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公开(公告)号:US08376149B2
公开(公告)日:2013-02-19
申请号:US12094580
申请日:2006-11-21
申请人: Jean-Yves Sanchez , Crístina Iojoiu , Régis Mercier , Nadia El Kissi , France Chabert , Jérèmie Salomon
发明人: Jean-Yves Sanchez , Crístina Iojoiu , Régis Mercier , Nadia El Kissi , France Chabert , Jérèmie Salomon
CPC分类号: H01G9/038 , B01D67/0006 , B01D2323/38 , B01D2323/42 , B01D2325/14 , B01J39/19 , B01J47/12 , C08J3/246 , C08J7/12 , H01G11/56 , H01M10/052 , H01M10/0565 , Y02E60/13
摘要: The invention relates to the preparation of a crosslinked polymeric film bearing ionic groupings.The process consists in extruding a material comprising at least one prepolymer, in polymerizing said material after extrusion, and in subjecting the extruded material to a chemical reaction for grafting ionic groupings. The prepolymer comprises repeating units each comprising at least one aromatic group GA and at least one functional group GF; it bears at least one group GP which is polymerizable thermally at a temperature greater than the extrusion temperature, or photochemically, and also at least one reactive group GR which allows the grafting of ionic groupings.The films are useful as a membrane for fuel cells or electrodialysis, as an electrolyte of a lithium battery, of a supercapacitor or of an electrochromic device, or as an ion exchange membrane.
摘要翻译: 本发明涉及具有离子基团的交联聚合物膜的制备。 该方法包括挤出包含至少一种预聚物的材料,在挤出后使所述材料聚合,以及使挤出的材料经受用于接枝离子组的化学反应。 预聚物包含各自包含至少一个芳族基团GA和至少一个官能团GF的重复单元; 它具有至少一个在大于挤出温度的温度下热可聚合的GP组,或光化学上还有至少一个允许离子组接枝的反应性基团GR。 这些膜可用作燃料电池或电渗析的膜,作为锂电池的电解质,超级电容器或电致变色器件,或作为离子交换膜。