公开(公告)号：US20100022791A1

公开(公告)日：2010-01-28

申请号：US12441155

申请日：2007-09-12

申请人： Jisoon Ihm ,  Hoonkyung Lee ,  Hyo Jin Jeon ,  Jong Sik Kim ,  Dong Ok Kim ,  Hee bock Yoon ,  Jeasung Park ,  Seong-Geun Oh ,  Chul Oh

发明人： Jisoon Ihm ,  Hoonkyung Lee ,  Hyo Jin Jeon ,  Jong Sik Kim ,  Dong Ok Kim ,  Hee bock Yoon ,  Jeasung Park ,  Seong-Geun Oh ,  Chul Oh

IPC分类号： C07F7/28

CPC分类号： C01B6/003 ,  C01B3/0015 ,  C07F7/003 ,  Y02E60/328

摘要： The present invention relates to an organic-transition metal complex which can safely and reversibly store hydrogen in a high capacity, and a process for preparing the same. In order to achieve the objects, the hydrogen storage material according to the invention comprises a complex generated by combination of an organic substance containing a hydroxyl (—OH) group(s) with a transition metal containing compound, which can more effectively store hydrogen with more than one transition metal being bonded per molecule. Examples of the organic substances containing hydroxyl (—OH) group(s) include alkyl derivatives such as ethylene glycol, trimethylene glycol and glycerol, and hydroxyl-containing aryl derivatives such as fluoroglucinol. As the transition metal, titanium (Ti), vanadium (V) and scandium (Sc), which can make Kubas binding, may be mentioned.

摘要翻译： 本发明涉及能够高容量地安全可逆地储存氢的有机 - 过渡金属络合物及其制备方法。 为了达到上述目的，根据本发明的储氢材料包含通过将含有羟基（-OH）基团的有机物质与含过渡金属的化合物组合产生的络合物，其可以更有效地将氢气与 每个分子键合多于一个过渡金属。 含有羟基（-OH）基团的有机物质的实例包括烷基衍生物如乙二醇，三亚甲基二醇和甘油，以及含羟基的芳基衍生物如氟葡萄糖醇。 作为过渡金属，可以提及可以使Kubas结合的钛（Ti），钒（V）和钪（Sc）。