公开(公告)号：US4192726A

公开(公告)日：1980-03-11

申请号：US957893

申请日：1978-11-06

Applicant: Jon B. Pangborn ,  James R. Dafler

Inventor： Jon B. Pangborn ,  James R. Dafler

IPC: C01B13/02 ,  C25B1/02 ,  C25B1/04 ,  C25B1/12

CPC classification number: C25B1/02 ,  C01B13/0207 ,  Y02P20/134

Abstract: A thermoelectrochemical process for production of hydrogen and oxygen from water providing a closed cycle reactant regenerative process wherein the primary energy input is thermal and a smaller electrical energy input is required for an electrolysis step. The process is a hybrid copper oxide-copper sulfate water splitting cycle.

Abstract translation: 一种用于从水提供氢和氧的热电化学方法，提供封闭循环反应物再生过程，其中一次能量输入是热的，并且电解步骤需要较小的电能输入。 该方法是一种杂化氧化铜 - 硫酸铜水分解循环。

公开(公告)号：US3998942A

公开(公告)日：1976-12-21

申请号：US536014

申请日：1974-12-23

Applicant: Jon B. Pangborn ,  John C. Sharer ,  Robert H. Elkins

Inventor： Jon B. Pangborn ,  John C. Sharer ,  Robert H. Elkins

IPC: C01B3/06 ,  C01B3/10 ,  C01B1/02 ,  C01B1/05 ,  C01B7/08 ,  C01B13/00

CPC classification number: C01B3/068 ,  C01B3/105 ,  Y02E60/36

Abstract: A process for the production of hydrogen and oxygen from water comprising the steps of forming ferric chloride from ferriferrous oxide by reaction with a chloride ion yielding substance, reducing the ferric chloride produced with a reducing agent to produce ferrous chloride, thermally reducing the ferric chloride to produce ferrous chloride, then oxidizing either the ferrous compound or metallic iron with water so as to produce hydrogen. The metallic iron may be formed by reducing the ferrous compound with hydrogen. Four specific reactant regenerative closed cycle systems are disclosed utilizing the process of this invention for the production of hydrogen with high energy efficiencies.

Abstract translation: 一种从水中生产氢和氧的方法，包括通过与产生氯离子的物质反应从氧化亚铁形成氯化铁的步骤，还原用还原剂生产的氯化铁以制备氯化亚铁，将氯化铁热还原成 产生氯化亚铁，然后用水氧化亚铁化合物或金属铁，以产生氢。 金属铁可以通过用氢还原亚铁化合物来形成。 利用本发明的方法公开了以高能量生产氢气的四种具体的反应物再生闭环系统。

公开(公告)号：US4332650A

公开(公告)日：1982-06-01

申请号：US226749

申请日：1981-01-21

Applicant: Stephen E. Foh ,  Mono M. Mazumder ,  Jon B. Pangborn

Inventor： Stephen E. Foh ,  Mono M. Mazumder ,  Jon B. Pangborn

IPC: C25B1/04 ,  C25B1/22

CPC classification number: C25B1/04 ,  C25B1/22 ,  Y02E60/366 ,  Y02P20/134

Abstract: A thermoelectrochemical process for production of hydrogen and oxygen from water providing a closed cycle reactant regenerative process wherein the primary energy input is thermal and a smaller electrical energy input is required for an electrolysis step. The process is a hybrid copper oxide-copper sulfate water splitting cycle using copper oxide reactant in the reactions producing both hydrogen and oxygen providing two phase reaction products in each step.

Abstract translation: 一种用于从水提供氢和氧的热电化学方法，提供封闭循环反应物再生过程，其中一次能量输入是热的，并且电解步骤需要较小的电能输入。 该方法是在产生氢和氧的反应中使用氧化铜反应物的混合氧化铜 - 硫酸铜水分解循环，在每个步骤中提供两相反应产物。

公开(公告)号：US4075313A

公开(公告)日：1978-02-21

申请号：US668138

申请日：1976-03-18

Applicant: Jon B. Pangborn ,  John C. Sharer ,  Robert H. Elkins

Inventor： Jon B. Pangborn ,  John C. Sharer ,  Robert H. Elkins

IPC: C01B3/06 ,  C01B3/10 ,  C01B1/08 ,  C01B13/00

CPC classification number: C01B3/063 ,  C01B3/068 ,  C01B3/105 ,  Y02E60/36

Abstract: A process for the production of hydrogen and oxygen from water comprising the steps of forming ferric chloride from ferriferrous oxide by reaction with a chloride ion yielding substance, thermally reducing the ferric chloride to produce ferrous chloride, reducing the ferrous chloride to metallic iron, then oxidizing the metallic iron with water so as to produce hydrogen. The metallic iron may be formed by reducing the ferrous compound with hydrogen. Two specific reactant regenerative closed cycle systems are disclosed utilizing the process of this invention for the production of hydrogen and oxygen.

Abstract translation: 一种从水中生产氢和氧的方法，包括以下步骤：通过与氯离子产生物质反应形成由二氧化铁形成的氯化铁，热还原三氯化铁产生氯化亚铁，将氯化亚铁还原为金属铁，然后氧化 金属铁与水一起生产氢气。 金属铁可以通过用氢还原亚铁化合物来形成。 利用本发明方法生产氢和氧来公开两种具体的反应物再生闭环系统。

公开(公告)号：US3955556A

公开(公告)日：1976-05-11

申请号：US489402

申请日：1974-07-17

Applicant: Jon B. Pangborn ,  John C. Sharer

Inventor： Jon B. Pangborn ,  John C. Sharer

IPC: F24H1/00 ,  F24H1/20 ,  F24H9/18

CPC classification number: F24H1/0045 ,  F24H1/00 ,  F24H1/205 ,  F24H9/1836

Abstract: A catalytic fluid heater formed of a number of nested fluid heating chambers spaced from one another to provide therebetween a heating zone having a chimney effect such that a mixture of fuel gas and air is caused to flow through the heating zone from the bottom to the top thereof. A catalyzed surface is disposed in contact with the walls of adjacent ones of the fluid heating chambers. A fuel gas, preferably hydrogen, is delivered to the heating zones, mixed with air and combusted on the catalyzed walls. The combustion product, in such cases, is primarily water vapor, so that external venting is not required.

Abstract translation: 一种催化流体加热器，由多个嵌套的流体加热室形成，彼此间隔开，从而在其间提供具有烟囱效应的加热区，使得燃料气体和空气的混合物从底部到顶部流过加热区 其中。 催化表面设置成与相邻的流体加热室的壁接触。 燃料气体，优选氢气被输送到加热区域，与空气混合并在催化壁上燃烧。 在这种情况下，燃烧产物主要是水蒸汽，因此不需要外部排气。

公开(公告)号：US4303121A

公开(公告)日：1981-12-01

申请号：US899377

申请日：1978-04-24

Applicant: Jon B. Pangborn

Inventor： Jon B. Pangborn

IPC: F28D20/00 ,  F28D13/00 ,  F24H7/00 ,  F24J1/00

CPC classification number: F28D20/003 ,  F24J2/423 ,  Y02E60/142 ,  Y02E70/30

Abstract: A process and apparatus for energy storage wherein thermal energy from solar or waste heat derived sources is passed in thermal exchange relation with a hydrated inorganic salt, such as calcium sulfate, endothermically dehydrating the salt thereby storing chemical energy and releasing the stored energy as heat by passing water under hydration conditions in contact with the salt exothermically hydrating the salt. The released thermal energy is substantially isothermal and available for any desired use involving thermal energy input. The process and apparatus of this invention is particularly suited to utilization of solar derived thermal energy.

Abstract translation: 一种能量储存的方法和装置，其中来自太阳能或废热衍生源的热能与水合无机盐（例如硫酸钙）以热交换关系通过，从而吸收盐，从而储存化学能并将储存的能量作为热释放 在与盐接触的水合条件下通过水使盐放热水合。 释放的热能基本上是等温的，可用于涉及热能输入的任何期望的使用。 本发明的方法和装置特别适合利用太阳能衍生的热能。

公开(公告)号：US3939257A

公开(公告)日：1976-02-17

申请号：US390178

申请日：1973-08-20

Applicant: Jon B. Pangborn ,  John C. Sharer

Inventor： Jon B. Pangborn ,  John C. Sharer

IPC: C01B3/06 ,  C01B1/02 ,  C01B1/05 ,  C01B7/08

CPC classification number: C01B3/068 ,  Y02E60/36

Abstract: A process for the production of hydrogen and oxygen from water comprising the steps of forming ferric chloride from ferriferrous oxide by reaction with a chloride ion yielding substance, reducing the ferric chloride produced with a reducing agent to produce ferrous chloride, and then oxidizing the ferrous compound with water so as to produce hydrogen. Suitable reducing agents include cuprous chloride, chromous chloride and platinum. Several reactant regenerative closed cycle systems are disclosed utilizing the process of this invention for the production of hydrogen with high energy efficiences.

Abstract translation: 一种从水中生产氢和氧的方法，包括以下步骤：通过与产生氯离子的物质反应从氧化亚铁形成氯化铁，还原用还原剂生产的氯化铁，生成氯化亚铁，然后氧化亚铁化合物 用水制成氢气。 合适的还原剂包括氯化亚铜，氯化铬和铂。 利用本发明的方法公开了用于生产具有高能效的氢气的几种反应物再生闭环系统。