POWER STATION-BASED METHANATION SYSTEM
    2.
    发明申请
    POWER STATION-BASED METHANATION SYSTEM 审中-公开
    基于电站的甲烷系统

    公开(公告)号:US20150080483A1

    公开(公告)日:2015-03-19

    申请号:US14390990

    申请日:2013-03-22

    IPC分类号: C07C1/04 C07C1/12 B01J7/00

    摘要: A power station-based methanation system which has a fossil fuel-fired power station together with an electrolysis unit and a methanation reactor is provided. The power station and the electrolysis unit are configured for supplying the methanation reactor with starting materials for a methanation reaction and the electrolysis unit can be operated both in a charging state and in a discharging state, in which charging state the electrolysis unit supplies electric power and a chemical energy store is at the same time charged and in which discharging state the chemical energy store is discharged.

    摘要翻译: 提供了一种具有化石燃料发电站的电站甲烷化系统以及电解单元和甲烷化反应器。 电站和电解单元构成为向甲烷化反应器供应用于甲烷化反应的原料,并且电解单元可以在充电状态和放电状态下操作,其中电解单元提供电力的充电状态, 化学能量储存器同时被充电,并且其中放电状态使化学能量存储器放电。

    Methods and Systems for Synthesizing Iron-Based Materials and Sequestering Carbon Dioxide
    3.
    发明申请
    Methods and Systems for Synthesizing Iron-Based Materials and Sequestering Carbon Dioxide 有权
    用于合成铁基材料和螯合二氧化碳的方法和系统

    公开(公告)号:US20120225007A1

    公开(公告)日:2012-09-06

    申请号:US13319831

    申请日:2010-05-14

    IPC分类号: C01B3/10 B01J7/00 C01G49/02

    摘要: Methods and systems for sequestering carbon dioxide and generating hydrogen are disclosed. In some embodiments, the methods include the following: dissolving an iron based material that includes a carbonate-forming element into a solution including the carbonate-forming element and iron; increasing a pH of the solution to cause precipitation of iron oxide from the solution thereby generating a first source of Fe2O3; reacting the carbonate-forming element in the solution with a first source of carbon dioxide to produce a carbonate thereby sequestering the carbon dioxide; oxidizing the first source of Fe2O3 with a carbonaceous fuel thereby generating a second source of carbon dioxide and iron; and oxidizing the iron with steam thereby generating hydrogen and an iron oxide. Some embodiments include producing iron-based catalysts.

    摘要翻译: 公开了用于隔离二氧化碳和产生氢的方法和系统。 在一些实施方案中,所述方法包括:将包含碳酸酯形成元素的铁基材料溶解到包含碳酸酯形成元素和铁的溶液中; 增加溶液的pH使溶液中的氧化铁沉淀,从而产生第一Fe 2 O 3源; 使溶液中的碳酸酯形成元素与第一二氧化碳源反应以产生碳酸盐,从而螯合二氧化碳; 用碳质燃料氧化第一来源的Fe 2 O 3,从而产生第二二氧化碳和铁源; 并用蒸汽氧化铁,从而产生氢气和氧化铁。 一些实施方案包括生产铁基催化剂。

    Process and apparatus for prodcing concrrently hydrogen or ammonia and metal oxide nanoparticles
    5.
    发明申请
    Process and apparatus for prodcing concrrently hydrogen or ammonia and metal oxide nanoparticles 审中-公开
    产生氢或氨和金属氧化物纳米粒子的方法和装置

    公开(公告)号:US20080019903A1

    公开(公告)日:2008-01-24

    申请号:US11628271

    申请日:2005-06-06

    申请人: KARSTEN WEGNER

    发明人: KARSTEN WEGNER

    IPC分类号: C01B3/08 B01J19/00

    摘要: A process for producing hydrogen or ammonia is disclosed. Steam (202) and a metal or a metal-containing compound (in the case of ammonia production, a metal nitride) are provided to a reaction zone (213) and reacted under conditions for obtaining gaseous hydrogen or ammonia, respectively. The metal or metal-containing compound is provided in the form of nanoparticles and/or nanodroplets with a BET surface area of at least 1.0 m2/g. The nanoparticles and/or nanodroplets may be produced in-situ, either by rapid cooling of a stream of a vapor (203) of the metal or metal-containing compound in a formation zone (212), or by feeding a stream of a precursor into the formation zone (212) and reacting the precursor with a reactant gas in the formation zone to obtain nanoparticles and/or nanodroplets. An apparatus (201) for carrying out the process is also disclosed

    摘要翻译: 公开了一种生产氢或氨的方法。 蒸汽(202)和金属或含金属的化合物(在氨生产的情况下,金属氮化物)分别提供到反应区(213),并在分别获得气态氢或氨的条件下反应。 金属或含金属的化合物以BET表面积至少为1.0m 2 / g的纳米颗粒和/或纳米液的形式提供。 可以通过在形成区(212)中快速冷却金属或含金属化合物的蒸汽(203)的流,或者通过将前体的流进料进行快速冷却来原位制备纳米颗粒和/或纳米质点 进入形成区(212)并使前体与形成区中的反应气体反应,以获得纳米颗粒和/或纳米液。 还公开了一种用于执行该过程的设备(201)

    Catalytic method of generating hydrogen
    7.
    发明授权
    Catalytic method of generating hydrogen 失效
    生成氢气的催化方​​法

    公开(公告)号:US5840270A

    公开(公告)日:1998-11-24

    申请号:US477521

    申请日:1995-06-07

    申请人: John Werth

    发明人: John Werth

    摘要: The catalyzed method of this invention features a method for operating an electrical automotive vehicle. The method of the invention utilizes a hydrogen-air fuel cell to power an electrical automotive vehicle having electrical drive motors. Hydrogen to fuel the fuel cell is supplied onboard by a bed of iron that is made to react with H.sub.2 O in the presence of an alkaline catalyst at temperatures not exceeding approximately 250.degree. C. The preferred alkali hydroxide is the hydroxide of potassium in a range of concentrations between 50 to 60 percent by weight, with the preferred concentration being about 53%. The hydrogen for fueling the fuel cell is generated onboard the automobile, in situ, by using a storage compartment containing iron materials. The hydrogen is generated by passing heated water over freshly ground iron, which then becomes iron oxide. The vehicle's operator obtains a fresh charge of the new iron materials from an iron fuel station for placement in a compartment of the vehicle. The iron materials of this invention may comprise in situ freshly-ground particulates. The particles range in diameter size from approximately 25 to 1,200 .mu.m, with an average-sized distribution having at least twenty per cent (20%) of the particles less than 300 .mu.m in diameter. It is preferable that at least 50% are less than 300 .mu.m in diameter. The average particle density ranges approximately from about 1 to 7.8 g/cc, with a non-compressed packed particle density ranging from about 1.5 to 3.5 g/cc. The particles have a surface area greater than approximately 0.001 meters.sup.2 /g.

    摘要翻译: 本发明的催化方法的特征在于一种用于操作电动汽车的方法。 本发明的方法利用氢空气燃料电池来为具有电驱动电动机的电动汽车提供动力。 通过在碱性催化剂存在下,在不超过约250℃的温度下与H 2 O反应的铁床提供氢气来燃料燃料电池。优选的碱金属氢氧化物是钾的氢氧化物,其范围为 浓度在50至60重量%之间,优选浓度为约53%。 用于燃料燃料电池的氢气通过使用包含铁材料的储藏室就地在汽车上产生。 通过将热水通过新鲜研磨的铁生成氢,然后将其变成氧化铁。 车辆的操作员从铁燃料站获得新的铁材料,以便放置在车辆的车厢内。 本发明的铁材料可以包括原位新鲜研磨的颗粒。 颗粒的直径尺寸范围为约25至1,200μm,其平均尺寸分​​布至少具有直径小于300μm的颗粒的20%(20%)。 优选至少50%的直径小于300μm。 平均颗粒密度范围约为1至7.8g / cc,非压缩填充颗粒密度为约1.5至3.5g / cc。 颗粒的表面积大于约0.001m 2 / g。

    Process for producing hydrogen and oxygen from water
    8.
    发明授权
    Process for producing hydrogen and oxygen from water 失效
    从水中产生氢和氧的方法

    公开(公告)号:US4075313A

    公开(公告)日:1978-02-21

    申请号:US668138

    申请日:1976-03-18

    摘要: A process for the production of hydrogen and oxygen from water comprising the steps of forming ferric chloride from ferriferrous oxide by reaction with a chloride ion yielding substance, thermally reducing the ferric chloride to produce ferrous chloride, reducing the ferrous chloride to metallic iron, then oxidizing the metallic iron with water so as to produce hydrogen. The metallic iron may be formed by reducing the ferrous compound with hydrogen. Two specific reactant regenerative closed cycle systems are disclosed utilizing the process of this invention for the production of hydrogen and oxygen.

    摘要翻译: 一种从水中生产氢和氧的方法,包括以下步骤:通过与氯离子产生物质反应形成由二氧化铁形成的氯化铁,热还原三氯化铁产生氯化亚铁,将氯化亚铁还原为金属铁,然后氧化 金属铁与水一起生产氢气。 金属铁可以通过用氢还原亚铁化合物来形成。 利用本发明方法生产氢和氧来公开两种具体的反应物再生闭环系统。

    Producing hydrogen and oxygen by decomposition of water via the
thermochemical iron-chlorine system
    9.
    发明授权
    Producing hydrogen and oxygen by decomposition of water via the thermochemical iron-chlorine system 失效
    通过热化学铁 - 氯系统分解水生产氢气和氧气

    公开(公告)号:US4024230A

    公开(公告)日:1977-05-17

    申请号:US613000

    申请日:1975-09-12

    CPC分类号: C01B3/063 C01B3/105 Y02E60/36

    摘要: Decomposition of water to hydrogen and oxygen with the aid of a thermochemical cyclic process based upon the iron/chlorine system by reduction of FeCl.sub.2 in the presence of H.sub.2 to Fe, oxidation of the Fe with steam to Fe.sub.3 O.sub.4, treatment of the hot Fe.sub.3 O.sub.4 with steam and chlorine to obtain oxygen, conversion of themixture of iron oxides so obtained with hydrogen chloride to FeCl.sub.2 and recycling of the FeCl.sub.2 to the reduction stage, wherein a part of the heat required for the process is supplied by heating the hydrogen and steam in indirect heat exchange with a hot coolant from a high temperature nuclear reactor. The conversion of the iron oxides to FeCl.sub.2 is carried out via the intermediate stage of dimeric FeCl.sub.3 and it is thus possible to convey the solid reaction products by free fall through the reaction zones.

    摘要翻译: 借助于基于铁/氯系统的热化学循环过程,将水分解成氢和氧,通过在H 2存在下将FeCl 2还原成Fe,将Fe用蒸汽氧化成Fe 3 O 4,用蒸汽处理热的Fe 3 O 4 和氯以获得氧气,用氯化氢将如此获得的氧化铁的混合物转化成FeCl 2并将FeCl 2再循环到还原阶段,其中通过以间接加热方式加热氢气和蒸汽来供应该方法所需的一部分热量 与来自高温核反应堆的热的冷却液进行交换。 铁氧化物转化为FeCl 2通过二聚FeCl 3的中间阶段进行,因此可以通过自由落体通过反应区输送固体反应产物。

    Process for obtaining hydrogen and oxygen from water
    10.
    发明授权
    Process for obtaining hydrogen and oxygen from water 失效
    从水中获取氢和氧的方法

    公开(公告)号:US4011305A

    公开(公告)日:1977-03-08

    申请号:US512797

    申请日:1974-10-04

    摘要: A process for the dissociation of water into hydrogen and oxygen in a multi-stage closed cycle process using a system involving at least one metallic element having multiple valency and at least one halogen, characterized in that a halide of the multiple valency metallic element is subjected to a mixture of steam and hydrogen converting the halide to a mixture of the metallic element and at least one oxide thereof, said latter mixture is subjected to steam to produce a mixed valency oxide of the metallic element accompanied by the liberation of hydrogen, and said mixed valency oxide is then subjected to a hydrogen halide to convert it back to the said metallic halide with the liberation of oxygen.