl group or a monovalent organic group, and Z is —O—, —CH2— or a single bond. The preferred organic group is a functional group or a group having a functional group.

摘要翻译： 本发明人已经获得了一种完全冷凝型的PSQ衍生物，其中通过使用四种碱金属原子与具有八个Si的笼型的倍半硅氧烷结合的不完全冷凝型的新型PSQ衍生物容易地引入官能团。 上述倍半硅氧烷衍生物由式（1）表示。 碱金属原子键合的倍半硅氧烷衍生物由式（2）表示。 在式（1）和式（2）中，R是选自烷基，芳基和芳烷基的基团; Y为式（a）或式（b）所示的基团。 M为单价碱金属原子。 式（a）和式（b）中的X为氢，卤素，羟基或一价有机基团，Z为-O-，-CH 2 - 或单键。 优选的有机基团是官能团或具有官能团的基团。

公开(公告)号：US20060175684A1

公开(公告)日：2006-08-10

申请号：US11316847

申请日：2005-12-27

申请人： Hisao Oikawa ,  Mikio Yamahiro ,  Koji Ohguma ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

发明人： Hisao Oikawa ,  Mikio Yamahiro ,  Koji Ohguma ,  Nobumasa Ootake ,  Kenichi Watanabe ,  Kohji Ohno ,  Yoshinobu Tsujii ,  Takeshi Fukuda

IPC分类号： H01L23/58 ,  H01L21/31

CPC分类号： C07F7/21

摘要： Since the majority of conventional organic/inorganic composite materials are obtained by mechanical blending of a silsesquioxane and an organic polymer or other means, it was extremely difficult to control the structure of the composite as a molecular agglomerate. In order to solve such a problem, the invention is to provide a silicon compound represented by Formula (1). This novel silicon compound has a living radical polymerization initiating ability for addition polymerizable monomers of a wide range. In Formula (1), R1 is hydrogen, an alkyl, an aryl, or an arylalkyl; R2 is an alkyl, phenyl, or cyclohexyl; and A is a group having a polymerization initiating ability for addition polymerizable monomers.

摘要翻译： 由于大多数常规有机/无机复合材料是通过机械共混倍半硅氧烷和有机聚合物或其它方法获得的，所以非常难以控制复合材料的结构作为分子聚集体。 为了解决这个问题，本发明提供一种由式（1）表示的硅化合物。 该新型硅化合物具有广泛范围的可加聚单体的活性自由基聚合引发能力。 在式（1）中，R 1是氢，烷基，芳基或芳基烷基; R 2是烷基，苯基或环己基; A是具有加成聚合性单体的聚合引发能力的基团。

公开(公告)号：US09857505B2

公开(公告)日：2018-01-02

申请号：US13880048

申请日：2011-10-13

申请人： Yuka Takahashi ,  Takuro Tanaka ,  Yukio Hirano ,  Koji Ohguma ,  Mikio Yamahiro

发明人： Yuka Takahashi ,  Takuro Tanaka ,  Yukio Hirano ,  Koji Ohguma ,  Mikio Yamahiro

IPC分类号： G02B27/00 ,  G02B1/111 ,  C08J7/04

CPC分类号： G02B1/111 ,  B32B27/30 ,  C08J7/04 ,  C08J7/047 ,  C08J2383/14 ,  G02B27/0006

摘要： A laminate body (1) is provided with a transparent substrate (10) and a refractive layer (11) which refracts incident light towards the top of the substrate (10). The refractive layer (11) contains, at least, one kind of fluorine compound (ss) selected from a group consisting of fluoro-silsesquioxane and fluoro-silsesquioxane polymers, and a resin (pl) having a refractive index higher than that of the aforementioned fluorine compound (ss). Of the side of the substrate (10) (the side of the back surface s2) and the side opposite thereof (the side of the front surface s1), the concentration of the fluorine compound (ss) in the refractive layer (11) is higher on said side opposite (the side of the front surface s1), and the refractive layer (11) forms a graded structure layer of high refractive indices and low refractive indices inside the layer.

公开(公告)号：US07868112B2

公开(公告)日：2011-01-11

申请号：US12519347

申请日：2007-12-17

申请人： Hisao Oikawa ,  Koji Ohguma ,  Kenya Ito ,  Minoru Nakayama ,  Shin Koga ,  Mikio Yamahiro ,  Hiroyuki Sato

发明人： Hisao Oikawa ,  Koji Ohguma ,  Kenya Ito ,  Minoru Nakayama ,  Shin Koga ,  Mikio Yamahiro ,  Hiroyuki Sato

IPC分类号： C08F30/08

CPC分类号： C08F290/06 ,  C08F283/12 ,  C08F290/068 ,  C08F290/14 ,  C08F290/148 ,  C08G77/04 ,  C08G77/24 ,  C08G77/385

摘要： A polymer containing: a constitutional unit A that is derived from fluorosilsesquioxane having one addition polymerizable functional group in a molecule; a constitutional unit B that is derived from organopolysiloxane having an addition polymerizable functional group; and a constitutional unit C that is derived from an addition polymerizable monomer and has a group having a polymerizable unsaturated bond on a side chain, and optionally containing a constitutional unit D that is derived from an addition polymerizable monomer other than the fluorosilsesquioxane having one addition polymerizable functional group in a molecule, the organopolysiloxane having an addition polymerizable functional group and the addition polymerizable monomer having a functional group capable of introducing a group having a polymerizable unsaturated bond.

摘要翻译： 含有：分子内具有一个加成聚合官能团的氟代倍半硅氧烷的结构单元A的聚合物; 衍生自具有可加聚官能团的有机聚硅氧烷的结构单元B; 和由可加成聚合单体衍生的具有在侧链上具有聚合性不饱和键的基团的结构单元C，并且任选地含有来自除了具有一个可加聚可聚合的氟代倍半硅氧烷之外的可加聚单体的结构单元D 分子中的官能团，具有加聚性官能团的有机聚硅氧烷和具有能够引入具有聚合性不饱和键的基团的官能团的加成聚合性单体。

公开(公告)号：US20100093951A1

公开(公告)日：2010-04-15

申请号：US12519354

申请日：2007-12-17

申请人： Hisao Oikawa ,  Koji Ohguma ,  Kenya Ito ,  Mikio Yamahiro

发明人： Hisao Oikawa ,  Koji Ohguma ,  Kenya Ito ,  Mikio Yamahiro

IPC分类号： C08L83/06 ,  C08G77/04 ,  C08G77/14

CPC分类号： C08F283/12 ,  C08F290/00 ,  C08F290/06 ,  C08F290/068 ,  C08F290/14 ,  C08F290/148 ,  C08G77/385 ,  C08G77/442 ,  C08L55/00 ,  C09D155/00 ,  C08L2666/02

摘要： A polymer containing: a constitutional unit A that is derived from fluorosilsesquioxane having one addition polymerizable functional group in a molecule; a constitutional unit B that is derived from organopolysiloxane having an addition polymerizable functional group; and a constitutional unit C that is derived from an addition polymerizable functional monomer containing a group having active hydrogen, and optionally containing a constitutional unit D that is derived from an addition polymerizable monomer other than the fluorosilsesquioxane having one addition polymerizable functional group in a molecule, the organopolysiloxane having an addition polymerizable functional group and the addition polymerizable monomer containing a group having active hydrogen.

摘要翻译： 含有：分子内具有一个加成聚合官能团的氟代倍半硅氧烷的结构单元A的聚合物; 衍生自具有可加聚官能团的有机聚硅氧烷的结构单元B; 和由含有具有活性氢的基团的加成聚合性官能单体衍生的结构单元C，并且任选地含有来自除了在分子中具有一个加成聚合官能团的氟代倍半硅氧烷以外的加聚性单体的结构单元D， 具有加聚性官能团的有机聚硅氧烷和含有具有活性氢的基团的加成聚合性单体。

公开(公告)号：US07449539B2

公开(公告)日：2008-11-11

申请号：US11545594

申请日：2006-10-11

申请人： Yoshitaka Morimoto ,  Kenichi Watanabe ,  Nobumasa Ootake ,  Jyun-ichi Inagaki ,  Kazuhiro Yoshida ,  Koji Ohguma

发明人： Yoshitaka Morimoto ,  Kenichi Watanabe ,  Nobumasa Ootake ,  Jyun-ichi Inagaki ,  Kazuhiro Yoshida ,  Koji Ohguma

IPC分类号： C07F7/21

CPC分类号： C08G77/20 ,  C07F7/21 ,  C08G77/04 ,  C08G77/045 ,  C08G77/14

摘要： The present inventors have obtained a PSQ derivative of a completely condensed type into which a functional group is readily introduced by using a novel PSQ derivative of an incompletely condensed type in which four alkaline metal atoms are bonded to silsesquioxane of a cage type having eight Si's. The above silsesquioxane derivative is represented by Formula (1). A silsesquioxane derivative to which alkaline metal atoms are bonded is represented by Formula (2). In Formula (1) and Formula (2), R is a group selected from alkyl, aryl and arylalkyl; Y is a group represented by Formula (a) or Formula (b); and M is a monovalent alkaline metal atom. X in Formula (a) and Formula (b) is hydrogen, halogen, a hydroxyl group or a monovalent organic group, and Z is —O—, —CH2— or a single bond. The preferred organic group is a functional group or a group having a functional group.

摘要翻译： 本发明人已经获得了一种完全冷凝型的PSQ衍生物，其中通过使用四种碱金属原子与具有八个Si的笼型的倍半硅氧烷结合的不完全冷凝型的新型PSQ衍生物容易地引入官能团。 上述倍半硅氧烷衍生物由式（1）表示。 碱金属原子键合的倍半硅氧烷衍生物由式（2）表示。 在式（1）和式（2）中，R是选自烷基，芳基和芳烷基的基团; Y为式（a）或式（b）所示的基团。 M为单价碱金属原子。 式（a）和式（b）中的X为氢，卤素，羟基或一价有机基团，Z为-O-，-CH 2 - 或单键。 优选的有机基团是官能团或具有官能团的基团。

公开(公告)号：US07169873B2

公开(公告)日：2007-01-30

申请号：US10490163

申请日：2002-09-17

申请人： Yoshitaka Morimoto ,  Kenichi Watanabe ,  Nobumasa Ootake ,  Jyun-ichi Inagaki ,  Kazuhiro Yoshida ,  Koji Ohguma

发明人： Yoshitaka Morimoto ,  Kenichi Watanabe ,  Nobumasa Ootake ,  Jyun-ichi Inagaki ,  Kazuhiro Yoshida ,  Koji Ohguma

IPC分类号： C07F7/21

CPC分类号： C08G77/20 ,  C07F7/21 ,  C08G77/04 ,  C08G77/045 ,  C08G77/14

摘要： The present inventors have obtained a PSQ derivative of a completely condensed type into which a functional group is readily introduced by using a novel PSQ derivative of an incompletely condensed type in which four alkaline metal atoms are bonded to silsesquioxane of a cage type having eight Si's. The above silsesquioxane derivative is represented by Formula (1). A silsesquioxane derivative to which alkaline metal atoms are bonded is represented by Formula (2). In Formula (1) and Formula (2), R is a group selected from alkyl, aryl and arylalkyl; Y is a group represented by Formula (a) or Formula (b); and M is a monovalent alkaline metal atom. X in Formula (a) and Formula (b) is hydrogen, halogen, a hydroxyl group or a monovalent organic group, and Z is —O—, —CH2— or a single bond. The preferred organic group is a functional group or a group having a functional group.

摘要翻译： 本发明人已经获得了一种完全冷凝型的PSQ衍生物，其中通过使用四种碱金属原子与具有八个Si的笼型的倍半硅氧烷结合的不完全冷凝型的新型PSQ衍生物容易地引入官能团。 上述倍半硅氧烷衍生物由式（1）表示。 碱金属原子键合的倍半硅氧烷衍生物由式（2）表示。 在式（1）和式（2）中，R是选自烷基，芳基和芳烷基的基团; Y为式（a）或式（b）所示的基团。 M为单价碱金属原子。 式（a）和式（b）中的X为氢，卤素，羟基或一价有机基团，Z为-O-，-CH 2 - 或单键。 优选的有机基团是官能团或具有官能团的基团。