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公开(公告)号:US20070092421A1
公开(公告)日:2007-04-26
申请号:US11242655
申请日:2005-10-04
申请人: Dan Hancu , Jonathan Male , Jennifer Redline , Stanlee Buddle , Teresa Rocha , Alison Palmatier , Benjamin Wood , Job Rijssenbeek
发明人: Dan Hancu , Jonathan Male , Jennifer Redline , Stanlee Buddle , Teresa Rocha , Alison Palmatier , Benjamin Wood , Job Rijssenbeek
IPC分类号: B01D53/56
CPC分类号: B01D53/8628 , B01D53/9477 , B01J23/10 , B01J23/34 , B01J23/62 , B01J23/83 , B01J23/888 , B01J23/8892 , B01J35/0006
摘要: Disclosed is a catalyst system for the reduction of NOx. The catalyst system comprises a catalyst in a first zone comprising a catalyst support, a catalytic metal comprising gallium, and at least one promoting metal selected from the group consisting of silver, gold, vanadium, zinc, tin, bismuth, cobalt, molybdenum, tungsten, indium and mixtures thereof; a catalyst in the second zone following the first zone; the catalyst comprising a second catalyst support, a second catalytic metal selected from the group consisting of indium, copper, manganese, tungsten, molybdenum, titanium, vanadium, iron, cerium and mixtures thereof. The catalyst system further comprises a gas stream comprising an organic reductant comprising oxygen or nitrogen. The catalyst system may further optionally comprise a catalyst in a third zone following the second zone; the catalyst comprising a third catalyst support and a third catalytic metal selected from the group consisting of platinum, palladium, and mixtures thereof. A method for reducing NOx utilizing the catalyst system is also provided.
摘要翻译: 公开了一种用于还原NO x的催化剂体系。 催化剂体系包括在包含催化剂载体,包含镓的催化金属和至少一种选自银,金,钒,锌,锡,铋,钴,钼,钨的促进金属的第一区中的催化剂 ,铟及其混合物; 在第一区之后的第二区中的催化剂; 所述催化剂包含第二催化剂载体,选自铟,铜,锰,钨,钼,钛,钒,铁,铈及其混合物的第二催化金属。 催化剂体系还包括含有包含氧或氮的有机还原剂的气流。 催化剂体系还可以任选地包括在第二区之后的第三区中的催化剂; 所述催化剂包含第三催化剂载体和选自铂,钯及其混合物的第三催化金属。 还提供了利用催化剂体系还原NO x的方法。
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公开(公告)号:US20050137083A1
公开(公告)日:2005-06-23
申请号:US10743646
申请日:2003-12-22
申请人: Teresa Rocha , Jonathan Male , Jennifer Redline , Alison Palmatier , Kaidong Chen , Dan Hancu , Grigorii Soloveichik , Eric Budesheim , Aaron Simon
发明人: Teresa Rocha , Jonathan Male , Jennifer Redline , Alison Palmatier , Kaidong Chen , Dan Hancu , Grigorii Soloveichik , Eric Budesheim , Aaron Simon
CPC分类号: B01J23/66 , B01D53/8628 , B01D2255/20 , B01J23/08 , B01J23/24 , B01J23/825 , B01J23/835
摘要: A catalyst system comprising a catalyst and a reductant is disclosed. The catalyst comprises a metal oxide catalyst support, a catalytic metal oxide, and a promoting metal. The catalytic metal oxide comprises gallium oxide, indium oxide or a combination of the two. The promoting metal comprises at least one of silver, cobalt, vanadium, molybdenum, tungsten, zinc, tin and bismuth. The catalyst comprises about 5 to about 31 mol % catalytic metal oxide and about 0.5 to about 9 mol % promoting metal. The reductant comprises a fluid hydrocarbon having at least 4 carbon atoms. Also disclosed is a process for reducing NOx to N2 using the disclosed catalyst system by mixing NOx with a reductant and passing the mixture through a catalyst of the disclosed catalyst system.
摘要翻译: 公开了一种包含催化剂和还原剂的催化剂体系。 催化剂包括金属氧化物催化剂载体,催化金属氧化物和促进金属。 催化金属氧化物包括氧化镓,氧化铟或两者的组合。 促进金属包括银,钴,钒,钼,钨,锌,锡和铋中的至少一种。 催化剂包含约5至约31摩尔%的催化金属氧化物和约0.5至约9摩尔%的促进金属。 还原剂包括具有至少4个碳原子的流体烃。 还公开了使用公开的催化剂体系通过将NO x x与还原剂混合并使混合物通过的方法将NO 2 x 2还原为N 2 所公开的催化剂体系的催化剂。
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公开(公告)号:US20060133977A1
公开(公告)日:2006-06-22
申请号:US11022901
申请日:2004-12-22
申请人: Jonathan Male , Grigorii Soloveichik , Alison Palmatier , Teresa Rocha , Dan Hancu , Gregory Warner , Jennifer Redline , Eric Budesheim , Kaidong Chen , Stanlee Buddle
发明人: Jonathan Male , Grigorii Soloveichik , Alison Palmatier , Teresa Rocha , Dan Hancu , Gregory Warner , Jennifer Redline , Eric Budesheim , Kaidong Chen , Stanlee Buddle
IPC分类号: B01D53/56
摘要: A catalyst system for the reduction of NOx comprises a catalyst comprising a metal oxide catalyst support, a catalytic metal oxide comprising at least one of gallium oxide or silver oxide, and at least one promoting metal selected from the group consisting of silver, cobalt, molybdenum, tungsten, indium and mixtures thereof. The catalyst system further comprises a gas stream comprising an organic reductant comprising oxygen. A method for reducing NOx utilizing the said catalyst system is also provided.
摘要翻译: 用于还原NO x的催化剂体系包括催化剂,其包含金属氧化物催化剂载体,包含氧化镓或氧化银中的至少一种的催化金属氧化物和至少一种选自 由银,钴,钼,钨,铟组成的组及其混合物。 催化剂体系还包括含有包含氧的有机还原剂的气流。 还提供了利用所述催化剂体系减少NO x的方法。
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公开(公告)号:US20060133976A1
公开(公告)日:2006-06-22
申请号:US11022897
申请日:2004-12-22
申请人: Jonathan Male , Grigorii Soloveichik , Alison Palmatier , Dan Hancu , Gregory Warner , Jennifer Redline , Eric Budesheim , Teresa Rocha
发明人: Jonathan Male , Grigorii Soloveichik , Alison Palmatier , Dan Hancu , Gregory Warner , Jennifer Redline , Eric Budesheim , Teresa Rocha
IPC分类号: B01D53/56 , B01J27/02 , B01J27/047 , B01D53/86 , B01J23/50
CPC分类号: B01J23/30 , B01D53/8628 , B01J21/04 , B01J23/08 , B01J23/28 , B01J23/66 , B01J23/681 , B01J23/686 , B01J23/896 , B01J37/16 , B01J37/20 , Y02C20/10
摘要: A catalyst system for the reduction of NOx comprises a catalyst comprising a metal oxide catalyst support, a catalytic metal oxide comprising at least one of gallium oxide or silver oxide, and at least one promoting metal selected from the group consisting of silver, cobalt, molybdenum, tungsten, indium, bismuth and mixtures thereof. The catalyst system further comprises a gas stream comprising an organic reductant, and a compound comprising sulfur. A method for reducing NOx utilizing the said catalyst system is also provided.
摘要翻译: 用于还原NO x的催化剂体系包括催化剂,其包含金属氧化物催化剂载体,包含氧化镓或氧化银中的至少一种的催化金属氧化物和至少一种选自 由银,钴,钼,钨,铟,铋及其混合物组成的组。 催化剂体系还包括含有机还原剂的气流和包含硫的化合物。 还提供了利用所述催化剂体系减少NO x的方法。
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