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公开(公告)号：US10081649B2
公开(公告)日：2018-09-25
申请号：US15468920
申请日：2017-03-24
Inventor： Albert Epshteyn , Zachary J. Huba , William Maza
CPC classification number: C07F15/025 , C01B3/0015 , C01B6/23 , C01C1/08 , Y02E60/328 , Y02P20/582
Abstract: A transition metal amino borohydride material includes a first row transition metal in conjunction with an amine ligand and borohydride, in a condition of having been thermally treated to a temperature of at least 70° C. and up to but not including 800° C. An exemplary such material, Fe(DETA)(BH4)2 having been heat treated at 300° C., had good hydrogen storage characteristics.
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公开(公告)号：US09919986B2
公开(公告)日：2018-03-20
申请号：US15116007
申请日：2015-01-29
Applicant: CHIYODA CORPORATION
Inventor： Kenichi Imagawa , Hironori Kawai , Masato Shiraga , Yusuke Nakajima
CPC classification number: C07C5/10 , C01B3/0015 , C01B3/26 , C01B2203/0277 , C07C5/367 , C07C2101/12 , C07C2521/04 , C07C2521/12 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/755 , C07C2601/12 , C07C2601/14 , Y02E60/328 , Y02P20/52 , C07C13/18 , C07C15/06
Abstract: The energy is minimized that is required to lower the concentration of the high boiling point components (containing the poisoning substance for the dehydrogenation catalyst) contained in the hydrogenated aromatic compound produced by the hydrogenation of an aromatic compound. The hydrogenation system (2) for an aromatic compound comprises a hydrogenation reaction unit (11) for adding hydrogen to an aromatic compound by a hydrogenation reaction to produce a hydrogenated aromatic compound, a first separation unit (12) for separating a gas and a liquid component from a product of the hydrogenation reaction unit while maintaining a temperature of the product generally higher than a boiling point of the hydrogenated aromatic compound, and a second separation unit (13) for separating the hydrogenated aromatic compound from the gas component separated by the first separation unit.
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3.发明授权公开(公告)号：US09856282B2
公开(公告)日：2018-01-02
申请号：US15183490
申请日：2016-06-15
Applicant: Kanto Kagaku Kabushiki Kaisha
Inventor： Ryohei Yamaguchi , Ken-ichi Fujita
IPC: C07F17/02 , C07C45/00 , C07C201/12 , B01J7/02 , C07C51/16 , B01J31/22 , C01B3/06 , C01B3/32 , C01B3/00 , C01B3/22 , C07B41/06 , C07B41/08 , C07J13/00
CPC classification number: C07F17/02 , B01J7/02 , B01J31/2295 , B01J2231/763 , B01J2231/766 , B01J2531/827 , C01B3/0015 , C01B3/06 , C01B3/22 , C01B3/326 , C01B2203/02 , C01B2203/0227 , C01B2203/0277 , C01B2203/1041 , C01B2203/1064 , C01B2203/1205 , C01B2203/1211 , C01B2203/1217 , C01B2203/1223 , C01B2203/1229 , C07B41/06 , C07B41/08 , C07C45/002 , C07C51/16 , C07C201/12 , C07C2601/08 , C07C2601/14 , C07J13/007 , Y02E60/328 , Y02E60/36 , Y02P20/132 , C07C47/02 , C07C47/06 , C07C47/32 , C07C47/52 , C07C49/04 , C07C49/213 , C07C49/395 , C07C49/403
Abstract: Objects of the present invention are to provide a novel dehydrogenation reaction catalyst, to provide a method that can produce a ketone, an aldehyde, and a carboxylic acid with high efficiency from an alcohol, and to provide a method for efficiently producing hydrogen from an alcohol, formic acid, or a formate, and they are accomplished by a catalyst containing an organometallic compound of Formula (1).
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公开(公告)号：US20170318672A1
公开(公告)日：2017-11-02
申请号：US15459973
申请日：2017-03-15
Applicant: The Trustees of Princeton University
Inventor： Robert K. PRUD'HOMME , Ilhan A. Aksay
CPC classification number: H05K1/095 , B82Y30/00 , B82Y40/00 , C01B31/0423 , C01B31/043 , C01B31/0476 , C01B32/192 , C01B32/225 , C01B32/23 , C01B2204/32 , H01G4/206 , H05K3/0091 , H05K3/10 , H05K2201/0323 , Y02E60/324 , Y02E60/325 , Y02E60/328 , Y10T428/13 , Y10T428/1341 , Y10T428/1379 , Y10T428/2982
Abstract: A thermal overload device containing a polymer composite, which contains at least one polymer and a modified graphite oxide material, containing thermally exfoliated graphite oxide having a surface area of from about 300 m2/g to 2600 m2/g, and a method of making the same.
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公开(公告)号：US20170275320A1
公开(公告)日：2017-09-28
申请号：US15468920
申请日：2017-03-24
Applicant: The Government of the United States of America, as represented by the Secretary of the Navy
Inventor： Albert Epshteyn , Zachary J. Huba , William Maza
CPC classification number: C07F15/025 , C01B3/0015 , C01B6/23 , C01C1/08 , Y02E60/328 , Y02P20/582
Abstract: A transition metal amino borohydride material includes a first row transition metal in conjunction with an amine ligand and borohydride, in a condition of having been thermally treated to a temperature of at least 70° C. and up to but not including 800° C. An exemplary such material, Fe(DETA)(BH4)2 having been heat treated at 300° C., had good hydrogen storage characteristics.
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Patent Agency Ranking
公开(公告)号：US09739423B2
公开(公告)日：2017-08-22
申请号：US14737759
申请日：2015-06-12
Inventor： David Antonelli
CPC classification number: F17C11/007 , C01B3/001 , C01B3/0015 , C01B3/0031 , C01B3/0042 , C01B6/02 , C07F9/00 , C07F11/00 , C07F13/00 , H01M4/383 , H01M8/065 , Y02E60/328
Abstract: The present disclosure relates to improved processes for the preparation of metal hydrides. The present disclosure also relates to metal hydrides, e.g., metal hydrides prepared by the processes described herein, that exhibit enhanced hydrogen storage capacity when used as hydrogen storage systems.
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公开(公告)号：US20170166496A1
公开(公告)日：2017-06-15
申请号：US15116007
申请日：2015-01-29
Applicant: CHIYODA CORPORATION
Inventor： Kenichi Imagawa , Hironori Kawai , Masato Shiraga , Yusuke Nakajima
CPC classification number: C07C5/10 , C01B3/0015 , C01B3/26 , C01B2203/0277 , C07C5/367 , C07C2101/12 , C07C2521/04 , C07C2521/12 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/755 , C07C2601/12 , C07C2601/14 , Y02E60/328 , Y02P20/52 , C07C13/18 , C07C15/06
Abstract: The energy is minimized that is required to lower the concentration of the high boiling point components (containing the poisoning substance for the dehydrogenation catalyst) contained in the hydrogenated aromatic compound produced by the hydrogenation of an aromatic compound. The hydrogenation system (2) for an aromatic compound comprises a hydrogenation reaction unit (11) for adding hydrogen to an aromatic compound by a hydrogenation reaction to produce a hydrogenated aromatic compound, a first separation unit (12) for separating a gas and a liquid component from a product of the hydrogenation reaction unit while maintaining a temperature of the product generally higher than a boiling point of the hydrogenated aromatic compound, and a second separation unit (13) for separating the hydrogenated aromatic compound from the gas component separated by the first separation unit.
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公开(公告)号：US20150362129A1
公开(公告)日：2015-12-17
申请号：US14737759
申请日：2015-06-12
Inventor： David ANTONELLI
CPC classification number: F17C11/007 , C01B3/001 , C01B3/0015 , C01B3/0031 , C01B3/0042 , C01B6/02 , C07F9/00 , C07F11/00 , C07F13/00 , H01M4/383 , H01M8/065 , Y02E60/328
Abstract: The present disclosure relates to improved processes for the preparation of metal hydrides. The present disclosure also relates to metal hydrides, e.g., metal hydrides prepared by the processes described herein, that exhibit enhanced hydrogen storage capacity when used as hydrogen storage systems.
Abstract translation: 本公开涉及用于制备金属氢化物的改进方法。 本公开还涉及金属氢化物，例如通过本文所述方法制备的金属氢化物，其在用作氢存储系统时表现出增强的储氢能力。
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公开(公告)号：US20150307363A1
公开(公告)日：2015-10-29
申请号：US14649092
申请日：2013-11-27
Applicant: Min-Zae OH , Jens HAUBROCK , Thorsten SCHWAERTZKE , Imad MOUSSALLEM , Martin TROCHA
Inventor： Min-Zae OH , Jens HAUBROCK , Thorsten SCHWAERTZKE , Imad MOUSSALLEM , Martin TROCHA
IPC: C01B33/04
CPC classification number: C01B33/04 , C01B3/0015 , C01B6/006 , C01B33/107 , Y02E60/328
Abstract: The present invention relates to a continuous process for hydrogenating halogen-containing silane compounds having at least three silicon atoms, in which at least one halogen-containing silane compound having at least three silicon atoms and at least one hydrogenating agent are converted continuously to form at least one hydridosilane compound having at least 3 silicon atoms and oxidized hydrogenating agent, and wherein oxidized hydrogenating agent is withdrawn and reduced, and the reaction product of this reduction reaction is sent back to the hydrogenation, to the hydridosilane compounds obtainable by this process and to the use thereof.
Abstract translation: 本发明涉及一种用于氢化含有至少三个硅原子的含卤素的硅烷化合物的连续方法，其中至少一种具有至少三个硅原子的含卤素的硅烷化合物和至少一种氢化剂被连续地转化成 至少一个具有至少3个硅原子的氢硅烷化合物和氧化的氢化剂，并且其中将氧化的氢化剂排出并还原，并将该还原反应的反应产物送回氢化，得到可通过该方法获得的氢硅烷化合物， 其使用。
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10.发明申请DEHYDROGENATION CATALYST, AND CARBONYL COMPOUND AND HYDROGEN PRODUCTION METHOD USING SAID CATALYST 有权脱氢催化剂和碳化合物和使用催化剂的氢生产方法公开(公告)号：US20150086473A1
公开(公告)日：2015-03-26
申请号：US14380088
申请日：2013-02-22
Applicant: Kanto Kagaku Kabushiki Kaisha
Inventor： Ryohei Yamaguchi , Ken-ichi Fujita
CPC classification number: C07F17/02 , B01J7/02 , B01J31/2295 , B01J2231/763 , B01J2231/766 , B01J2531/827 , C01B3/0015 , C01B3/06 , C01B3/22 , C01B3/326 , C01B2203/02 , C01B2203/0227 , C01B2203/0277 , C01B2203/1041 , C01B2203/1064 , C01B2203/1205 , C01B2203/1211 , C01B2203/1217 , C01B2203/1223 , C01B2203/1229 , C07B41/06 , C07B41/08 , C07C45/002 , C07C51/16 , C07C201/12 , C07C2601/08 , C07C2601/14 , C07J13/007 , Y02E60/328 , Y02E60/36 , Y02P20/132 , C07C47/02 , C07C47/06 , C07C47/32 , C07C47/52 , C07C49/04 , C07C49/213 , C07C49/395 , C07C49/403
Abstract: Objects of the present invention are to provide a novel dehydrogenation reaction catalyst, to provide a method that can produce a ketone, an aldehyde, and a carboxylic acid with high efficiency from an alcohol, and to provide a method for efficiently producing hydrogen from an alcohol, formic acid, or a formate, and they are accomplished by a catalyst containing an organometallic compound of Formula (1).
Abstract translation: 本发明的目的是提供一种新颖的脱氢反应催化剂，以提供一种能够从醇高效地生产酮，醛和羧酸的方法，并提供一种从醇中高效生产氢的方法 ，甲酸或甲酸酯，并且它们通过含有式（1）的有机金属化合物的催化剂完成。
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