Abstract:
A process is described for producing gasoline from a paraffinic hydrocarbon feed wherein the feed is catalytically cracked and then reformed. In the process a novel porous hydrocracking catalyst composite is employed. This catalyst comprises a silica-alumina cracking base component and a noble metal hydrogenation component. It is stabilized as a result of a unique method used for introducing the noble metal in the form of a highly dispersed gravimetric precipitate into a gelatinous silica-alumina cogel precursor of the cracking base component. An organic gravimetric reagent is used for the precipitation. The resulting crackate is reformed by ordinary methods.
Abstract:
A process is described for producing gasoline from a paraffinic hydrocarbon feed wherein the feed is catalytically cracked and then reformed. In the process a novel porous hydrocracking catalyst composite is employed. This catalyst comprises a silica-alumina cracking base component and a noble metal hydrogenation component. It is stabilized as a result of a unique method used for introducing the noble metal in the form of a highly dispersed gravimetric precipitate into a gelatinous silica-alumina cogel precursor of the cracking base component. An organic gravimetric reagent is used for the precipitation. The resulting crackate is reformed by ordinary methods.
Abstract:
This invention is concerned with catalysts, particularly those useful for hydroconversion, preferably hydrocracking, a process for using the catalysts, and a method for manufacturing the catalysts, which comprises:A. forming a mixture comprising an aqueous gelatinous precipitate containing in intimate admixture a first component, said precipitate comprising an inorganic oxide or precursor thereof;B. forming a catalyst precursor comprising at least one organic-metal-compound precipitate and said gelatinous precipitate by reacting said first component with a second component, said reaction being effected by intimately intermixing said mixture with said second component, said components belonging to different groups, and being selected from the following groups:A. a first group consisting of water soluble transition metal series compounds; andB. a second group consisting of water soluble organic gravimetric reagents for said transition series compounds;C. converting said catalyst precursor to a catalyst, said converting comprising at least a step of maintaining said precursor at a temperature in the range from about 500.degree.F to 1800.degree.F for a period in the range from about 1 to 48 hours.The preferred catalyst comprises a noble metal, preferably palladium on a silica-alumina support, particularly useful for hydrocracking processes.
Abstract:
This invention is concerned with a hydrocarbon hydrocracking process using a catalyst prepared by:A. forming an intimate mixture of a gelatinous silica-alumina precipitate and an organic-metal compound obtained by interaction of a transition series metal compound with an organic gravimetric reagent therefore; andB. converting said mixture to said catalyst by at least a step of heating the mixture at a temperature in the range of 500.degree. to 1800.degree. F for a period in the range 1 to 48 hours, said catalyst being porous and having a surface area in the range 50 to 700 m.sup.2 /g.
Abstract:
A hydrocarbon hydroconversion catalyst comprising an alumina-silica-magnesia matrix containing a hydrogenation component, and a crystalline zeolitic molecular sieve substantially free of hydrogenation components, said catalyst having a specific gravity less than about 1.8, preferably 1.1 to 1.8.
Abstract:
A method for removing sulfur from liquid compositions containing aliphatic or cylic organic sulfur-containing compounds, e.g., dibenzothiophene includes activating the sulfur-containing compound by oxidizing either the organic sulfur or adjacent carbon atoms in the presence of a suitable active biocatalyst (ie., microorganism, enzyme, etc.) followed by treating of the activated compound by techniques such as fluidized catalytic cracking so as to remove the sulfur therefrom.
Abstract:
A process is disclosed for reducing the impact of basic compounds, such as nitrogen, on hydrocarbonaceous feed intended for catalytic cracking. In a preferred embodiment, a portion of the regenerated catalyst of a catalytic cracking process is separated and contacted with the hydrocarbonaceous feed at a temperature and for a time sufficient to strongly bind the basic contaminants in the feed with the separated portion of the acid catalyst. The feed is then passed to the catalytic cracking reactor in a slurry with the separated catalyst, resulting in a desirable conversion increase.