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1.发明申请Process for Separating at Least One Actinide Element From Lanthanide Elements in an Aqueous Medium by Sequestration and Membrane Filtration 失效通过封存和膜过滤在水介质中从镧系元素分离至少一种锕系元素的方法公开(公告)号：US20090026138A1
公开(公告)日：2009-01-29
申请号：US12162501
申请日：2007-01-30
Applicant: Gilles Bernier , Jean-Marc Adnet , Alain Favre-Reguillon , Jacques Foos , Gerard Le Buzit , Marc Lemaire , Stephane Pellet-Rostaing , Antoine Sorin
Inventor： Gilles Bernier , Jean-Marc Adnet , Alain Favre-Reguillon , Jacques Foos , Gerard Le Buzit , Marc Lemaire , Stephane Pellet-Rostaing , Antoine Sorin
CPC classification number: C22B59/00 , B01D61/027 , B01D61/145 , B01D2315/14 , C22B3/205 , G21F9/06 , Y02P10/234
Abstract: The invention relates to a process for separating, in an aqueous medium, at least one actinide element from one or more lanthanide elements by using at least one molecule which sequesters the said actinide element to be separated and membrane filtration, the said process successively comprising: a) a step of bringing at least one molecule which sequesters the said actinide element in contact with the aqueous medium, the said molecule not being retained in the non-complexed state by the said membrane and being capable of forming a complex with the actinide element to be separated, comprising the said element and at least two of the said sequestering molecules, which complex is capable of being retained by the membrane; b) a step of passing the aqueous medium over the membrane in order to form a permeate on one side, comprising an aqueous effluent depleted of the said actinide element, and a retentate comprising the said complex.
Abstract translation: 本发明涉及通过使用至少一种螯合所述待分离的锕系元素和膜过滤的分子在水性介质中从至少一种镧系元素分离至少一种锕系元素的方法，所述方法依次包括： a）使至少一个螯合所述锕系元素与水介质接触的分子的步骤，所述分子不被所述膜保持在非络合状态，并且能够与锕系元素形成络合物 被分离，其包含所述元素和至少两个所述螯合分子，所述复合物能够被膜保留; b）使含水介质通过膜以在一侧上形成渗透物的步骤，其包含贫化所述锕系元素的水性流出物和包含所述络合物的渗余物。
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2.发明授权
公开(公告)号：US5344624A
公开(公告)日：1994-09-06
申请号：US935038
申请日：1992-08-25
Applicant: Jacques Foos , Marc Lemaire , Alain Guy , Vincent Guyon , Rodolphe Chomel , Andre Delo Ge , Pierre Doutreluigne , Henri Le Roy
Inventor： Jacques Foos , Marc Lemaire , Alain Guy , Vincent Guyon , Rodolphe Chomel , Andre Delo Ge , Pierre Doutreluigne , Henri Le Roy
CPC classification number: G21C19/46 , G21F9/06 , Y02W30/883
Abstract: The invention concerns the recovery of Pu (IV) by using crown compounds.According to the invention, the aqueous solution containing the plutonium (IV) is placed in contact with at least one crown compound, for example DCH 18C6, dissolved in an organic diluting agent, such as benzonitrile. In the case where the solution only contains traces of Pu, it is possible to use a crown compound secured to a solid phase, such as silica.The aqueous solution is a concentrated solution of fission products, an effluent originating from an irradiated nuclear fuel reprocessing installation or a concentrated solution of plutonium with americium.
Abstract translation: 本发明涉及通过使用冠状化合物回收Pu（IV）。 根据本发明，含有钚（IV）的水溶液与至少一种溶解在有机稀释剂如苄腈中的冠状化合物（例如DCH 18C6）接触。 在溶液仅含有痕量Pu的情况下，可以使用固定在固相上的冠状化合物，例如二氧化硅。 水溶液是裂变产物的浓缩溶液，源自辐照的核燃料后处理装置的流出液或钚与钚的浓缩溶液。
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3.发明授权
公开(公告)号：US5925254A
公开(公告)日：1999-07-20
申请号：US614828
申请日：1996-03-08
Applicant: Marc Lemaire , Jacques Foos , Alain Guy , Eric Gaubert , Colette Bardot , Rodolph Chomel , Jean-Jacques Radecky , Alain Maurel , Henri Barnier
Inventor： Marc Lemaire , Jacques Foos , Alain Guy , Eric Gaubert , Colette Bardot , Rodolph Chomel , Jean-Jacques Radecky , Alain Maurel , Henri Barnier
IPC: B01D61/44 , B01D69/10 , B01D69/12 , B01D71/12 , B01D71/34 , B01D71/56 , B01D71/62 , B01D71/68 , G21F9/06 , G21F9/12 , B01D61/00
Abstract: The invention relates to a process for separating sodium from aqueous effluents resulting from the reprocessing of spent nuclear fuel elements. According to the invention, the effluent (3) is introduced into a tangential filtration module (11), whose membranes are made from polyaramide, sulphonated polysulphone or perfluorinated ionomer, so as to collect a permeate P containing sodium, depleted in radioactive elements and a retentate R enriched in radioactive elements.
Abstract translation: 本发明涉及从废核燃料元件的后处理产生的含水废水中分离钠的方法。 根据本发明，将流出物（3）引入切向过滤组件（11）中，其中膜由聚芳酰胺，磺化聚砜或全氟离子交联聚合物制成，以收集含有钠的渗透物P，其耗尽放射性元素和 滞留R富集放射性元素。
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4.发明授权Method for recovering with the aid of a crown compound plutonium (IV) present in solutions, such as aqueous effluents, concentrated solutions of fission products and concentrated solutions of plutonium 失效在解决方案中，如解决方案中提供的化合物四氢呋喃（IV）的补充方法，如水溶液，离子产物的浓缩溶液和浓缩溶液的解决方案
公开(公告)号：US5183645A
公开(公告)日：1993-02-02
申请号：US625550
申请日：1990-12-11
Applicant: Jacques Foos , Marc Lemaire , Alain Guy , Vincent Guyon , Rodolphe Chomel , Andre Deloge , Pierre Doutreluigne , Henri Le Roy
Inventor： Jacques Foos , Marc Lemaire , Alain Guy , Vincent Guyon , Rodolphe Chomel , Andre Deloge , Pierre Doutreluigne , Henri Le Roy
CPC classification number: G21C19/46 , G21F9/06 , Y02W30/883
Abstract: The invention concerns the recovery of Pu (IV) by using crown compounds.According to the invention, the aqueous solution containing the plutonium (IV) is placed in contact with at least one crown compound, for example DCH 18C6, dissolved in an organic diluting agent, such as benzonitrile. In the case where the solution only contains traces of Pu, it is possible to use a crown compound secured to a solid phase, such as silica.The aqueous solution is a concentrated solution of fission products, an effluent originating from an irradiated nuclear fuel reprocessing installation or a concentrated solution of plutonium with americium.
Abstract translation: 本发明涉及通过使用冠状化合物回收Pu（IV）。 根据本发明，含有钚（IV）的水溶液与至少一种溶解在有机稀释剂如苄腈中的冠状化合物（例如DCH 18C6）接触。 在溶液仅含有痕量Pu的情况下，可以使用固定在固相上的冠状化合物，例如二氧化硅。 水溶液是裂变产物的浓缩溶液，源自辐照的核燃料后处理装置的流出液或钚与钚的浓缩溶液。
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5.发明授权Process for separating at least one actinide element from lanthanide elements in an aqueous medium by sequestration and membrane filtration 失效通过封存和膜过滤在水性介质中从镧系元素分离至少一种锕系元素的方法公开(公告)号：US08048308B2
公开(公告)日：2011-11-01
申请号：US12162501
申请日：2007-01-30
Applicant: Gilles Bernier , Jean-Marc Adnet , Alain Favre-Reguillon , Gérard Le Buzit , Marc Lemaire , Stéphane Pellet-Rostaing , Antoine Sorin , Jacques Foos
Inventor： Gilles Bernier , Jean-Marc Adnet , Alain Favre-Reguillon , Gérard Le Buzit , Marc Lemaire , Stéphane Pellet-Rostaing , Antoine Sorin , Jacques Foos
CPC classification number: C22B59/00 , B01D61/027 , B01D61/145 , B01D2315/14 , C22B3/205 , G21F9/06 , Y02P10/234
Abstract: The invention relates to a process for separating, in an aqueous medium, at least one actinide element from one or more lanthanide elements by using at least one molecule which sequesters the said actinide element to be separated and membrane filtration, the said process successively comprising: a) a step of bringing at least one molecule which sequesters the said actinide element in contact with the aqueous medium, the said molecule not being retained in the non-complexed state by the said membrane and being capable of forming a complex with the actinide element to be separated, comprising the said element and at least two of the said sequestering molecules, which complex is capable of being retained by the membrane; b) a step of passing the aqueous medium over the membrane in order to form a permeate on one side, comprising an aqueous effluent depleted of the said actinide element, and a retentate comprising the said complex.
Abstract translation: 本发明涉及通过使用至少一种螯合所述待分离的锕系元素和膜过滤的分子在水性介质中从至少一种镧系元素分离至少一种锕系元素的方法，所述方法依次包括： a）使至少一个螯合所述锕系元素与水介质接触的分子的步骤，所述分子不被所述膜保持在非络合状态，并且能够与锕系元素形成络合物 被分离，其包含所述元素和至少两个所述螯合分子，所述复合物能够被膜保留; b）使含水介质通过膜以在一侧上形成渗透物的步骤，其包含贫化所述锕系元素的水性流出物和包含所述络合物的渗余物。
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Patent Agency Ranking
公开(公告)号：US20080073272A1
公开(公告)日：2008-03-27
申请号：US11986402
申请日：2007-11-21
Applicant: Marc Lemaire , Jacques Foos , Alain Guy , Frederic Chitry , Stephane Pellet-Rostaing , Olivier Vigneau
Inventor： Marc Lemaire , Jacques Foos , Alain Guy , Frederic Chitry , Stephane Pellet-Rostaing , Olivier Vigneau
IPC: B01D11/00
CPC classification number: B01J45/00 , B01D59/22 , B01D59/30 , C07C237/04 , Y10S423/07
Abstract: A process in which isotopes of the same element belonging to the alkaline earth metals, transition elements and heavy metals having an atomic mass of less than 209, in particular lanthanide metals, are separated in an aqueous medium by treating an aqueous medium.
Abstract translation: 通过处理水性介质，在水性介质中分离属于碱土金属，过渡元素和原子质量小于209的重金属，特别是镧系元素的同质元素的同位素。
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7.发明授权
公开(公告)号：US5028402A
公开(公告)日：1991-07-02
申请号：US367487
申请日：1989-06-16
Applicant: Jacques Foos , Pierre Epherre , Alain Guy , Marc Lemaire , Rodolph Chomel , Gerard Cauquil , Pierre Patigny , Alain Vian
Inventor： Jacques Foos , Pierre Epherre , Alain Guy , Marc Lemaire , Rodolph Chomel , Gerard Cauquil , Pierre Patigny , Alain Vian
CPC classification number: G21F9/04
Abstract: Process for separating plutonium from uranium contained in a nitric acid aqueous solution from the reprocessing of irradiated fuels comprising plutonium, uranium and fission products by means of crown ethers. Nitric acid aqueous solution (5) containing plutonium, uranium and fission products is contacted at (2) with an organic liquid membrane (3) containing a crown ether. The uranium and plutonium are extracted in the liquid membrane (3) and then transferred by said membrane into a receiving solution (7), which becomes enriched with uranium, because the latter is transferred more rapidly than the plutonium. The crown ether can be DCH 18 C6 or DB 18 C6.
Abstract translation: 从含有钚，铀和裂变产物的经辐照燃料后处理的硝酸水溶液中分离钚与铀的方法。 含有钚，铀和裂变产物的硝酸水溶液（5）在（2）与含有冠醚的有机液体膜（3）接触。 铀和钚在液膜（3）中提取，然后由所述膜转移到富集铀的接收溶液（7）中，因为后者比钚转移得更快。 冠醚可以是DCH 18 C6或DB18 C6。
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公开(公告)号：US07318899B2
公开(公告)日：2008-01-15
申请号：US10250833
申请日：2001-01-05
Applicant: Marc Lemaire , Jacques Foos , Alain Guy , Frédéric Chitry , Stéphane Pellet-Rostaing , Olivier Vigneau
Inventor： Marc Lemaire , Jacques Foos , Alain Guy , Frédéric Chitry , Stéphane Pellet-Rostaing , Olivier Vigneau
CPC classification number: B01J45/00 , B01D59/22 , B01D59/30 , C07C237/04 , Y10S423/07
Abstract: A process in which isotopes of the same element belonging to the alkaline earth metals, transition elements and heavy metals having an atomic mass of less than 209, in particular lanthanide metals, are separated in an aqueous medium by treating an aqueous medium.
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9.发明授权Method for separating in an aqueous medium lanthanides and/or actinides by combined complexing-nanofiltration, and novel complexing agents therefor 失效通过组合络合纳滤法在水性介质中分离镧系元素和/或锕系元素的方法及其新型络合剂公开(公告)号：US06843917B1
公开(公告)日：2005-01-18
申请号：US09926620
申请日：2000-05-29
Applicant: Alain Guy , Jacques Foos , Marc Lemaire , Frederic Chitry , Stephane Pellet-Rostaing , Christel Gozzi
Inventor： Alain Guy , Jacques Foos , Marc Lemaire , Frederic Chitry , Stephane Pellet-Rostaing , Christel Gozzi
IPC: B01D61/04 , B01D61/16 , C22B3/00 , C22B3/22 , C22B3/28 , C22B7/00 , C22B59/00 , G21F9/10 , B01D11/00
CPC classification number: C22B3/22 , B01D61/025 , B01D61/027 , B01D61/04 , B01D61/145 , B01D61/147 , B01D61/16 , B01D2311/04 , C22B3/0012 , C22B59/00 , G21F9/10 , Y02P10/234 , B01D2311/12
Abstract: The invention relates to the separation of lanthanides and actinides by nanofiltration complexation. The object of the invention is to satisfy the existing need for a simple, efficient and economical technique for separating lanthanides and actinides. This object is achieved by a process consisting of using ligands of the polyamino acid type, such as EDTA or DTPA, for complexing lanthanides and/or actinides before separating them by nanofiltration. The invention further relates to novel polyamino acid ligands incorporating ligand structures additional to EDTA and DTPA. Application to the production of rare earths or nuclear waste processing, especially to recycling operations carried out on spent nuclear fuels is also discussed.
Abstract translation: 本发明涉及通过纳滤络合分离镧系元素和锕系元素。 本发明的目的是满足现有对用于分离镧系元素和锕系元素的简单，有效和经济的技术的需要。 该目的通过使用聚氨基酸类型的配体如EDTA或DTPA组成的方法来实现，所述方法用于在通过纳滤分离之前络合镧系元素和/或锕系元素。 本发明还涉及掺入EDTA和DTPA附加的配体结构的新型聚氨基酸配体。 还讨论了生产稀土或核废料处理，特别是对废核燃料进行回收利用的应用。
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10.发明授权Process for trapping gaseous ruthenium on polyvinyl pyridine, more particularly usable for recovering radioactive ruthenium from irradiated nuclear fuels 失效用于将气态钌捕获在聚乙烯基吡啶上的方法，更特别可用于从辐照的核燃料中回收放射性钌
公开(公告)号：US5417942A
公开(公告)日：1995-05-23
申请号：US24933
申请日：1993-03-02
Applicant: Jacques Foos , Marc Lemaire , Alain Guy , Micheline Draye , Rodolph Chomel , Andre Deloge , Pierre Doutreluingne
Inventor： Jacques Foos , Marc Lemaire , Alain Guy , Micheline Draye , Rodolph Chomel , Andre Deloge , Pierre Doutreluingne
CPC classification number: C22B61/00 , C22B11/02 , G21C19/48 , Y02W30/884
Abstract: The invention relates to a process fop trapping gaseous ruthenium on polyvinyl pyridine, more particularly usable for recovering radioactive ruthenium from irradiated nuclear fuels.This process consists of contacting a gas containing ruthenium in gaseous form with an adsorbent (11b) constituted by a vinyl pyridine polymer or copolymer for fixing the ruthenium to the latter. The gas can be constituted by yapours from a concentrate of fission products containing ruthenium, which has been heated (at 31) in the presence of an oxidizing agent for volatilizing the ruthenium.
Abstract translation: 本发明涉及一种将气态钌捕获在聚乙烯吡啶上的方法，更特别可用于从辐照的核燃料中回收放射性钌。 该方法包括将含有气态钌气体与由乙烯基吡啶聚合物或共聚物构成的吸附剂（11b）接触，用于将钌固定在其上。 气体可以由来自含有钌的裂变产物的浓缩物的酸组成，其在用于挥发钌的氧化剂的存在下已被加热（31℃）。
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